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In-situ X-Ray Diffraction (XRD) and electrochemical characterization of cathodes for Li-Sulfur batteries Natalia A. Ca as, Kei Hirose, Norbert Wagner ... – PowerPoint PPT presentation

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Title: Folie 1


1
In-situ X-Ray Diffraction (XRD) and
electrochemical characterization
of cathodes for Li-Sulfur batteries Natalia
A. Cañas, Kei Hirose, Norbert Wagner and Seniz
Sörgel German Aerospace Center (DLR), Institute
of Technical Thermodynamics Correspondence to
natalia.canas_at_dlr.de
Results X-ray Diffraction X-ray
diffractograms of Li-S battery at various states
of charge and discharge.
Semi-quantitativ
e analysis Relative Integrated area of S8 and
Li2S Bragg peaks Rel. Integrated Intensity
() integrated intensity x y zj / integrated
intensity x y zinitial/final, j state of
charge. Electrochemical Impedance Spectroscopy
Equivalent electrical
circuit Variation of the
equivalent circuit elements during cycling
determined by EIS analysis. Average discharge
and charge capacity 1276 and 1283 Ah kgsulfur-1,
respectively.
  • Introduction
  • Lithium-sulfur batteries
  • high theoretical specific capacity
  • high energy density
  • sulfur is abundant, inexpensive and nontoxic
  • - High degradation during cycling
  • - Structural and morphological changes during
    electrochemical reactions are still not well
    understood
  • In this work
  • X-Ray Diffraction (XRD) and Electrochemical
    Impedance Spectroscopy (EIS) were applied to
    investigate the physical and chemical processes
    occurring in Li-S battery during cycling.
  • Materials and Methods
  • Sulfur cathode
  • Composition 50 wt. sulfur, 40 wt. carbon black
    and 10 wt. polyvinylidene fluoride
  • Method of preparation
    Suspension-spraying on aluminum foil.
    Solvents DMSO and ethanol 64
  • Cycling of the battery
  • Charge / Discharge Voltage (V) 2.8 / 1.5
  • Specific discharge current 300 mA/g S

Discharge
Charge
Model Chemical and physical cause
R0 Ohmic resistance
R1-CPE1 Anode charge transfer
R2-CPE2 Cathode process charge transfer of sulfur intermediates
R3-CPE3 Cathode process reaction and formation of S8 and Li2S
R4-CPE4 Diffusion
Discharge
Charge
  • Summary and conclusion
  • A suitable cell for in-situ X-ray diffraction
    analysis was designed and reaction products
    (S8 and Li2S) were monitored during cycling
    and semi-quantitatively determined.
  • An equivalent electrical circuit for the cell was
    designed and evaluated by means of EIS. Variation
    of resistance contributions were studied in
    dependence with state of charge.
  • This work highlights the importance of in-situ
    studies and the combination
    of XRD and EIS techniques to reveal new
    insights into Li-S batteries.
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