??? ?????????

1
??? ?????????  

• 2.1 ????? 2.2 ????? 2.3 ??????? 2.4 ???????
  2.5 ???? 2.6 ??????????

2
2.1 ?????

• ??(electroplating)???????????(electrodepos- ition
  process), ???
• ??(electrode)????,?????? ?????,
  ??????????????????

3
2.2 ?????

• ????????????????(deposit),????????????????????????
  ???????????? ???????????????? ??????????????
  ???????????????

4
2.3 ???????

• ???(electroplating) ????(electroless
  plating) 
• ???(hot dip plating)  ?????(spray plating) 
• ????(plastic plating) ????(immersion plating) 
• ????(diffusion plating) ????(cathode supptering)
• ??????(vacuum plating) ???? (alloy plating)
• ???? (composite plating ???? (selective
  plating) 
• ???? (through-hole plating)???(pen plating)
• ?? (electroforming) 

5
2.4 ???????

• ???????? (solution) ???,????????? ? (aqueous
  solution) ???,?? 30 ?????????????,
  ???????????Cu??Ni??Cr??Zn.?????????????????.?????
  ????????????????????????? ?????

6
?????????????

• ????
• ????
• ???
• ???
• ??????
• ????

7
??(solution)

• ???????????(solute),???????????
  ?(solute)?????????????(aqueous solution)?
• ?????,????????,????????????????(weight
  percentage)? ?????????(molal concentration)?

8
????(reaction of matter)

• ????????,??????????,?????????????,?????????,??????
  ????????????????????????????

9
???(electrochemistry)

• ????????( electrodeposition )??,????????(electrode
  )????,????????????????? ????????? ??????????????
• ???(electrolyte)?????????????? (electrolytic
  solution)????????(ions),?????????
  (movement)?????????????(anode)????????(anion),????
  ????(cathode)??(migrate)??????? cations)?
• ????????????????????(anode),??????????
  ????????(cathode)????????????(electrolysis)?

10
????(electrode potentials)

• ??(electrode potential)?????(electrolytic)?????,??
  ?????????????(electrode potential)??????????????,
  ???????????????????(standard electrode)?
• ?????(hydrogen standard electrode)????????0

11

• ?????????Nernst equation???
• EE0RT/nF ln aMn/aM  
• E????  
• E0????????(volt)  
• R????(8.3143 J.K-1MOL-1)  
• T????( K)  
• n???????(??????)  
• aMn???????(activity),???????,???????? 
• ?? ???(concentration)C???????????????,?a r
  c????????,???????1 ?  
• F??????    

12
??????(standard electrode potential)

• ??????(standard electrode potential)??????????
  1(???)?????????1???????
•  
• ? EE0 
• EE0RT/nF ln 1/1 
• E00 E0   
•  

13

• ???????????????0,??????????? (REFERENCE
  ELECTRODE),?????????0
• ????????????????????Li?? ????,????,???,???,???????
  ??(basic metal)????Au????????.????.????.?????????
  ??(noble metal)?

14

• ?? ?? ?? ??
•      Li -3.045               Co2
  -0.277    Rb
  -2.93                 Ni2 -0.250 
  K -2.924              Sn2
  -0.136  Ba2 -2.90             
      Pb2 -0.126  Sr2
  -2.90                 Fe3 -0.04  Ca2
  -2.87                  H
  0.000  Na -2.715               Sb3
  0.15    Mg2 -2.37   
             Bi3 0.20
•       Al3 -1.67                As3
  0.30    Mn2 -1.18            
  Cu2 0.34 
•       Zn2 -0.762               O2
  0.40 
•       Cr3 -0.74                 Cu
  0.52 
•       Cr2 -0.56                
  Hg22 0.789 
•       Fe2 -0.441              Ag
  0.799   

15
Nernst ????

• ???????????????,?????????,?????????,???????,??????
  ??????????????????????,???
• ??????????????????????????? (electrolatic
  solution pressure)?p?????????????
  ????????(osmotic pressure)?p,????????

16

• (1) PgtP?,?????,????,???????????,??
•      ??????????????? 
• (2) PltP?,??????????????????????,
•      ??????????,?????????  
• (3) PP?,????????

17

• ??????????????????E,?1 mole????????,??????????nF
  , n?????????,???????,F??????,???????nFE,?????
• ERT/nF ln P/P 
• ?????????(activity)? aMn?????K,?P KaMn??E -
  RT/nF ln p/KaMn
• E??????,?aMn1????????E ,? 
• E0- RT/ nF ln P/K RT/nF ln 1 -RT/nF ln P/R 

18

• ????????  
• EE0RT/Nf ln aMn / aM    ???aM???????? 

19
????????????

• ??????????????????.
•  ??Cu ltgt Cu2e- ???? ???? ?????????  
• Cu(R) ?Cu2e-  ????  
• Cu? Cu2e-   ???? 
• EE0-RT/F ln aCu/aCu

20
???????

• ?????????????????????????,????????????????????????
  ????????

21
?????(liquid junction potential)

• ?????????(diffusion potential),???????
  ???????????????,?????????? ,??????????,?????????

22
???(overvoltage)

• ??????,????????????????? ??????????,???????????,??
  ???????,???????????????????????????(polarization)
  ?????????????????????????????????????(hydrogen
  overvoltage),?????????????H2??,???????????,? ?H2E
  i-Eeq  ???H2????, Ei???? ,Eeq???? 
• ????????????????????,???????????????????????? 

23
?????????

• 1.??????(activiation overvoltage)
• 2.?????(concentration overvoltage)
• 3.???????(solution resistance overvoltage)
• 4.????????(passivity overvoltage)

24
??????

