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An enzyme oxidizing a-hydroxy acids to a-keto acids may bind only one enantiomer (binding specificity) or it may bind both but oxidize only one isomer. ...
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Identification of (trapped) intermediates. Determination of regio- and stereospecificity of reaction mechanisms ... bovine PLA2 free (Tsai) Interfacial catalysis ...
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Syn addition for the formation of cis-alkenes. Anti addition for the formation of trans-alkenes ... rule. Explanation: t-butyl bromide !! 13. 14. General ...
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Chapter 8: Enzymes!! Properties of Enzymes. Proteins. Catalysts ... (OMP=Orotidine monophosphate involved in UMP synthesis) Proteases: e.g. ? Trypsin. Chymotrypsin ...
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Title: OC 2/e 13 NMR Author: Bill Brown Last modified by: Bill Brown Created Date: 7/20/1997 6:22:08 AM Document presentation format: US Letter Paper
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Chapter 13 Introduction to Enzymes Read pages 459 466 & 470 Chymotrypsin with bound substrate Enzymes are the agents of metabolic function Enzymes endow cells ...
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30 alcohol 20 alcohol 10 alcohol. some primary and secondary ... Vicinal Debromination. vicinal (vic) geminal (gem) 14. E2 mechanism. 15. Reactivity (ch 8) ...
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Chorismate Mutase-catalyzed Conversion of Chorismate to Prephenate Conformation of Chorismate in ... Figure 13.4 Ab initio calculations disfavor pathway e No ...
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Spontaneous Reactions: thermodynamically or energetically favorable ... Hydrolases: hydrolysis reactions (cleavage and introduction of water) ...
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Organometallic compound: a compound that contains a carbon-metal bond. We focus on organometallic ... prepared by photolysis or thermolysis of diazomethane ...
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ketone. 58. Reaction with both esters and acyl halides. Two ... OH, -NH2, -NHR, -CO2H, -SO3H, -SH, -CC-H, aldehyde, ketone, esters, amide -NO2, -CN, epoxide ...
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product, you need to know two things: (1) stereochemistry of alkene (cis or trans; ... atactic. isotactic. syndiotactic. Atactic Polypropylene ...
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Examining Pharmaceutical Claims of Immense Scope Gary L. Kunz Supervisory Patent Examiner Art Unit 1616 571-272-0887 Michael Woodward Training Quality Assurance ...
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Pasteur First scientist to study enzyme-catalyzed reactions. ' Fermentations' Buchner Ground yeast cells and made ... pepsinogen -- pepsin. Medical Enzymes ...
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... NADH ATP, ADP Ca+2 key allosteric enzymes: the dehydrogenases citrate synthase LNC Fig.16.15 the Krebs cycle is amphibolic THE GLYOXYLATE CYCLE LNC Chapter ...
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Borane, BH3, adds a hydrogen to the most substituted carbon in ... the alkyl borane with basic hydrogen peroxide produces the alcohol. ... hydrogen peroxide ...
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Electrons in pi bond are loosely held. Electrophiles are attracted ... Milder oxidation than permanganate. Products formed are ketones or aldehydes. Chapter 8 ...
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Conjugation and Color. Visible region is... Extended systems of conjugation absorb in visible region. b-Carotene, 11 double bonds in conjugation, max = 455 nm ...
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Jurgen Doreleijers, Ton Rullmann & Rob Kaptein. NMR spectroscopy, ... No labile protons. Arginine. Tyrosine. 8. Universiteit Utrecht. Example: HU Protein ...
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Title: Introduction to enzymes Author: William R. Widger Last modified by: jaljamalr Created Date: 9/12/1998 6:36:47 PM Document presentation format
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... tryptophan (Mexican Indians treated corn with Ca(OH)2 before making tortillas! ... 2. Metal-activated enzymes- loosely bind ions Na , K , Mg , or Ca ...
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HX is lost from the alkyl halide and an alkene is formed. b-carbon. a-carbon. new p-bond is formed ... Reactions of Secondary Alkyl Halides ...
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Pick up oranges with left hand and peel them with right hand. Maximum velocity, Vmax ... Add plastic balls to the bin of oranges. Non-competitive. Alters enzyme ...
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A compound with an electronegative atom bonded to an sp3 ... Larger than second row anion nucleophile. Weaker base with other substitution-enhancing cond's ...
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5-ethyl-2-methyl-2,4-heptadiene. Chapter 6. 11. IUPAC Nomenclature of Dienes ... 5-ethyl-2-methyl-2,4-heptadiene. or 5-ethyl-2-methyl-hepta-2,4-diene. Chapter 6. 12 ...
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At physiological pH the amino acids exist as a bipolar ion known as a zwitterion. ... Natural polymers made up of a-amino acids (molecular weight from ' 6000 to ...
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product, you need to know two things: (1) stereochemistry of alkene (cis or trans; ... atactic. isotactic. syndiotactic. Atactic Polypropylene ...
