Chemistry 356

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Chemistry 356

• Structure and reactivity

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http//www.tulane.edu/inorg/PDF20Files/Symmetry
20and20Molecular20Orbitals/Methane20-20Molecul
ar20Orbitals20and20PES.pdf
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Structure from X-ray diffraction
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Structure by X-ray diffraction(ORTEP)
http//www.chem.unl.edu/xray/ORTEP20Drawing.html
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IR spectrum CO2
http//science.widener.edu/svb/ftir/ir_co2.html
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Benzene
Raman
IR
http//riodb01.ibase.aist.go.jp/sdbs/cgi-bin/direc
t_frame_top.cgi
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1H NMR GeH4
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19F NMR ClF3
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19F NMR of PCl2F3
Doublet due to P-F coupling Only one chemical
shiftresult of exchange
Sharpness is lost as temperature increases
Splitting from Fax-Feq (smaller) and P-F
(larger) Check out integration and multiplicity
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31P NMR Rh(PMe3)4Me