Title: CH HYPERDISPERSANT
1CH HYPERDISPERSANT
- STRUCTURE PRORERTIES
- SHANGHAI SANZHENG POLYMER MATERIAL Co.,LTD
2DISPERSING PROCESS OF PIGMENTS
- 1) WETTING
L/S INTERFACE--S/G INTERFACE - 2) DEAGGLOMERATION BREAKAGE
REAGGLOMERATION - 3) STABILIZATION REMAINING PARTICLE
SIZE ITS DISTRIBUTION
3MECHANISM OF DISPERSION STABILIZATION
- ELECTROSTATIC STABILIZATION DOUBLE--LAYER
THEORY - STERIC STABILIZATION OSMOTIC REPULSION
THEORY ENTROPIC REPULSION THEORY
4DEEFFICIENCY OF CLASSICAL SURFACTANTS
- HYDROPHILIC GROUP NOT DESIGNED
FOR PIGMENT SURFACE, EASY TO DESORB - HYDROPHOBIC GROUP NON-POLAR
STRUCTURE INCOMPATIBLE WITH POLAR MEDIA 18
CARBON ATOMS, TOO SHORT
5MOLECULAR STRUCTURE OF CH HYPERDISPERSANTS
6ANCHORING GROUP
- DESIGNED FOR PIGMENT SURFACE STRONG POLARITY
SURFACE SINGLE-SPOT CHEMICAL BONDING WEAK
POLARITY SURFACE MULTI-SPOT HYDROGEN BONDING
NON-POLAR PIGMENT SURFACE SURFACE SYNERGIST
7SOLVATABLE CHAIN
- MONO-FUNCTIONAL TERMINAL
- JUSTABLE COMPATIBILITY MONOMER STRUCTURE
MONOMER RATIO SOLVATABLE CHAIN
POLARITY - LENGTH OF SOLVATABLE CHAIN CONTROLLED
MOLECULAR WEIGHT ADEQUATE CHAIN LENGTH
8MORPHOLOGY OF HYPERDISPERSANT
9ADSORPTION PROPERTIES OF HYPERDISPERSANT
Rehacek Method
10??????????????? (Mn700)
??????????????? (Mn1500)
?????????????? (Mn700)
?????????????? (Mn1500)
11 RHEOLOGICAL PROPERTIES OF THE DISPERSION
WITH HYPERDISPERSANT
Viscosity-reducing properties
Viscosity-reducing properties
Influence of anchoring group
Influence of solvatable chain
12STABILIZATION PROPERTIES OF THE DISPERSION WITH
HYPERDISPERSANT
Deposition curve of magnetic
dispersion
Viscosity stability of the ink with
hyperdispersant
13METHOD OF USE OF HYPERDISPERSANTS
- MINIMAL RESIN REDUCED
RESIN SOLIDS--LOWERED VISCOSITY STABILITY - ADDING HYPERDISPERSANT IMPROVED
STABILITY FURTHER
REDUCED VISCOSITY - IMPROVING PIGMENT CONTENT HIGH PIGMENT /
VEHICLE RATIO HIGH STABILITY, NORMAL
VISCOSITY
14NOTATION FOR USE OF HYPERDISPERSANT
- ADDED BEFORE PIGMENTS, FILLERS AND OTHER
INGREDIENTS - ADDING SURFACTANTS DURING LET-DOWN OR LATER
STAGES - DOSAGE DEPENDS ON SURFACE AREA(ABOUT 2MG/M2)
15ADVANTAGES OF HYPERDISPERSANTS
- FAST WETTING, SHORTER MILLING TIME, IMPROVED
PRODUCTIVITY - HIGH PIGMENT / VEHICLE RATIO, LESS ENERGY AND
LABOUR COST - REDUCED VISCOSITY, IMPROVED RHEOLOGICAL
PROPERTIES - IMPROVED DISPERSING STABILITY, IN AVOID
OF RE-DISPERSION
16ADVANTAGES OF HYPERDISPERSANTS
- WIDE COMPATIBILITY OF MILLBASE
