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CH HYPERDISPERSANT

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Title: CH HYPERDISPERSANT


1
CH HYPERDISPERSANT
  • STRUCTURE PRORERTIES
  • SHANGHAI SANZHENG POLYMER MATERIAL Co.,LTD

2
DISPERSING PROCESS OF PIGMENTS
  • 1) WETTING
    L/S INTERFACE--S/G INTERFACE
  • 2) DEAGGLOMERATION BREAKAGE
    REAGGLOMERATION
  • 3) STABILIZATION REMAINING PARTICLE
    SIZE ITS DISTRIBUTION

3
MECHANISM OF DISPERSION STABILIZATION
  • ELECTROSTATIC STABILIZATION DOUBLE--LAYER
    THEORY
  • STERIC STABILIZATION OSMOTIC REPULSION
    THEORY ENTROPIC REPULSION THEORY

4
DEEFFICIENCY OF CLASSICAL SURFACTANTS
  • HYDROPHILIC GROUP NOT DESIGNED
    FOR PIGMENT SURFACE, EASY TO DESORB
  • HYDROPHOBIC GROUP NON-POLAR
    STRUCTURE INCOMPATIBLE WITH POLAR MEDIA 18
    CARBON ATOMS, TOO SHORT

5
MOLECULAR STRUCTURE OF CH HYPERDISPERSANTS
6
ANCHORING GROUP
  • DESIGNED FOR PIGMENT SURFACE STRONG POLARITY
    SURFACE SINGLE-SPOT CHEMICAL BONDING WEAK
    POLARITY SURFACE MULTI-SPOT HYDROGEN BONDING
    NON-POLAR PIGMENT SURFACE SURFACE SYNERGIST

7
SOLVATABLE CHAIN
  • MONO-FUNCTIONAL TERMINAL
  • JUSTABLE COMPATIBILITY MONOMER STRUCTURE
    MONOMER RATIO SOLVATABLE CHAIN
    POLARITY
  • LENGTH OF SOLVATABLE CHAIN CONTROLLED
    MOLECULAR WEIGHT ADEQUATE CHAIN LENGTH

8
MORPHOLOGY OF HYPERDISPERSANT
9
ADSORPTION PROPERTIES OF HYPERDISPERSANT
Rehacek Method
10
??????????????? (Mn700)
??????????????? (Mn1500)
?????????????? (Mn700)
?????????????? (Mn1500)
11
RHEOLOGICAL PROPERTIES OF THE DISPERSION
WITH HYPERDISPERSANT
Viscosity-reducing properties
Viscosity-reducing properties
Influence of anchoring group
Influence of solvatable chain
12
STABILIZATION PROPERTIES OF THE DISPERSION WITH
HYPERDISPERSANT
Deposition curve of magnetic
dispersion
Viscosity stability of the ink with
hyperdispersant
13
METHOD OF USE OF HYPERDISPERSANTS
  • MINIMAL RESIN REDUCED
    RESIN SOLIDS--LOWERED VISCOSITY STABILITY
  • ADDING HYPERDISPERSANT IMPROVED
    STABILITY FURTHER
    REDUCED VISCOSITY
  • IMPROVING PIGMENT CONTENT HIGH PIGMENT /
    VEHICLE RATIO HIGH STABILITY, NORMAL
    VISCOSITY

14
NOTATION FOR USE OF HYPERDISPERSANT
  • ADDED BEFORE PIGMENTS, FILLERS AND OTHER
    INGREDIENTS
  • ADDING SURFACTANTS DURING LET-DOWN OR LATER
    STAGES
  • DOSAGE DEPENDS ON SURFACE AREA(ABOUT 2MG/M2)

15
ADVANTAGES OF HYPERDISPERSANTS
  • FAST WETTING, SHORTER MILLING TIME, IMPROVED
    PRODUCTIVITY
  • HIGH PIGMENT / VEHICLE RATIO, LESS ENERGY AND
    LABOUR COST
  • REDUCED VISCOSITY, IMPROVED RHEOLOGICAL
    PROPERTIES
  • IMPROVED DISPERSING STABILITY, IN AVOID
    OF RE-DISPERSION

