Title: BioMass Fueling our Future
1BioMass Fueling our Future
2Agenda
- History on Biofuels
- Types of Biofuels
- Current Biofuel trade Economy
- Future Economics of Biofuel trade
- Production of Biofuels
- Biofuel Technology
- Government Programs and Support
- Interesting Facts
3Millenium Development Goal 7
- Integrate the principles of sustainable
development into country policies and programmes
reverse loss of environmental resources. - Reduce by half the proportion of people without
sustainable access to safe drinking water. - Achieve significant improvement in lives of at
least 100 million slum dwellers, by 2020.
4Biofuel Drivers
- increase of security of energy supply
- reduction of dependence on fossil fuels
- reduction of greenhouse gas emissions
- reduction local air pollution
- protection of soil and groundwater through the
use of biodegradable products - reduction of health hazards by using non-toxic
products.
5Biofuel Detractors
- Drives up cost of food as corn and sugar products
are diverted into fuel tanks - Biodiesel is currently about one and a half times
more expensive than petroleum diesel fuel. - It takes energy to produce biodiesel fuel from
crops - Biodiesel fuel can damage rubber hoses in some
engines, particularly in cars built before 1994. - Biodiesel cleans the dirt from the engine. This
dirt then collects in the fuel filter, which can
clog it. Filters must be replaced frequently
initially. - Biofuels are not distributed as widely as
traditional petroleum
6Biofuel History
- Since the dawn of fire, man has used biofuels in
the form of wood and dried waste. - Nikolaus August Otto (combustion engine
inventor), originally designed his engine to run
on ethanol - Rudolf Diesel (diesel engine inventor), designed
his to run on peanut oil. Debuted at 1900 Worlds
Fair. - Henry Ford originally designed Model T to run on
pure ethanol.
7Biofuel History
- WWII brought about cheap Middle Eastern oil which
lessened the overall interest in biofuels as oil
became cheaper and more abundant - Through the decades interest has waxed and waned
as the price and availability of oil has
fluctuated. - Recently the rising cost of oil, global warming
and government awards has renewed the interest in
the biofuel industry.
8Various Types of Biofuels
- Biodiesel
- Ethanol
- Vegetable oils
- Alcohols (Butanol, methanol, and other blends)
- Biohydrogen
9Biofuel Yields
10Biodiesel
- How is biodiesel made?Biodiesel is made through
a chemical process called transesterification
whereby the glycerin is separated from the fat or
vegetable oil. The process leaves behind two
products -- methyl esters (the chemical name for
biodiesel) and glycerin (a valuable byproduct
usually sold to be used in soaps and other
products). - Understanding Blending Blending is the process
by which biodiesel is mixed with petroleum-based
fuel. In its purest form, biodiesel is signified
as a B100 blend (100 biodiesel). Blending can be
achieved at any percentage. A B10 blend simply
means that the fuel contains 10 biodiesel and
90 petrol-diesel. - Biodiesel is biodegradable and non-toxic, and
typically produces about 60 less net carbon
dioxide emissions than petroleum-based diesel, as
it is itself produced from atmospheric carbon
dioxide via photosynthesis in plants.
11Biodiesel Description
- Golden to dark brown in color
- High boiling point
- Low vapor pressure
- Immiscible to water
- Viscosity similar to petroleum
- Flash point 150 C
- Pure Biodiesel is non toxic.
- Higher lubricity index than diesel (extends
injector life)
12Biodiesel Feedstock
- Rapeseed
- Soybean
- Jatropha
- Sunflower
- Palm oil
- Canola
- Waste vegetable oil
- Virgin oil feedstock
- Animal fats
- algae
- Sewage (A company in New Zealand has successfully
developed a system for using sewage waste as a
substrate for algae and then producing
bio-diesel)
13World Biodiesel Production
14Jatropha
- natively occur in tropical areas, India, Africa,
North America, and the Caribbean. - resistant to drought and pests
- produces seeds with up to 40 per cent oil content
15Jatropha
- When the seeds are crushed, the resulting
jatropha oil can be used in a standard diesel
car, while the residue can also be processed into
biomass to power electricity plants - The plant can grow in wastelands, fertilizes the
soil that it grows in, and yields more than four
times as much fuel per hectare as soybean more
than ten times that of corn. A hectare of
jatropha produces 1,892 liters of fuel (about 6.5
barrels per acre)
16Rape Seed
- Also known as Canola, Rapa, and oilseed rape.
