Title: Whats the Matter
1Whats the Matter?
Interest Grabber
Section 2-1
- All of the materials around you are made up of
matter. You are made up of matter, as are the
chair you sit on and the air you breathe. - 1. Give an example of solid matter.
- 2. Give an example of liquid matter.
- 3. Give an example of gaseous matter.
- 4. Is all matter visible?
- 5. Does all matter take up space?
2Section Outline
Section 2-1
- 21 The Nature of Matter
- A. Atoms
- B. Elements and Isotopes
- 1. Isotopes
- 2. Radioactive Isotopes
- C. Chemical Compounds
- D. Chemical Bonds
- 1. Ionic Bonds
- 2. Covalent Bonds
- 3. Van der Waals Forces
3- Matter anything that occupies space and has
mass - Mass measure of the amount of matter in an
object
4 States of Matter
- Solid particles tightly linked, vibrate, fixed
shape and volume - Liquid particles more loosely linked, greater
movement of particles, takes shape of container,
fixed volume
5- Gas particles have little or no attraction to
each other, move most rapidly, fill volume of
container
6- A. Atom smallest particle of matter that can
exist and still have the properties of a
particular kind of matter (element) - Elements and Isotopes
7- Element substance consisting entirely of one
type of atom - Isotopes atoms of the same element have the
same number of protons but the number of neutrons
varies
8- Radioactive isotopes isotopes with unstable
nuclei the atoms break down at a constant rate
over time
9Structure of Atoms
- Nucleus in atoms, the center, which contains
protons and neutrons and accounts for 99.9 of
the atoms mass - Proton positively charged subatomic particle
located in the nucleus
10- Neutron subatomic particle that is electrically
neutral and is located in the atomic nucleus - Atomic number number of protons in the nucleus
of an atom identifies each element
11- Electron negatively charged subatomic particle
located outside the atomic nucleus - high energy particles with very little mass
- move rapidly around nucleus at different levels
12- outer level electrons have more energy
- 1st level holds up to 2 electrons
- 2nd level holds up to 8 electrons
13An Element in the Periodic Table
Section 2-1
6
C
Carbon
12.011
14(No Transcript)
15Figure 2-2 Isotopes of Carbon
Section 2-1
Nonradioactive carbon-12
Nonradioactive carbon-13
Radioactive carbon-14
6 electrons 6 protons 6 neutrons
6 electrons 6 protons 8 neutrons
6 electrons 6 protons 7 neutrons
16C. Chemical Compounds
- Compound a substance formed by the chemical
combination of two or more elements in definite
proportions
17- Eg H2O formula for water in a 21 ratio of
hydrogen to oxygen - H2SO4 formula for sulfuric acid in a 214
ratio of hydrogen to sulfur to oxygen
18D. Chemical Bonds
- 1. Ionic bond chemical bond that involves the
transfer of electrons a bond formed by
electrical attraction between two oppositely
charged ions
19Figure 2-3 Ionic Bonding
Section 2-1
Sodium atom (Na)
Chlorine atom (Cl)
Sodium ion (Na)
Chloride ion (Cl-)
Transfer of electron
Protons 11 Electrons -11 Charge 0
Protons 17 Electrons -17 Charge 0
Protons 11 Electrons -10 Charge 1
Protons 17 Electrons -18 Charge -1
20Figure 2-3 Ionic Bonding
Section 2-1
Sodium atom (Na)
Chlorine atom (Cl)
Sodium ion (Na)
Chloride ion (Cl-)
Transfer of electron
Protons 11 Electrons -11 Charge 0
Protons 17 Electrons -17 Charge 0
Protons 11 Electrons -10 Charge 1
Protons 17 Electrons -18 Charge -1
21 Ionic Bonding
22(No Transcript)
23(No Transcript)
24(No Transcript)
25- 2. Covalent bond chemical bond formed by two
atoms sharing one or more pairs of electrons - Molecule two or more atoms covalently bonded
26 Covalent Bonding
273. Van der Waals Forces
- A slight attraction that develops between the
oppositely charged regions of nearby molecules
28Water, Water Everywhere
Interest Grabber
Section 2-2
- If you have ever seen a photograph of Earth from
space, you know that much of the planet is
covered by water. Water makes life on Earth
possible. If life as we know it exists on some
other planet, water must be present to support
that life.
29Interest Grabber continued
Section 2-2
- 1. Working with a partner, make a list of ten
things that have water - in them.