- NOT EASY TO BE OXIDIZED, LESS SURFACE WASTAGE
PRODUCED - HYDROPHOBIC DISPERSANTS NO
HYDROPILIC FILM INDUCED - COMPLETE WETTING AND BETTER APPLICATION
QUALITIES
17CH Hyperdispersant
18HYPERDISPERSANT SELECTION
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19HYPERDISPERSANT
20BENEFITS
- IMPROVED QUALITY HIGHER GLOSS
GREATER INTENSITY
MORE TRANSPARENCY - HIGHER PRODUCTIVITY SHORTER
DISPERSION TIMES HIGHER PIGMENT CONTENT
21BENEFITS
- MORE FLEXIBILITY
- MORE VERSATILE MILLBASE HEATSET AND
SHEETFET FROM SAME MILLBASE - MORE STABLE CONCENTRATES ABILITY TO
TRANSPORT
22HYPERDISPERSANT FOR OFFSET INKS
- HYPERDISPERSANT SELECTION
- FOR LITHOL RUBINE / RUBINE TONER
- USE CH-5 ONLY
- FOR PHTHALOCYANINE BLUE OR CARBON BLACK
- USE CH-5 CH-11B
- FOR DIARYLIDE YELLOW USE
CH-5 CH-22
23TYPICAL DOSAGE
- (SHOWN AS WEIGHT OF PIGMENT)
- RUBINE-------8----CH-5
- BLUE---------10----31 CH-5CH-11B
- YELLOW---10---31 CH-5CH-22
- BLACK------4--10 CH-5
(DEPENDS ON THE SPECIAL SURFACE OF CARBON
BLACK)
24GUIDELINES FOR USE
- REDUCING RESIN SOLID TO 30-40 IN
MILLBASE - HOLD BACK IN MILLBASE AS MUCH AS POSSIBLE
GELLED VEHICLE OR GELLING AGENT - ADDING HIGHER PROPORTIONS OF GELLED VEHICLE
/ GELLING AGENT AT THE LET-DOWN STAGE TO
COMPENSATE
25TYPICAL FORMULATIONHEATSET / SHEETFET MILLBASE
26TYPICAL FORMULATIONGRINDING VEHICLE
27TYPICAL FORMULATIONLET-DOWN VARNISHES
28TYPICAL FORMULATIONFINAL INK FORMULATIONS
29TYPICAL FORMULATIONFINAL INK FORMULATIONS
30CH-35 WATER PICK-UP REDUCING AGENT
- APPLICATION IN OFFSET PRINTING INK AND FLUSH
31BENEFITS OF CH-35
- REDUCING EMULSIFICATION, IMPROVING THE FLUIDITY,
TRANSFERRING AND PRINTING DENSITY OF OFFSET INK - REDUCING WATER PICK-UP, FAST CREATING WATER
BALANCE - ACCELERATING THE OUT-COMING OF WATER IN FLUSH
- CONVENIENT TO USE
32METHOD OF USE OF CH-35
- ADDED IN THE VEHICLE DURING THE PREPARATION
PROCESS OF INK OR FLUSH,OR ADDED IN THE INK
PRODUCT - COMPLETELY MIXED WITH VEHICLE
- AT THE DOSAGE OF 0.2-0.4
33CH-1 HYPERDISPERSANT
- APPLICATION IN MASTERBATCH
- AND PLASTIC COMPOUNDS
34BENIFITS OF CH-1
- REDUCED PIGMENT COST
- IMPROVED PRODUCTIVITY
- IMPROVED PRODUCT QUALITY
- REDUCED MANUFACTURE COST
- IMPROVED PROCESSING
- NO OBVIOUS ADVERSE EFFECTS
35METHOD OF USE OF CH-1
- Charge polymer to high speed blender or tumbler
- Add CH-1 and blend thoroughly with polymer
(2min/1800rpm blender or 5min tumbling) - Add pigments, fillers, processing aids and other
essential ingredients and continue blending.