• ????,?????????????????? ,????????,???????????????
  ????,????????????,??Tafel????
• ? actab log i 
•   b???,i???, ?act??????????i??? act??,??? ?
  act??????,??????,?????????

25
?????(

• ?????,????????????????????? ????????,?????????,???
  ???,??? ?????????
• ????????????????,????,???????????????,????????,???
  ???????

26
???????

• ???????IR???,?????????IR???????????,?????IR???????
  ???
• ????????????,?????????????,???IR????????????????,?
  ???????????????

27
????????

• ????,?????????????,?A1?????,?????????,????????????
  ?????,????????????????

28
??????

• ???????,??????????,????? ??????????????????????,??
  ?????????,???????,??????? ??,?????????????????????
  ???????????????????????

29
?????????

• ????????????????,?????????????,????,???????????
  ???????????????????,??????????,?????????????????,?
  ???????????????????????? ???????,???????

30
?????

• ?????????,???????????,? ????????????????????????
  ????????????????????????????????,??????????

31
????

• ???????????????????,??? ?????????,??????????????
  ??????????????????????????????????????

32
????

• ??????????????
• ??????? ????
• ????????? ???
• ??? ??????
• ?????? ???????????
• ???? ??????
• ???? ????
• ????

33
?????????

• ????,?????????????? ??????????????
• ??????(work)???(rack)?
• ??(anode)?
• ???(bath solution)?
• ??( plating tank )???????(heating or colling coil
  )?
• ????

34
??????

• ?????????
• ????????
• ????????????
• ???????????????
• ??????????????????
• ??????????
• ???????????????????
• ???????????????????
• ??, ????????

35
???????

• ????,?????????????????????????????????????????????
  ?????????????????????????????????????,????????????
  ?????????????????????,??? ????????????????????????
  ???????????????

36
????,????(plating bath)

• ???????????????????????,??????????????????????????
  ???????pH???2???,???????????,??????????
  ???pH??25.5????,???????????pH???7???,????????????
  ?????????????

37
?????????

• ?????????????????
• ??????,????
• ????CuSO4NiSO4
• ????????,???????,
• ??????????????
• ?,????????????
• ????

38
?????????

• ????????????????,???????,???????????????????
• ????????????pH???,??pH???????,???????(pH58),pH??
  ??????
• ???????,?????????????,??????,?????,??????,???
  ???????????????????????????????
• ?????????????,???????,??????,??????????????????
• ?????????????????????????????????????????? 
• ???(wetting agent) ??????????????

39
?????

• ????????????????????????????????????,?????????????
  ??,?pH???????????????????????????

40
?????

• ?????????????,???????Hull??(Hull cell
  test)????????????,??????????????????????????,?????
  ??????????????????????????????????????????????????
  ???

41
????

• ????????????????,???????????????????????????,?????
  ???????????????????????(anode basket)??
• ????????????,??????????????,??????????,?
  ???????,?????????????????? ???

42
???(anode bag)

• ??????????????,?????????????????,???????,?????????
  ??????????????????,????????,??????,???????,???????
  ,?????????????????

43
????

• ????????????,?????????????????????,???????????????
  ??? ????????????????????????????

44
??????

• ??????,?????(pretreatment),??????
• 1.??????????????????,??????
• ????????????????????
• 2.?????????????????????
• 3.?????????????,?????????????????????????????????
  ??????
• 4.?????????,???????????????
• 5.???????????,?????

45
????(rack)

• ???????????????????,??????1.?,?????????2.??,?????
  ?????3.??,????????4.????,??????,????????????
• ?????????1.????,2.?????,3.????????,4.?????,5.?????
  ??????, 6.?????????????????,7.??????????

46
????(rack)

• ?????????
• 1.????,????????,???????,???????????
• 2.?????,?????????,????????????????????????
• 3.??,????????????,????????????????????
• 4.T????????,??????????,????????????

47
????(rack)

• ????????????
• 1.???,
• 2.??,
• 3.????,
• 4.??????,
• 5.????,
• 6.????,
• 7.????????

48
????(rack)

• ???????????????,????????
• 1.??????????
• 2.?????????????,????
• ???
• 3.???????
• 4.?????????
• 5.???????
• 6.??????,???????

49
???????????

• 1.?????? 12.????
• 2.????? 13.????
• 3.????? 14.?????
• 4.??? 15.?????
• 5.????? 16.?????
• 6.???? 17.?????
• 7.??????? 18.??????????
• 8.??? 19.????
• 9.pH??
• 10.???
• 11.???

50
??????

• ???????????????????,????????????
• 1.???(adhesion),????????????,??????????????,????
  
• (1)???????,??????????
• ????
• (2)???????????
• (3)??????????????????
• ???

51
??????

• 2.???(cohesion),?????????????,????,???????????????
  ????(1)????,????,(3)??,??????,???????????????
• 3.???(continuity),????????(pore),?????????????????
  ????,????,?????,?????

52
??????

• 4.???(uniformity),????????????????????????????????
  ??????????,?????????????????????Haring????????????
  ???Hull?????
• 5.???(appearence),???????,?????,????,?????????????
  ??????????????????,?????????????????????????????

53
??????

• 6.??(stress),???????????,??????????,????????(1)??
  ?????,(2)????,(3)?????????????????
• 7.????????????????????????????????????????

54
???????

• ?????(Faraday's Law)
• ?1???5??????5??,?????,??????100
• ????(???/(???96500))(????????)  
• W(A/(n96500))(ITCE) (63.54/(296500))(55
  6060100)31.8(g)
• ????31.8g??
• ?2??10???2.5g???NiSO?????????
• ????100?
• I( (n96500)/(A))((W)/(tCE))
• ((296500)/(58.69))((2.5)/(1060100))13.7
• ????13.7??

55
(No Transcript)