- 2. Exchange your list for the list of another
pair of students. Did your lists contain some of
the same things? Did anything on the other list
surprise you? - 3. Did either list contain any living things?
30Section Outline
Section 2-2
- 22 Properties of Water
- A. The Water Molecule
- 1. Polarity
- 2. Hydrogen Bonds
- B. Solutions and Suspensions
- 1. Solutions
- 2. Suspensions
- C. Acids, Bases, and pH
- 1. The pH Scale
- 2. Acids
- 3. Bases
- 4. Buffers
31 A. The Water Molecule
- 1. Polarity
- H and O atoms are covalently bonded
- O with 8 protons has a greater charge than H
with only 1 proton
32- O pulls shared electrons toward its nucleus due
to the greater charge attracting the
electrons - Electrical charge is not evenly distributed
33- The O region is weakly negative
- The H regions are weakly positive
- Water is a polar compound due to the uneven
distribution of charges.
34- This makes it a good solvent for other polar
compounds such as sugar, some proteins - Also good at dissolving ionic compounds such as
NaCl
35http//www.luminet.net/wenonah/hydro/h2o.htm
36http//www.luminet.net/wenonah/hydro/h2o.htm
37 2. Hydrogen bonds
- Because water is polar, the molecules are
attracted to one another. - 2 water molecules are held together by hydrogen
bonding - A hydrogen bond is formed
38- between the hydrogen region of one molecule and
the oxygen region of another molecule - Hydrogen bonds are weak and easily broken
39- H bonds cause water to stick to itself and other
substances. - Cohesion attraction of like molecules to each
other - Ex surface tension of water
- Adhesion attraction of unlike substances to
each other
40- Adhesion cohesion together let water exhibit
capillary action - Capillary action the reaction of a liquid
surface with a solid lets water move up the
inside of a narrow tube against gravity
41Solutions and Suspensions1. Solutions
- Mixture two or more elements or compounds
physically mixed together but not chemically
combined
42- Solution - a mixture in which one or more
substances are uniformly dissolved in another
substance - Solute a substance dissolved in a solution
43- Solvent in a solution, the substance in which a
solute is dissolved - Ex water universal solvent
- Concentration measurement of the amount of
solute dissolved in a fixed amount of solution
44- Saturated solution one in which no more solute
can dissolve - Aqueous solutions solutions with water as the
solvent water is the universal solvent
452. Suspensions
- Mixture of water and nondissolved materials the
nondissolved materials have particles so small,
they do not settle out
46C. Acids, Bases, and pH
- 1. The pH Scale to show the concentration of H
(hydrogen) ions in solution - OH- is a hydroxide ion.
47pH scale potential hydrogen scale
- The pH scale is logarithmic.
- A change of one pH unit a 10X change in the
strength of the acid or base.
48- The higher the above 7, the stronger the base.
- The lower the below 7, the stronger the acid.
- 7 is neutral
492. Acids
- A compound that forms hydrogen ions H in
solution - Have higher concentrations of hydrogen ions than
pure water - pH is below 7
50- Dissociation breaking apart of water molecule
into 2 ions of opposite charge - H2O ? H OH-
513. Base
- A compound that makes hydroxide ions (OH-) in
solution - Bases have lower concentrations of H ions than
pure water - Bases have a pH above 7
524. Buffer
- Weak acid or base that can react with strong
acids or bases to help prevent sharp, sudden
changes in pH
53pH Scale
Section 2-2
Oven cleaner
Bleach
Ammonia solution
Increasingly Basic
Soap
Sea water
Human blood
Neutral
Pure water
Milk
Normal rainfall
Acid rain
Increasingly Acidic
Tomato juice
Lemon juice
Stomach acid
54Figure 2-9 NaCI Solution
Section 2-2
Cl-
Cl-
Na
Na
Water
Water
55Figure 2-9 NaCI Solution
Section 2-2
Cl-
Cl-
Na
Na
Water
Water
56Lifes Backbone
Interest Grabber
Section 2-3
- Most of the compounds that make up living things
contain carbon. In fact, carbon makes up the
basic structure, or backbone, of these
compounds. Each atom of carbon has four electrons
in its outer energy level, which makes it
possible for each carbon atom to form four bonds
with other atoms. - As a result, carbon atoms can form long chains. A
huge number of different carbon compounds exist.
Each compound has a different structure. For
example, carbon chains can be straight or
branching. Also, other kinds of atoms can be
attached to the carbon chain.
