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The Alkali Metals

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Group - 1 / A Agenda Introduction Lithium (Li) Sodium (Na) Potassium (K) Rubidium (Rb) Caesium (Cs) Francium (Fr) Introduction The elements of 1st A group are all ... – PowerPoint PPT presentation

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Title: The Alkali Metals


1
The Alkali Metals
  • Group - 1 / A

2
Agenda
  • Introduction
  • Lithium (Li)
  • Sodium (Na)
  • Potassium (K)
  • Rubidium (Rb)
  • Caesium (Cs)
  • Francium (Fr)

3
Introduction
  • The elements of 1st A group are all solid but
    soft at room temperature
  • All are shiny metals that have to be kept under
    oil or in inert atmospheres because they are very
    reactive
  • With the exception of the radio active and
    extremely rare Francium, these shiny metals react
    rapidly with oxygen in the air, so that their
    surfaces quickly become dull.
  • Caesium is the most chemically reactive of all
    the elements in this group, and spontaneously
    catches fire in air.

4
Introduction cont.
  • The atoms of this elements all have just one
    electron in there outer shell this is why they
    are so reactive.
  • All group-1 elements react violently in water
    displacing hydrogen ions to produce hydrogen gas
    (H), leaving an excess of hydroxide ions (OH-)
    in solution in the remaining water.
  • Any solution with more (OH -) than (H) ions is
    alkaline, hence the name of the group
    dissolving these elements in water results in a
    strongly alkaline solution.

5
Lithium (Li)
  • Lithium is the least dense solid element, and one
    of the most reactive metals
  • It was discovered in 1817 by Swedish chemist
    Johan Arfwedson.
  • Its atomic number is 3
  • The surface of the metal reacts slowly with
    oxygen from the air to form a dull grey layer of
    lithium oxide and hydroxide
  • Lithium compounds are used in the glass and
    ceramics industry.
  • Characteristic red light produced by a lithium
    compound
  • in a flame the light is produced by
    electrons that after
  • being excited by heat drop to a lower energy
    level.

6
Sodium (Na)
  • Sodium is the sixed most abundant element in
    Earths crust, and there are more than 10 kg of
    it, as dissolved sodium ions (Na), in every
    cubic metre of sea water.
  • Sodium metal is a soft, silvery metal similar to
    lithium, which will react violently with water,
    producing hydrogen gas.
  • Liquid sodium is used as a coolant in some
    nuclear power stations. Pure sodium is used in
    the
  • manufacture of sodium lamps (street lighting).
  • Atomic number - 11

7
Potassium (K)
  • Potassium is the seventh most abundant element in
    Earths crust
  • The pure metal is produced industrially by
    heating potassium chloride (KCl) from potassium
    bearing minerals with pure sodium vapour.
  • Potassium metal reacts violently with water
    being dripped on to it from above.
  • The three most important potassium compounds are
  • Potassium chloride (KCl)
  • Potassium nitrate (KNO3)
  • Potassium hydroxide (KOH)
  • Potassium was first discovered by English chemist
  • Humphry Davy
  • Atomic number - 19

8
Rubidium (Rb)
  • It is the sixteenth most abundant element in
    Earth s crust.
  • It was discovered in 1861 by German chemists
    Robert Bunsen and Gustav Kirchhoff.
  • Only about 3 tonnes of pure rubidium are produced
    each year
  • Rubidium melts at 39.3 Celsium it can become
    molten on a hot summer day.
  • The radioactive isotope rubidium 87 is used in
  • medicine it is absorbed into blood cells.
  • Atomic number - 37

9
Caesium (Cs)
  • Unlike other elements in Group- 1, pure cesium
    has a slide golden tinge.
  • It was discovered in 1861 by Robert Bunsen and
    Gustav Kirchhoff.
  • The name is from the Latin Caesius, meaning sky
    blue
  • Melting point 28.4 C. / Caesium can become
    liquid in a warm room.
  • Used in atomic clocks.
  • Atomic number - 55

10
Francium (Fr)
  • This is the last of the alkali metals, discovered
    in 1939 by French physicist Marguerite Perey.
  • The element was named after Pereys native
    country.
  • It has a melting point of 28 C.
  • The largest sample of francium ever prepared,
    consisting of only about 300,000 atoms was made
    by bombarding gold atoms with oxygen atoms.
  • Francium occurs naturally, probably not more than
  • a few grams at any one time in the whole
    world
  • It is the product of other radioactive elements

11
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