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THE PERIODIC TABLE

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Newlands (1865): atomic mass and octaves. Meyers and Mendeleev (1869): based on atomic mass and columns ... Malleability vs. ductility. Electron Configuration ... – PowerPoint PPT presentation

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Title: THE PERIODIC TABLE


1
THE PERIODIC TABLE
2
The History of the Table
  • Dobereiner (early 1800s) triads.
  • Newlands (1865) atomic mass and octaves.
  • Meyers and Mendeleev (1869) based on atomic
    mass and columns with similar properties.
  • Moseley (1913) based on atomic number.

3
The Periodic Law
  • When elements are arranged in order of increasing
    atomic number, their physical and chemical
    properties show a periodic pattern.

4
The Organization
  • Groups or families and periods.
  • Family names.
  • Groups similar properties.
  • Vertical columns vs. horizontal rows.
  • Metals (transition inner transition),
    nonmetals, and semi-metals.
  • Malleability vs. ductility.

5
Electron Configuration
  • Electrons in the highest principle energy level
  • Outermost electrons
  • Valence electrons
  • Elements in a group have similar properties
    because they have valence electrons in a similar
    configuration.
  • Abbreviated electron configuration using the
    noble gas inner core.
  • Four blocks (s, p, d, and f).

6
  • The shape of the periodic table is a result of
    the way electrons fill the orbitals of different
    energy levels.

7
Periodic TrendsA systematic variation in the
properties of elements going down a group or
across a period.
  • Atomic radius.
  • Ionic radius.
  • Ionization energy.
  • Successive ionization energies.
  • Electronegativity.

8
Atomic Radius
  • The distance from the center of an atoms nucleus
    to its outermost electron.
  • Atoms get larger going down a group.
  • Atoms get smaller moving from left to right
    across each period.
  • Why?

9
Ionic Radius
  • Atom loses electrons positive ion smaller.
  • Atom gains electrons negative ion larger.
  • Ion trend (Left vs. Right side).

10
Ionization Energy
  • The energy needed to remove one of an atoms
    electrons.
  • Measure of how strongly an atom holds onto its
    outermost electron.
  • Ionization energies decrease as you move down a
    group.
  • Ionization energies increase as you move from
    left to right across a period.
  • Opposite the atomic radius trends.

11
Successive Ionization Energies
  • Increases for each electron removed.
  • Large jump for noble gas inner core.

12
Electronegativity
  • Reflects the ability to attract electrons in a
    chemical bond.
  • Related to its ionization energy and electron
    affinity.
  • Increases as you move from left to right and
    decreases as you move down.

13
In Generalas you move down a family
metals melting points
boiling points Decreases as metals get
heavier nonmetals melting points
boiling points Increases as nonmetals get
heavier
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