57Interest Grabber continued
Section 2-3
- 1. On a sheet of paper, make a list of at least
ten things that contain carbon. - 2. Working with a partner, review your list. If
you think some things on your list contain only
carbon, write only carbon next to them. - 3. If you know other elements that are in any
items on your list, write those elements next to
them.
58Section Outline
Section 2-3
- 23 Carbon Compounds
- A. The Chemistry of Carbon
- B. Macromolecules
- C. Carbohydrates
- D. Lipids
- E. Nucleic Acids
- F. Proteins
5923 Carbon CompoundsA. The Chemistry of Carbon
- Organic chemistry - study of compounds that
contain carbon and are usually associated with
living things most organic compounds have bonds
between carbon atoms
60- Carbon - Carbon bonds can be single, double, or
triple covalent bonds
61B. Macromolecules
- Means giant molecules
- Made from thousands or hundreds of thousands of
smaller molecules
62- Formed by polymerization
- Smaller units, monomers, join together to form
polymers
63- Biomolecules (organic molecules found in living
things) include carbohydrates, lipids, proteins,
and nucleic acids
64Concept Map
Section 2-3
Carbon Compounds
include
that consist of
that consist of
that consist of
that consist of
which contain
which contain
which contain
which contain
65Carbon is Unique!
- Forms a variety of covalent bonds that are strong
and stable - Has 4 electrons in its second energy level
- Can form 4 single covalent bonds
66- Can also form double and triple bonds
- Can form long chains by bonding with other carbon
atoms - Can form rings
67C. Carbohydrates
- Made up of carbon, hydrogen, and oxygen with the
monomer in the ratio of 121 - Hydrogen and Oxygen are in a 21 ratio in all
carbohydrates
68- Carbohydrates are the main sources of energy for
living things - Plants and some animals also use carbohydrates
structurally
69Monosaccharides
- Single sugar molecules
- Chemical formula C6H12O6
- Ex glucose, fructose, galactose
70Isomers
- Have the same chemical formula but different
structural formula
71Structural formula for glucose
http//www.borg.com/lubehawk/biochem.htm
72Monosaccharide Isomers C6H12O6
http//www.purchon.com/biology/sugars.htm
73Dehydration Synthesis
- Monosaccharides are combined to form larger
molecules by a process of polymerization - A bond forms between each simple sugar at the OH
groups
74- A water molecule is removed where the bond forms
between the 2 monosaccharides - Since an HOH is pulled out, or one water
molecule, the process is called dehydration
synthesis
75Dehydration Synthesis
- Reaction in which small molecules join to form a
large molecule, removing water in the process - Dehydration means loss of water
- Synthesis means putting together
76Disaccharides
- form as a result of dehydration synthesis
between 2 monosaccharides (ex maltose,
sucrose)
77http//www.purchon.com/biology/sugars.htm
C12 H22O11, sucrose, formed as a result of
dehydration synthesis This is table sugar.
78http//homepages.ius.edu/GKIRCHNE/biomolec.htm
79http//faculty.clintoncc.suny.edu/faculty/Michael.
Gregory/files/Bio20101/Bio2010120Lectures/Bioch
emistry/biochemi.htm
80- Sucrose
-
- This is called a condensation or dehydration
synthesis reaction
http//faculty.clintoncc.suny.edu/faculty/Michael.