- Rapeseed oil is the preferred oil stock for
biodiesel production in most of Europe, partly
because rapeseed produces more oil per unit of
land area as compared to other oil sources, such
as soy beans.
17Rape Seed
- Rapeseed derived biodiesel cost more to produce
than standard diesel fuel. Prices of rapeseed oil
are at very high levels presently (start November
05) due to increased demand on rapeseed oil for
this purpose.
18Ethanol
- Ethanol is "an alcohol product produced from
corn, sorghum, potatoes, wheat, sugar cane, even
biomass such as cornstalks and vegetable waste.
When combined with gasoline, it increases octane
levels while also promoting more complete fuel
burning that reduces harmful tailpipe emissions
such as carbon monoxide and hydrocarbons."
(Abengoa Bioenergy)
19Ethanol
- Its oxygen content helps gasoline burn more
efficiently, cutting tailpipe pollutants
including carbon monoxide and benzene. E10 can
cut carbon monoxide emissions by 20, benzene
emissions by 25 and overall gasoline toxicity by
30. - Over 99 of fuel ethanol in the US is consumed as
E10, a 10 blend with gasoline. But E85, an 85
blend, is beginning to emerge. The big three US
automakers annually sell around 250,000 flexible
fuel vehicles capable of running on E85 at no
added cost to buyers.
20Ethanol Producing Countries
21Biofuels Pump
- B20 20 blend of biodiesel and diesel
- E85 85 blend of gasoline with ethanol
- E10 10 blend of gasoline and ethanol
22Comparisons
23Vegetable Oils
- Grease Cars typically duel fuel system cars of
both vegetable oil and diesel. - Can be used to both fuels vehicles and heat
homes. - Makes use of filtered waste vegetable oil (WVO)
and straight vegetable oil (SVO) - Should not be used in colder climates without a
heating system.
24Alcohols (Butanol Methanol)
- Due to similar molecular structure of alcohol,
Butanol is more similar to gasoline than ethanol
is. - Butanol has been demonstrated to work in some
vehicles designed for use with gasoline without
any modification. - Methanol is currently produced from natural gas,
a fossil fuel. It can also be produced from
biomass. - Oils are mixed with sodium hydroxide and methanol
(or ethanol) and the chemical reaction produces
biodiesel (FAME) and glycerol. 1 part glycerol is
produced for every 10 parts biodiesel. - Glycerol can then be used
- Medicine and pharmaceutical technology
(lubricants, cough syrups, laxatives, and
dessicants) - Personal care (toothpaste, mouthwash, soaps,
deodorants) - Foods and beverages (solvent, sweetners, food
preservatives.) - Feed
- And much more
25Biohydrogen
- Hydrogen produced from biomass feedstock.
- Principle comes from manipulating plants such as
algae and growing them in conditions that is
photosynthesizes hydrogen from the water - Most often used in fuel cells to produce
electricity.
26Small Scale Biodiesel Operation
- Materials needed
- Oil (seed oil, waste oil, etc can usually be
obtained for free from many restaurants) - Chemicals (Lye, Methanol 0.50/gallon)
- Containers (12 /5 gallon polyethylene resin
container) - Freedom Fueler Deluxe Biodiesel kit (4500,
produces 80 gallons in 24 hours 110v/220V) - Processing costs is about 0.70 a gallon)
27Savings
- Buying 100 gallons of diesel 2 monthly at 3 a
gallon costs 300 - Assuming a 0.70 processing cost.
- By making our own we will save 2.30 a gallon or
230 a month if we use 100 blending. Break even
would be at 20 months for kit price - Using a 20 blend the savings are reduced to
46.00. Break even would be at 8.1 years for
kit price - The glycerin byproducts can be composted back
into the soil or crops used to grow the oil
producing plants.
28Growing Seed Oil for Coop
- We choose to use Jatropha since it is a hardy
plant, and native to most of the world. - Its ability to grow in a range of soils makes it
ideal as a seed oil crop. - Since it is toxic to animals, we dont have to
worry about livestock consuming the plants. - It is also drought and pest resistant
- The biomass residue left after seed pressing can
then be used to power electricity plants. - It also serves to regenerate topsoil and stall
erosion - It absorbs carbon dioxide as it grows, thus
making it carbon-neutral even when burnt. - A jatropha bush can live for up to 50 years,
producing oil in its second year of growth, and
survive up to three years of consecutive drought.