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Living organisms extract, transform, and use energy from ... Catabolism degradation. Anabolism synthesis. ATP is universal carrier of metabolic energy, ...
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Radionuclide production in cyclotron. Dose dispensing ... protocol is required for recovery of radionuclide produced via 18O(p,n)18F ...
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Structurally non-specific action results from accumulation of a drug in some ... Structural features of drugs and their pharmacological activity Stereochemistry: ...
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Title: OC 2/e 6 Subject: Alkenes II Author: Bill Brown Description: Same format as Alkenes I Last modified by: Bill Brown Created Date: 7/13/1997 8:01:25 AM
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Abundance of articles available which document the high unpredictability of the ... but actually caused pain-like behavior (scratching, biting, and licking) ...
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Compounds can have more than one double or triple bond ... Charles Goodyear discovered heating with small amount of sulfur produces strong material ...
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From Prediction of Structure to Design of Function
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Largely done for core atoms, but need extra logic to handle. S,P atoms (d orbitals) ... Before full combinatorial reactivity compatibility check, pre-filter orbital ...
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IN ETHER, THE CONCENTRATION OF CHLORIDE ION. IS LOW, DECOMPOSITION ... In ether - the chlorosulfite ester undergoes thermal decomposition, SNi with retention. ...
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Third Year Organic Chemistry Course CHM3A2 Frontier Molecular Orbitals and Pericyclic Reactions Part 2(ii): Cycloaddition Reactions Suprafacial HOMO y2
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Understand the chemical makeup of polymeric materials ... Engineering plastics. TS's. 8. 4.3 Altering Polymer Properties. Molecular weight changes ...
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Summary of Anaerobic Glycolysis. Glucose 2 ADP 2 Pi. 2 Lactate 2 ATP 2 H2O 2 H ... Glucose 6 O2 6 CO2 6 H2O. Go' = -200 kJ/mol. Go' = -2866 kJ/mol ...
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Stereochemistry Chapter 6 Is the ... Tamiflu: a drug for influenza Transition state for action of influenza neuraminidase N-acetyl neuraminic acid O-sugar ...
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where n = number of structural units capable of stereochemical variation ... atactic. isotactic. syndiotactic. Dr. Wolf's CHM 201 & 202. 7-22. Atactic Polypropylene ...
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Chemical measured in a laboratory. Physical mainly non-destructive ... Engineering (Fig 2-15) True (Fig 2-16) Work or strain hardening. Significance of exponent ...
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Why study thermal sensation
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GLUTATHIONE SYNTHESIS, EFECT OF NUTRITION ON REGULATORY CONTROL MECHANISM Mohammad Hanafi, MBBS (Syd).,dr.,MS.) Senior Lecturer in Biochemistry
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Nomenclature and classification of enzymes. General classification. Isoenzymes ... The present-day accepted nomenclature of enzymes is that recommended by the ...
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Second Year Organic Chemistry Course CHM3A2 Frontier Molecular Orbitals and Pericyclic Reactions Part 2(i): Electrocyclic Reactions An electrocyclic reaction involves ...
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Email: adriennepedrech@hotmail.com -Course website: http://www.chemistry.mcmaster.ca ... Lectures: MW 8:30 F 10:30 (CNH/B107) Office Hours: T 10:00-12:30 & F 1: ...
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cause crowding. and give Hofmann. products. ANALYSIS OF 2-SUBSTITUTED PENTANE ELIMINATIONS ... less crowding in. this area of the. molecule. cis. trans. ZAITSEV ...
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Arial Angsana New Arial Unicode MS Symbol Default Design CS ChemDraw Drawing Pericyclic Reactions Slide 2 Slide 3 Slide 4 Slide 5 Diels Alder Reaction More ...
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Organic Chemistry. Molecular Orbital Theory- Spartan. Dimethylhexanes- ring conformations ... Combinatorial Chemistry. Parallel testing. Cleverly prepared mixtures ...
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Glycolysis Glycolysis G-6-P inhibits hexokinase Glucose stimulates hexokinase production Concept of Km? Definition of a Kinase Mg++ or Mn++ Inhibited by Fluorine ...
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Unauthorized copying and re-distribution of this document or its contents is prohibited. ... Potential in fowl (think of the egg) ...
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Clinical Use of Dexmedetomidine Charles E. Smith, MD Professor of Anesthesia Director, Cardiothoracic Anesthesia MetroHealth Medical Center Case Western Reserve ...
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consideration whatever shall be given to the nationality of the ... 1908, many researchers have tried to unravel and prove the mechanism of this reaction. ...
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The E-S complex is a central feature of the Michaelis-Menten approach to ... Carbonic anhydrase 600,000. Acetyl cholinesterase 25,000. Penicillinase 2,000 ...
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A helical wheel diagram showing the distribution of polar and non-polar residues ... Side-by-side association of four amphipathic helices ...
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