Gregory/files/Bio20101/Bio2010120Lectures/Bioch
emistry/biochemi.htm
81Hydrolysis
- A catabolic reaction that splits apart larger
molecules into smaller ones with the consumption
of water - Hydrolysis means water splitting
82Hydrolysis
http//campus.northpark.edu/biology/cell/chemreact
.html
83Polysaccharides
- 3 or more connected monosaccharides (ex starch,
glycogen, chitin, cellulose - Animals store excess sugar in the form of the
polysaccharide glycogen
84- Plants store excess sugar in the form of the
polysaccharide starch - Cellulose, another polysaccharide is used by
plants for strength and rigidity
85Figure 2-11 Carbon Compounds
Section 2-3
Methane
Acetylene
Butadiene
Benzene
Isooctane
86THE DEHYDRATION SYNTHESIS OF MALTOSE FROM TWO
GLUCOSE MOLECULES
THE DEHYDRATION SYNTHESIS OF MALTOSE FROM TWO
GLUCOSE MOLECULES Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â
                                                 Â
                                                 Â
                                                 Â
                                                 Â
                                                 Â
                                         Â
http//www.borg.com/lubehawk/biochem.htm
87Figure 2-13 A Starch
Section 2-3
Starch
Glucose
88D. Lipids
- Not soluble in water
- Contain many carbon and hydrogen atoms, and a few
oxygen atoms - Can store energy
89- Are important parts of biological membranes and
waterproof coverings - Steroids are chemical messengers and are lipids
90Building Blocks of Lipids
Glycerol
http//www.borg.com/lubehawk/biochem.htm
91- When a glycerol molecule and 3 fatty acid
molecules are bonded together as a result of
dehydration synthesis, a lipid molecule is formed
92Dehydration Synthesis to form a lipid molecule
http//www.borg.com/lubehawk/biochem.htm
93Saturated Fats
- If all carbon atoms are bonded to the next carbon
atom in the fatty acid chains with only single
bonds, it is saturated with the most hydrogen
atoms possible
94Monounsaturated Fat
- If there is one carbon-carbon double bond in a
fatty acid chain, it is a monounsaturated Fat
95Polyunsaturated fat
- If a fatty acid chain contains several double
carbon-carbon bonds, it is a polyunsaturated fat - Unsaturated fats are liquid at room temperature
96E. Nucleic Acids
- Macromolecules containing hydrogen, oxygen,
nitrogen, carbon, and phosphorus - Polymers made up of monomers called nucleotides
the building blocks of nucleic acids
97- Nucleotides are made up of 3 parts
- a 5-carbon sugar
- a phosphate group
- a nitrogenous base
98 Nucleotides Building
Blocks of a Nucleic Acid
- One nucleotide consists of a 5 carbon sugar, a
phosphate group, and a nitrogenous base
http//www.borg.com/lubehawk/biochem.htm
99DNA Deoxyribonucleic Acid
- 5-carbon sugar Deoxyribose
- Phosphate group
- Either Adenine, Thymine, Guanine, or Cytosine 4
possible nitrogenous bases
100RNA Ribonucleic Acid
- 5-carbon sugar Ribose
- Phosphate group
- Either Adenine, Uracil, Guanine, or Cytosine 4
possible nitrogenous bases
101Nucleic Acids
- Store and transmit genetic information
102F. Proteins
- Macromolecules that are made of many amino acids
bonded together
103Amino Acids
- Each amino acid is made up of
- an amino group (-NH2) on one end
- a carboxyl group (-COOH) on the other end
-
104- a central carbon atom
- a side chain called an R-group
- The R-groups are varied in composition and
account for the 20 different types of amino acids
105- Some R-groups are acidic, some basic, some polar,
some nonpolar - Some have carbon rings
106- DNA provides the instructions for putting the
amino acids into a specific order to make
specific proteins - Each protein does a specific job
107Proteins
- Control rate of reactions
- Regulate cell processes
- Form bones and muscles
- Transport substances into or out of cells
108- Help fight disease antibodies are proteins
- Most enzymes are proteins
109Levels of Organization of Proteins
- 1st level primary - amino acid sequence
- 2nd level - secondary - amino acids within a
chain can be twisted or folded
110- 3rd level - tertiary - the chain is folded
- 4th level - quaternary - if there is more than
one chain, each chain has a specific arrangement
111- Hydrogen bonds and Van der Waals forces help keep
a proteins shape
112Figure 2-16 Amino Acids
Section 2-3
Amino group
Carboxyl group
General structure
Alanine
Serine
113Figure 2-16 Amino Acids
Section 2-3
Amino group
Carboxyl group
General structure
Alanine
Serine
114Figure 2-16 Amino Acids
Section 2-3
Amino group
Carboxyl group
General structure
Alanine
Serine
115- Peptide bond a type of covalent bond that holds
amino acids together in protein molecules - Dipeptide - two amino acids bonded together
- Polypeptide - 3 or more amino acids bonded
together
116 Dehydration Synthesis to form a Dipeptide
http//www.borg.com/lubehawk/biochem.htm
117Figure 2-17 A Protein
Section 2-3
Amino acids
118Matter and Energy
Interest Grabber
Section 2-4
- Have you ever sat around a campfire or watched
flames flicker in a fireplace? The burning of
wood is a chemical reactiona process that
changes one set of chemicals into another set of
chemicals. A chemical reaction always involves
changes in chemical bonds that join atoms in
compounds. The elements or compounds that enter
into a chemical reaction are called reactants.
The elements or compounds produced by a chemical
reaction are called products. As wood burns,
molecules of cellulose are broken down and
combine with oxygen to form carbon dioxide and
water vapor, and energy is released.
119Interest Grabber continued
Section 2-4
- 1. What are the reactants when wood burns?