29Jatropha Coop Land
- Every hectare can produce 5500 gallons per
hectare of oil (2.7 tons/hectare) and about 4
tons of biomass. Every 8,000 hectares of the
plant can run a 1.5 megawatt station, enough to
power 2,500 homes. - Community farmers could use micro lending
agencies to purchase the equipment and 5 hectares
of land per farmer to form cooperatives. - Assuming 20 farmers to a coop, this gives 100
hectares of jatropha fields yielding a total of
550,000 gallons of oil annually.
30Cost / Savings
- The cost of cultivation depends upon labor
availability and comes around US 550 per
hectare, or 55,000 annually for 100 hectares. - The cost maintenance of plantation is around US
100-120 per year per hectare, or 12000 annually
for 100 hectares - The cost of oil extraction roughly comes about US
0.12 / kg or 109 per ton. This gives
294,000 for 100 hectares of oil extraction. - Total cost is 361,000 annually for the coop.
- 550,000 gallons produced annually means that the
cost is about 0.66/gal (This comes very close to
the 0.70 figure for processing previously) - Given the 3/gal cost today, that is a savings of
457 or 2.34/gal. The total savings is 1.28
million dollars a year.
31Coop Equipment and Land
32Time Scale
- TIMINGBiodiesel typically takes a couple of days
to a week from start to finish to make a batch.
Most people making biodiesel make anywhere
between 20 to 100 gallons at a time in a batch
process. - Here's a breakdown of typical timing intervals
from start to finish - START
- Collecting Oil - 1-2 hours
- Filtering Oil - 1-2 hours (depends on amount of
oil) - Titration Of Oil - 10-15 minutes
- Transferring Oil To Processor - 10-20 minutes
- Heating Oil - 1-4 hours (depends on amount of
oil, voltage wattage of element) - Making Methoxide - 5-20 minutes (depends on
amount of methanol and catalyst used) - Mixing Methoxide Into Oil - 20-30 minutes
- Mixing Oil Methoxide - 2-3 hours
- Settling Oil - 8-10 hours (usually overnight)
- Draining Glycerine - 5-10 minutes
- Transferring Biodiesel To Wash Tank - 10-20
minutes - First Mist Wash - 2-3 hours
- Second Mist Wash - 2-3 hours
- First Bubble Wash - 6-8 hours (usually overnight)
- Second Bubble Wash - 6-8 hours (usually
overnight) - Transferring Biodiesel To Drying Containers -
10-20 minutes (depends on amount)
33Current trade economy
- Brazil Sugar Cane (Ethanol)
- India jatropha (Bio diesel)
- United States Soy and Corn (Bio diesel)
- Alaska Fish oils (Bio diesel)
- Haiti jatropha (Bio diesel)
- Costa Rica Crude Palm oil (Bio diesel)
- Europe/Aisa Rapseed (Bio diesel)
34Government Aid and Support
- U.S. Dept. of Energy has awarded 375 million
for bioenergy research centers. - A 2006 reports by Global Subsidies Initiative
(GSI) estimates that subsidies to biofuels are
between 5.5 billion and 7.3 billion a year - Governments around the world continue to show
their support for increased use of bioethanol,
with recent initiatives coming from Australia,
Japan and the world's fastest growing economy,
China.
35Brazilian Biofuel
- Mid-1980s were a major success for mass
producing biofuels and motor vehicles - Farmers payed generous subsidies to grow sugar
cane for ethanol - Higher sugar prices and newly discovered offshore
oil caused backlash in the 1990s.
36India Biofuels
- Two major sources
- Biodiesel primarily from Jatropha seed oil
- Ethanol Corn and cane sugar
- Since the usage of ethanol sources diverts food
into gas tanks, and sends corn prices
skyrocketing, jatropha (a non edible plant) is
gaining a lot of headway in the biodiesel section
37United States Biofuels
- Primary Biofuel is Ethanol
- The current ethanol industry traces its origins
back to the oil shocks of 1973 and 1979 that
caused the initial interest in renewable energy
sources. - In 1990 the Clean Air Act (CAA90) created a new
source of demand for ethanol in the US. - In response to CAA90, US ethanol production
tripled from 1 billion gallons in 1990 to 3
billion gallons by 2003. - Corn is the largest feedstock used in ethanol
production accounting for 90 of all ethanol
production.
