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Ch 13: Solids and Liquids

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Title: Introductory Chemistry: A Foundation FOURTH EDITION by Steven S. Zumdahl University of Illinois Author: Richard Principe (revised by) Last modified by – PowerPoint PPT presentation

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Title: Ch 13: Solids and Liquids


1
Ch 13 Solids and Liquids
  • Ch 13 begins with notes from Ch 3.6 and 3.7 on
    Energy, Temperature and Heat.
  • We did not do these sections when in Ch 3 as the
    material is better discussed at the start of Ch
    13.

2
Ch 3.6 -- Energy, Temperature and Heat
  • Energy is the capacity to do work
  • chemical, mechanical, thermal, electrical,
    radiant, sound, nuclear
  • Energy may affect matter
  • e.g. raising or lowering its temperature will
    eventually cause a state change
  • ex solid ? liquid? gas
  • All physical changes and chemical changes involve
    energy changes

3
  • Heat a flow of energy due to a temperature
    difference
  • Heat flows from a region of higher temp to a
    region of lower temp until equilibrium is
    reached. (see fig 3.12, 3.13, 3.14 on page 67)
  • Exothermic A process that results in the
    evolution of heat.
  • Example when a match is struck, it releases
    energy as heat and light.
  • Endothermic A process that absorbs energy.
  • Example melting ice absorbs heat from the
    environment to form liquid water.

4
Ch 3.7 Calculating Energy Changes
  • Calculate the quantity of energy required for
    various processes.
  • Units
  • calorie (cal) -- is the amount of energy needed
    to raise the temperature of one gram of water by
    1C
  • A kilocalorie (kcal) 1000 cal energy needed
    to raise the temperature of 1000 g of water by
    1C
  • In nutrition, a Calorie (capital C) is equal to
    one kcal (1000 cal)
  • joule (J) the SI unit of energy
  • 4.184 J 1 cal
  • Converting J to cal (see example)

5
Energy and the Temperature of Matter
  • The temperature increase of an object depends on
    the amount of heat added (Q).
  • If the added heat energy is doubled, the
    temperature of the object will double.
  • The temperature increase of an object also
    depends on its mass
  • If the mass of the substance is doubled, it will
    take twice as much heat energy to raise the
    temperature the same amount.
  • Specific Heat Capacity (s) the amount of
    energy required to raise the temperature of one
    gram of a substance by one degree Celsius. Units
    of s J/g oC
  • Q s X m X ?T
  • Q energy (heat) required
  • s specific heat capacity of substance
  • m mass of substance in grams
  • ?T change in temperature in oC

6
Example 1 Converting calories to
joulesExample 2Calculate the amount of
heat energy (in joules) needed to raise the
temperature of 7.40 g of water from 29.0C to
46.0C
7
Example 3A 1.6 g sample of metal that appears
to be gold requires 5.8 J to raise the
temperature from 23C to 41C. Is the metal
pure gold?
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