16
ADVANTAGES OF HYPERDISPERSANTS
  • WIDE COMPATIBILITY OF MILLBASE
  • NOT EASY TO BE OXIDIZED, LESS SURFACE WASTAGE
    PRODUCED
  • HYDROPHOBIC DISPERSANTS NO
    HYDROPILIC FILM INDUCED
  • COMPLETE WETTING AND BETTER APPLICATION
    QUALITIES

17
CH Hyperdispersant
  • Counter part

18
HYPERDISPERSANT SELECTION
  • ..\sszl\Echyn.htm
  • ..\sszl\Echym.htm
  • ..\sszl\Echyq.htm
  • ..\sszl\Echsl.htm

19
HYPERDISPERSANT
  • OFFSET INK APPLICATION

20
BENEFITS
  • IMPROVED QUALITY HIGHER GLOSS
    GREATER INTENSITY
    MORE TRANSPARENCY
  • HIGHER PRODUCTIVITY SHORTER
    DISPERSION TIMES HIGHER PIGMENT CONTENT

21
BENEFITS
  • MORE FLEXIBILITY
  • MORE VERSATILE MILLBASE HEATSET AND
    SHEETFET FROM SAME MILLBASE
  • MORE STABLE CONCENTRATES ABILITY TO
    TRANSPORT

22
HYPERDISPERSANT FOR OFFSET INKS
  • HYPERDISPERSANT SELECTION
  • FOR LITHOL RUBINE / RUBINE TONER
  • USE CH-5 ONLY
  • FOR PHTHALOCYANINE BLUE OR CARBON BLACK
  • USE CH-5 CH-11B
  • FOR DIARYLIDE YELLOW USE
    CH-5 CH-22

23
TYPICAL DOSAGE
  • (SHOWN AS WEIGHT OF PIGMENT)
  • RUBINE-------8----CH-5
  • BLUE---------10----31 CH-5CH-11B
  • YELLOW---10---31 CH-5CH-22
  • BLACK------4--10 CH-5
    (DEPENDS ON THE SPECIAL SURFACE OF CARBON
    BLACK)

24
GUIDELINES FOR USE
  • REDUCING RESIN SOLID TO 30-40 IN
    MILLBASE
  • HOLD BACK IN MILLBASE AS MUCH AS POSSIBLE
    GELLED VEHICLE OR GELLING AGENT
  • ADDING HIGHER PROPORTIONS OF GELLED VEHICLE
    / GELLING AGENT AT THE LET-DOWN STAGE TO
    COMPENSATE

25
TYPICAL FORMULATIONHEATSET / SHEETFET MILLBASE
26
TYPICAL FORMULATIONGRINDING VEHICLE
27
TYPICAL FORMULATIONLET-DOWN VARNISHES
28
TYPICAL FORMULATIONFINAL INK FORMULATIONS
29
TYPICAL FORMULATIONFINAL INK FORMULATIONS
30
CH-35 WATER PICK-UP REDUCING AGENT
  • APPLICATION IN OFFSET PRINTING INK AND FLUSH

31
BENEFITS OF CH-35
  • REDUCING EMULSIFICATION, IMPROVING THE FLUIDITY,
    TRANSFERRING AND PRINTING DENSITY OF OFFSET INK
  • REDUCING WATER PICK-UP, FAST CREATING WATER
    BALANCE
  • ACCELERATING THE OUT-COMING OF WATER IN FLUSH
  • CONVENIENT TO USE

32
METHOD OF USE OF CH-35
  • ADDED IN THE VEHICLE DURING THE PREPARATION
    PROCESS OF INK OR FLUSH,OR ADDED IN THE INK
    PRODUCT
  • COMPLETELY MIXED WITH VEHICLE
  • AT THE DOSAGE OF 0.2-0.4

33
CH-1 HYPERDISPERSANT
  • APPLICATION IN MASTERBATCH
  • AND PLASTIC COMPOUNDS

34
BENIFITS OF CH-1
  • REDUCED PIGMENT COST
  • IMPROVED PRODUCTIVITY
  • IMPROVED PRODUCT QUALITY
  • REDUCED MANUFACTURE COST
  • IMPROVED PROCESSING
  • NO OBVIOUS ADVERSE EFFECTS

35
METHOD OF USE OF CH-1
  • Charge polymer to high speed blender or tumbler
  • Add CH-1 and blend thoroughly with polymer
    (2min/1800rpm blender or 5min tumbling)
  • Add pigments, fillers, processing aids and other
    essential ingredients and continue blending.
    (1min/1800rpm blending or 15min tumbling)
  • Process resultant blend in normal manner. e.g.
    extrusion,internal mixing, or 2-roll milling.