38Ethanol Geography
39US Ethanol Capacity
40Ethanol by State
41Oregon Biofuels
- Ethanol currently comprises 4 of Oregons
gasoline supply. - Oregon Governor Ted Kulongoski signed legislation
in July 2007 that will require all gasoline sold
in the state to be blended with 10 bioethanol (a
blend known as BE10) and all diesel fuel sold in
the state to be blended with 2 biodiesel (a
blend known as BD2). - Imports from the Midwest supply most Northwest
ethanol consumption. According to Federal Highway
Administration figures, 33 million gallons are
blended into Washingtons 2.6 billion gallon per
year gasoline consumption. Oregon blends 14
million gallons of ethanol into its annual
gasoline consumption of 1.5 billion gallons.
42Oregon Biofuel Legislation
- 7 bills are pending.
- Provides incentives to produce biofuels in Oregon
(HB 3030, SB 736) - Provides incentives to utilize Oregon crops (HB
3031, HB 3032) - Sets a renewable fuel standard for gasoline and
diesel (HB 3033) - Expands markets for biodiesel (HB 3034)
- Cleans up diesel school buses with biodiesel (HB
3035)
43Haiti Biofuels
- Jatropha Biofuel production is in its infancy
still - Big push underway to establish small scale
jatropha operations in the villages. - Farmers can utilize micro credit loans to
purchase Kick Start presses to run their
jatropha farms. - Village generators can run independently of power
grids on jatropha seed oil.
44Costa Rica
- Primary Biomass
- Sugar Cane
- Palm Oil
- Jatropha
- Palm Oil can produce up to 5000 litres per acre
(1100 gallons) - Costa Rica announced it's plans to become the
world's first carbon neutral country by 2030.
Five teams will drive 4,500 miles on grease power
from the USA to Mexico, Guatemala, Honduras,
Nicaragua and Costa Rica.
45Asia
- Biodiesel the most prominent resulting from
- Rapeseed
- Palm oil
- Cassava
- Ethanol is also gaining ground most notably in
Cellulosic Ethanol - China which led the major drive across its cities
in use of biofuels for transportation, with
ambitious plan of increasing the present 1
million tons of ethanol and biodiesel last year
to 12 million tones in 2020. Japan has also
followed suit with goals of supplementing
traditional fuels with bioethanol by 2010.
46Malaysia
- Malaysia has already begun preparations to change
from diesel to bio-fuels by 2008, including
drafting legislation that will make the switch
mandatory. From 2007, all diesel sold in Malaysia
must contain 5 palm oil. Being the world's
largest producer of crude palm oil, Malaysia
intends to take advantage of the rush to find
cleaner fuels.
Newly Started Palm Oil Plantation
47Europe
- The European biofuel sector is made up of two
distinct sectors - Ethanol Obtained from fermenting beets, corn,
barley or wheat, which are used for their sugar
content that can be transformed into alcohol. - Biodisel Biodiesel (or FAME fatty acids methyl
ester) is produced from rapeseed or sunflower for
use as an additive to diesel fuel. - Combined European production (EU-15) of both of
these sectors represented 1,743,500 tons
(equivalent to 1,488,680 toe) in 2003, with a
strong prominence of biodiesel which represents
82.2 of European biofuel production. The overall
figures represent a growth of 26 with respect to
2002 - EU has set a goal that by 2010 each member state
should have at least 5.75 biofuel usage for
traffic fuel and 10 by 2020.
48EU vs. World
49EU Production
50OPEC Oil
51Hydrocarbon Projections
52Future Trade Impacts
- In terms of Economics, OPEC currently dominates
the world with their 50 trillion dollar oil
profits (not excess!!!) - However as oil production peaks in 2010 and
starts to decline through 2050, those profits
will also begin to dwindle. - This will bring about a new world super power in
terms of fuel economics and power. - Currently India and South America lead the way in
the production of alternative biofuels and
continue to grow their production and technology. - If nothing is done to change the current status
the OPEC group will lose their grip on the fuel
leader of the world as Indian and South America
take over
53Future Trade Impacts
- Since OPEC currently has a projected profit of
50 trillion over the next 15 years, their best
bet would be to invest part of that (after the
EDGE students get their cut to reforest the
world) in the Indian and South American companies
producing alternative fuels or the creation of
their own. (Jatropha can grow in deserts!) - Europe, Asia, and the US would be the next major
biofuel players behind India and South America.
