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CONTENTS

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Title: CONTENTS


1
POLYMERS
  • CONTENTS
  • Prior knowledge
  • Types of polymerisation
  • Addition polymerisation
  • Polymerisation of propene
  • Condensation polymerisation
  • Peptides
  • Check list

2
POLYMERS
  • Before you start it would be helpful to
  • know the functional groups found in organic
    chemistry
  • know the arrangement of bonds around carbon
    atoms
  • recall and explain electrophilic addition
    reactions of alkenes

3
POLYMERISATION
General A process in which small molecules
called monomers join together into large
molecules consisting of repeating units. There
are two basic types ADDITION all the atoms
in the monomer are used to form the
polymer CONDENSATION monomers join up the
with expulsion of small molecules not all
the original atoms are present in the polymer
4
POLYMERISATION OF ALKENES
ADDITION POLYMERISATION
Preparation Many are prepared by a free radical
process involving high pressure, high temperature
and a catalyst. The catalyst is usually a
substance (e.g. an organic peroxide) which
readily breaks up to form radicals whichinitiate
a chain reaction. Another famous type of
catalyst is a Ziegler-Natta catalyst (named after
the scientists who developed it). Such catalysts
are based on the compound TiCl4. Properties Ph
ysical varied by changing the reaction conditions
(pressure, temperature etc). Chemical have
chemical properties based on the functional
groups in their structure. poly(ethene) is
typical it is fairly inert as it is basically a
very large alkane. This means it is resistant
to chemical attack and non-biodegradable.
5
POLYMERISATION OF ALKENES
ADDITION POLYMERISATION
Process during polymerisation, an alkene
undergoes an addition reaction with itself
all the atoms in the original alkenes are used to
form the polymer long hydrocarbon chains are
formed
the equation shows the original monomer and
the repeating unit in the polymer
ethene poly(ethene)
MONOMER POLYMER
n represents a large number
6
POLYMERISATION OF ALKENES
EXAMPLES OF ADDITION POLYMERISATION
ETHENE
POLY(ETHENE)
PROPENE
POLY(PROPENE)
CHLOROETHENE
POLY(CHLOROETHENE) POLYVINYLCHLORIDE PVC
POLY(TETRAFLUOROETHENE) PTFE Teflon
TETRAFLUOROETHENE
7
POLYMERISATION OF PROPENE - ANIMATION
AN EXAMPLE OF ADDITION POLYMERISATION
PROPENE MOLECULES DO NOT ALWAYS ADD IN A REGULAR
WAY
THERE ARE THREE BASIC MODES OF ADDITION
ISOTACTIC SYNDIOTACTIC ATACTIC
Animation may not work in earlier versions of
Powerpoint
8
POLY(PROPENE)
ISOTACTIC CH3 groups on same side most desirable
properties SYNDIOTACTIC CH3 groups alternate
sided ATACTIC random most likely outcome
9
CONDENSATION POLYMERS
monomers join up the with expulsion of
small molecules not all the original
atoms are present in the polymer
Examples polyamides (nylon) polyesters (teryl
ene) peptides starch Synthesis reactions
between diprotic carboxylic acids and
diols diprotic carboxylic acids and
diamines amino acids
ESTER LINK
AMIDE LINK
10
POLYESTERS - TERYLENE
Reagents terephthalic acid HOOC-C6H4-COOH eth
ane-1,2-diol HOCH2CH2OH Equation n
HOCH2CH2OH n HOOC-C6H4-COOH gt
-OCH2CH2OOC(C6H4)CO n - n
H2O Product poly(ethylene terephthalate) Teryl
ene, Dacron Repeat unit -OCH2CH2OOC(C6H4)CO
- n Eliminated water Reaction esterification
Properties contain an ester link can be
broken down by hydrolysis the C-O bond
breaks behaves as an ester
biodegradable Uses fabrics
11
POLYAMIDES - NYLON-6,6
Reagents hexanedioic acid HOOC(CH2)4COOH hexa
ne-1,6-diamine H2N(CH2)6NH2 Equation n
HOOC(CH2)4COOH n H2N(CH2)6NH2 gt
-NH(CH2)6NHOC(CH2)4CO n- n
H2O Product Nylon-6,6 two repeating units, each
with 6 carbon atoms Repeat unit -NH(CH2)6NHOC(C
H2)4CO-n Eliminated water Mechanism addition
-elimination Properties contain a peptide (or
amide) link can be broken down by
hydrolysis the C-N bond breaks behave
as amides biodegradable can be spun
into fibres for strength Uses fibres and ropes
12
PEPTIDES
Reagents amino acids Equation
H2NCCH2COOH H2NC(CH3)COOH gt
H2NCCH2CONHHC(CH3)COOH H2O Product peptide
(the above shows the formation of a
dipeptide) Eliminated water Mechanism addition-
elimination
Amino acids join together via an amide or peptide
link 2 amino acids
joined dipeptide 3 amino acids
joined tripeptide many amino acids
joined polypeptide
a dipeptide
13
PROTEINS
polypeptides with large relative molecular
masses (gt10000) chains can be lined up with
each other the CO and N-H bonds are polar
due to a difference in electronegativity
hydrogen bonding exists between chains dotted
lines ---------- represent hydrogen bonding
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