36
TYPICAL FORMULATION OF CH-1 IN PE
MASTERBATCH
37
TYPICAL FORMULATION OF CH-1 IN RIGID
PVC--WINDOW PROFILE COMPOUND
38
TYPICAL FORMULATION OF CH-1 IN PVC BOTTLE
COMPOUND
39
TYPICAL FORMULATIONFLEXIBLE PVC--CABLE
  • FORMULATION ?OF TBLS
  • TRIBASIC LEAD ?SULPHATE 80PHR
  • LEAD 5PHR
  • DOP 8PHR
  • SNOWCAL70 5PHR

40
TYPICAL FORMULATION OF CH-1 IN ABS
41
TYPICAL FORMULATION OF CH-1 IN PS
42
CH-2 HYPERDISPERSANT
  • APPLICATION IN
  • PLASTICISER DISPERSION

43
CH-2 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
  • BENEFITS
  • LOW VISCOSITY, GOOD FLOW AND
    PUMPABILITY
  • HIGH PIGMENT CONTENT, IMPROVED PRODUCTIVITY
  • MORE NEWTONIAN RHEOLOGY
  • IMPROVED COLOUR STRENGTH

44
CH-2 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
  • BENEFITS
  • SHORTER MILLING TIMES, LOWER ENERGY
    CONSUMPTION, LOWER LABOUR AND FIXED COSTS
  • LESS COLOUR SEPARATIO
  • WIDE COMPATIBILITY
  • NO ADVERSE EFFECT ON PLASTICS

45
METHOD OF USE OF CH-2
  • ADDED AND DISSOLVED INTO PLASTICISER BEFORE
    ADDING OTHER INGREDIENTS
  • AT DOSAGE OF ABOUT 1--5 OF THE TOTAL
    WEIGHT OF PIGMENTS AND FILLERS
  • HIGH PIGMENT LOADING

46
TYPICAL FORMULATION OF CH-2 IN PLASTICISER
DISPERSION
47
CH-6 HYPERDISPERSANT
APPLICATION IN PLASTICISER DISPERSION
48
CH-6 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
  • BENEFITS
  • LOW VISCOSITY, GOOD FLOW AND
    PUMPABILITY
  • HIGH PIGMENT CONTENT, IMPROVED PRODUCTIVITY
  • MORE NEWTONIAN RHEOLOGY
  • IMPROVED COLOUR STRENGTH

49
CH-6 HYPERDISPERSANT FOR PLASTICISER
DISPERSION
  • BENEFITS
  • SHORTER MILLING TIMES, LOWER ENERGY
    CONSUMPTION, LOWER LABOUR AND FIXED COSTS
  • LESS COLOUR SEPARATIO
  • WIDE COMPATIBILITY
  • NO ADVERSE EFFECT ON PLASTICS

50
METHOD OF USE OF CH-6
  • ADDED AND DISSOLVED INTO PLASTICISER BEFORE
    ADDING OTHER INGREDIENTS
  • AT DOSAGE OF ABOUT 5-15 OF THE TOTAL
    WEIGHT OF CARBON BLACK OR ORGANIC PIGMENTS
  • HIGH PIGMENT LOADING

51
TYPICAL FORMULATION
52
CH-4 HYPERDISPERSANT
  • APPLICATION IN
  • SURFACE TREATMENT

53
BENEFITS OF CH-4
  • MAKE PIGMENT HYDROPHOBIC, LESS WATER
    CONTENT,EASY TO BE FILTERED AND DRIED
  • MAKE PIGMENT AGGEARATED LOOSELY,EASY TO BE
    DISPERSED
  • REDUCED OIL ADSORPTION, IMPROVED HEAT
    STABILITY AND COLOUR STRENGTH

54
METHOD OF USE OF CH-4
  • ADDED AND MIXED COMPLETELY WITH PIGMENT OR
    FILLER AT ANY STAGE BEFORE FILTERING
    PROCESS
  • DOSAGE ABOUT 10-50 OF THE DRY WEIGHT OF
    PIGMENTS
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