54Future Trade Impacts
- The scarcity of land for OECD (Organization for
Economic Co-operation and Development) countries
presents a problem in the biofuel world. - This would increase international trade with
those tropical and sub tropical countries who
have the potential for production due to better
climates, land and infrstructure.
55Future Trade Impacts
- There is currently no standard classification of
Biofuels at the WTO level - Ethanol generally classified as agricultural
- Biodiesel classified as industrial
- This difference is important because the rules
differ based on agricultural versus industrial as
far as market access and subsidies - Lack of International Standards and
Certifications - These barriers have limited the emergence of a
global market in biofuels, but over the next few
decades, pressure to reduce these barriers or
eliminate them altogether will increase immensely.
56Interesting Facts
- Biodiesel improves domestic energy security. By
using domestically produced, renewable fuels like
biodiesel, the United States can reduce
dependence on foreign countries for oil.
Biodiesel has the highest energy balance of any
fuel, further increasing its value in our energy
portfolio. Every unit of fossil fuel it takes to
make biodiesel results in 3.2 units of energy
gain. Since petroleum diesel has a negative
energy balance of .88, every gallon of biodiesel
used has the potential to extend our petroleum
reserves by four gallons.
57Interesting Facts
- You can run any diesel engine on restaurant's
used vegetable oil. - Any Diesel engine after '94 needs no alterations
to its engine in order to make such a conversion. - Any diesel engine before '94 just needs new
tubing for the gas line so that the oil does not
corrode the fuel lines. - Any blend of biodiesel and fossil fuel diesel can
be used in a diesel engine without fear of any
engine flaws. - Biodiesel also extends the life of your engine by
20 because it naturally lubricates the engines
moving parts cutting down on the friction
created. Also, less friction means less heat
which in turn will reduce the frequency of heat
related breakdowns. - Burning vegetable oil smells like hot donuts
cooking in your engine block.
58Energy Needs
- Can biofuels replace and meet our Energy needs?
- Growing biofuel on 100 of the world's farmland
would only provideabout 20 of the energy
produced each year from crude oil - ..Its a start though.
59Biofuel Yields
60World Deforestation
- Ryan Canady
- EDGE Summer 2007
61Annual Deforestation Rates 2000-2005 (x1000
Factor)
Rhett A. Butler / mongabay.com
62Year 2000 Summary
Rhett A. Butler / mongabay.com
63Deforestation Rates (x1000)
Rhett A. Butler / mongabay.com
64World Contributions
Rhett A. Butler / mongabay.com
65Carbon Emissions (per capita per country)
Rhett A. Butler / mongabay.com
66Global CO2 Emissions in Tons (in Millions)
67Reforesting Efforts
- Planting the wrong kind of trees, such as
monocultures of eucalyptus or pine where they are
not native species, can devastate the lands of
the local people. - A practical solution is to plant tough,
fast-growing native tree species which begin
rebuilding the land - Reforestation, if several native species are used
can provide other benefits in addition to
financial returns, including restoration of the
soil, rejuvenation of local flora and fauna, and
the capturing and sequestering of 38 tonnes of
carbon dioxide per hectare per year
68Worldly Data
- Total Average Deforested per year 12,599,000
Hectares - 2000-2005 Deforestation 62,995,000 Hectares
- Carbon Sequestration from Native Species 38
tonnes per hectare per year - Total Sequestration potential over 5 years
2,393,810,000 tonnes.
69Reforestation Rates 2000-2005 (x1000 factor)
Rhett A. Butler / mongabay.com
70Costs
- Mitigation costs through forestry can be quite
modest (US0.1US20 / metric ton carbon dioxide)
in some tropical developing countries - As little as 90 US will plant 900 trees, enough
to annually remove as much carbon dioxide as is
annually generated by the fossil-fuel usage of an
average United States resident
71Carbon Sequestration Diagram
72US Sequestration
- In the United States in 2004 (the most recent
year for which EPA statistics are available),
forests sequestered 10.6 of the carbon dioxide
released in the United States by the combustion
of fossil fuels. Urban trees sequestered another
1.5 To further reduce U.S. carbon dioxide
emissions by 7, as stipulated by the Kyoto
Protocol, would require the planting of "an area
the size of Texas 8 of the area of Brazil
every 30 years", according to William H.