(1min/1800rpm blending or 15min tumbling) - Process resultant blend in normal manner. e.g.
extrusion,internal mixing, or 2-roll milling.
36TYPICAL FORMULATION OF CH-1 IN PE
MASTERBATCH
37TYPICAL FORMULATION OF CH-1 IN RIGID
PVC--WINDOW PROFILE COMPOUND
38TYPICAL FORMULATION OF CH-1 IN PVC BOTTLE
COMPOUND
39TYPICAL FORMULATIONFLEXIBLE PVC--CABLE
- FORMULATION ?OF TBLS
- TRIBASIC LEAD ?SULPHATE 80PHR
- LEAD 5PHR
- DOP 8PHR
- SNOWCAL70 5PHR
40TYPICAL FORMULATION OF CH-1 IN ABS
41TYPICAL FORMULATION OF CH-1 IN PS
42CH-2 HYPERDISPERSANT
- APPLICATION IN
- PLASTICISER DISPERSION
43CH-2 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
- BENEFITS
- LOW VISCOSITY, GOOD FLOW AND
PUMPABILITY - HIGH PIGMENT CONTENT, IMPROVED PRODUCTIVITY
- MORE NEWTONIAN RHEOLOGY
- IMPROVED COLOUR STRENGTH
44CH-2 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
- BENEFITS
- SHORTER MILLING TIMES, LOWER ENERGY
CONSUMPTION, LOWER LABOUR AND FIXED COSTS - LESS COLOUR SEPARATIO
- WIDE COMPATIBILITY
- NO ADVERSE EFFECT ON PLASTICS
45METHOD OF USE OF CH-2
- ADDED AND DISSOLVED INTO PLASTICISER BEFORE
ADDING OTHER INGREDIENTS - AT DOSAGE OF ABOUT 1--5 OF THE TOTAL
WEIGHT OF PIGMENTS AND FILLERS - HIGH PIGMENT LOADING
46TYPICAL FORMULATION OF CH-2 IN PLASTICISER
DISPERSION
47CH-6 HYPERDISPERSANT
APPLICATION IN PLASTICISER DISPERSION
48CH-6 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
- BENEFITS
- LOW VISCOSITY, GOOD FLOW AND
PUMPABILITY - HIGH PIGMENT CONTENT, IMPROVED PRODUCTIVITY
- MORE NEWTONIAN RHEOLOGY
- IMPROVED COLOUR STRENGTH
49CH-6 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
- BENEFITS
- SHORTER MILLING TIMES, LOWER ENERGY
CONSUMPTION, LOWER LABOUR AND FIXED COSTS - LESS COLOUR SEPARATIO
- WIDE COMPATIBILITY
- NO ADVERSE EFFECT ON PLASTICS
50METHOD OF USE OF CH-6
- ADDED AND DISSOLVED INTO PLASTICISER BEFORE
ADDING OTHER INGREDIENTS - AT DOSAGE OF ABOUT 5-15 OF THE TOTAL
WEIGHT OF CARBON BLACK OR ORGANIC PIGMENTS - HIGH PIGMENT LOADING
51TYPICAL FORMULATION
52CH-4 HYPERDISPERSANT
- APPLICATION IN
- SURFACE TREATMENT
53BENEFITS OF CH-4
- MAKE PIGMENT HYDROPHOBIC, LESS WATER
CONTENT,EASY TO BE FILTERED AND DRIED - MAKE PIGMENT AGGEARATED LOOSELY,EASY TO BE
DISPERSED - REDUCED OIL ADSORPTION, IMPROVED HEAT
STABILITY AND COLOUR STRENGTH
54METHOD OF USE OF CH-4
- ADDED AND MIXED COMPLETELY WITH PIGMENT OR
FILLER AT ANY STAGE BEFORE FILTERING
PROCESS - DOSAGE ABOUT 10-50 OF THE DRY WEIGHT OF
PIGMENTS