Schlesinger, dean of the Nicholas School of the
Environment and Earth Sciences at Duke
University, in Durham, N.C.. Carbon offset
programs are planting millions of fast-growing
trees per year to reforest tropical lands, for as
little as 0.10 per tree over their typical
40-year lifetime, one million of these trees will
fix 0.9 teragrams of carbon dioxide
73What are we doing?
- ABB (Power and Automation Technologies) built the
worlds first commercial CO2 capture facility at
its Shady Point, Oklahoma coal-fired power plant.
It captures 200 tons of CO2 a day from the
plants flue gas, which is purified, liquefied,
and sold to the food products industry (Soda,
Soda water, Pop Rocks, Baking powder...) - AEP (American Electric Power), under DOEs
Climate Challenge Tree Planting Project, has
planted 21,914 acres with nearly 19 million mixed
hardwood and conifer trees at a cost of
approximately 5.7 million. Projected CO2
sequestration is 4.7 million metric tons over the
term of the project. In a separate initiative in
Louisiana, AEP has planted 9,784 acres with
nearly 3 million bottomland hardwood trees at a
cost of 6.25 million. Projected carbon
sequestration is over 4.4 million metric tons. - Royal Dutch/Shell is a member of the CO2 capture
project CO2 Capture Research Project, an
international effort by seven of the worlds
leading energy companies.
74What are we doing?
- Pacific Gas and Electric Company has submitted a
proposal to the California Public Utilities
Commission (CPUC) for a new and innovative
environmental program that will allow interested
customers to contribute toward a cleaner
California. This voluntary program would be
available to most of PGEs residential and
business customers. - Through the Climate Protection Program,
customers can choose to sign up and pay a small
premium on their monthly utility bill which will
fund independent environmental projects aimed at
removing carbon dioxide from the air. To read
more about this program, click here. - In 2004 Weyerhaeuser improved its process for
inventorying GHG emissions and the carbon stored
in its forests and products. The companys
operations sequestered approximately 26 million
metric tons of carbon dioxide equivalents and
emitted approximately 7 million tons from the use
of fossil fuels and other activities. This
effectively sequestered 19 million metric tons of
carbon dioxide equivalent or 0.5 metric tons of
carbon equivalents per ton of production, an
improvement of approximately 18 over 2003.
75Value of Remaining OPEC Oil
- 913 Billion Barrels 913,000,000,000
- Average cost of extraction 15 to 20/barrel
- Expected Price on Market 75/barrel
- Scarcity Profit 55 x 913,000,000,000
- 50,215,000,000,000 50.215 trillion (on
remaining reserves) - If spread over 15 years it will be about 3.347
trillion/year - World population 6.6 billion
- Oil Profit 507 for/from each person on earth
per year. - Referened from EDGE Summer 07 Lecture 04 B.
Lusignan
76Cost of CO2
- At a cost of 90 for 900 trees that will absorb
30 tons of CO2 annually, this gives the cost of
3/ton. - 125,128,600,000 worldwide tons of CO2 annually
multiplied by 3 a ton 375.6 billion to
sequester the annual CO2 emmissions. - OPEC profits are 50.215 trillion (on remaining
reserves) - A contribution from OPEC of 375.6 billion /
50.125 trillion or 0.74798 of their profits
could reforest enough of the world to account for
annual CO2 emmissions.
77References
- Wikipedia
- Greasecar.com
- www.bbc.co.uk
- www.laughlinoil.com
- www.biodiesel.org
- www.soygrower.com
- www.saabbiopower.co.uk
- www.mongabay.com
- www.ecoworld.com
- www.jatrophabiodiesel.org
- Bruce Lusignan, EDGE lectures, 2007
- The Structure and Outlook for the US Biofuels
Industry Informa Economics, Inc October 2005
(www.in.gov) - Implications of a Future Global Biofuels Market
for Economic Development and International Trade
Henry Lee, William Clark, Robert Lawrence, Gloria
Viscount Harvard University, May 09,2007