- 2. What are the products when wood burns?
- 3. What kinds of energy are given off when wood
burns? - 4. Wood doesnt burn all by itself. What must you
do to start a fire? What does this mean in terms
of energy? - 5. Once the fire gets started, it keeps burning.
Why dont you need to keep restarting the fire?
120Section Outline
Section 2-4
- 24 Chemical Reactions and Enzymes
- A. Chemical Reactions
- B. Energy in Reactions
- 1. Energy Changes
- 2. Activation Energy
- C. Enzymes
- D. Enzyme Action
- 1. The Enzyme-Substrate Complex
- 2. Regulation of Enzyme Activity
121- 24 Chemical Reactions and Enzymes
- A. Chemical Reaction -
any process in which a chemical change occurs
122- Reactants elements or compounds that enter into
a chemical reaction - Products elements or compounds produced by a
chemical reaction
123- Chemical reactions always involve the breaking of
bonds in reactants and the formation of new bonds
in products
124- A chemical equation is used to represent a
chemical reaction - Ex
- CO2 H20 ? H2CO3
- H2CO3 ? CO2 H2O
125- Carbon dioxide forms carbonic acid in your
bloodstream where it reacts with water in the
lungs it changes back to carbon dioxide and water
126- Reactants are on the left side of the equation
- Products are on the right side
- The numbers of atoms of each kind must be the
same on both sides of the equation
127B. Energy in Reactions
- Energy Changes chemical reactions either
release energy or absorb energy - Energy releasing reactions can occur
spontaneously
128- Energy is released in the form of heat energy and
sometimes as light and sound energy (when
hydrogen gas explodes) - Ex hydrogen gas reacting with oxygen to yield
water vapor - 2H2 O2 ? 2H2O
129- Energy absorbing reactions need a source of
energy - Ex when water is changed into hydrogen and
oxygen gas - 2H2O ? 2H2 O2
130- All organisms must carry out reactions that need
energy in order to stay alive - Plants get energy by trapping sunlight for
photosynthesis and storing energy in compounds
produced
1312. Activation Energy
- Energy that is need to get a reaction started
132C. Enzymes
- Enzymes are organic catalysts they speed up
reactions in organisms - Catalysts speed up the rate of chemical reactions
by lowering the activation energy
133D. Enzyme Action
- Reactants must collide with enough energy to
break old bonds and form new ones
1341. The Enzyme-Substrate Complex
- Active site - the place on the enzyme where
reactants (substrates) are brought together to
react
135Substrate
- The substance on which an enzyme acts
- The Enzyme-Substrate Complex formed when an
enzyme joins with a substrate
136Figure 2-21 Enzyme Action
Section 2-4
Enzyme (hexokinase)
Glucose
Substrates
ADP
Products
Glucose-6- phosphate
ATP
Products are released
Active site
Substrates bind to enzyme
Enzyme-substrate complex
Substrates are converted into products
137Figure 2-21 Enzyme Action
Section 2-4
Enzyme (hexokinase)
Glucose
Substrates
ADP
Products
Glucose-6- phosphate
ATP
Products are released
Active site
Substrates bind to enzyme
Enzyme-substrate complex
Substrates are converted into products
138Figure 2-21 Enzyme Action
Section 2-4
Enzyme (hexokinase)
Glucose
Substrates
ADP
Products
Glucose-6- phosphate
ATP
Products are released
Active site
Substrates bind to enzyme
Enzyme-substrate complex
Substrates are converted into products
139Figure 2-21 Enzyme Action
Section 2-4
Enzyme (hexokinase)
Glucose
Substrates
ADP
Products
Glucose-6- phosphate
ATP
Products are released
Active site
Substrates bind to enzyme
Enzyme-substrate complex
Substrates are converted into products
1402. Regulation of Enzyme Activity
- Work best at specific temperature (close to 370C
in humans) and pH 7 - Specific proteins can turn key enzymes on or
off
141Effect of Enzymes
Section 2-4
Reaction pathway without enzyme
Activation energy without enzyme
Activation energy with enzyme
Reactants
Reaction pathway with enzyme
Products
142Figure 2-19 Chemical Reactions
Section 2-4
Energy-Releasing Reaction
Energy-Absorbing Reaction
Activation energy
Products
Activation energy
Reactants
Reactants
Products
143Figure 2-19 Chemical Reactions
Section 2-4
Energy-Releasing Reaction
Energy-Absorbing Reaction
Activation energy
Products
Activation energy
Reactants
Reactants
Products
144Video Contents
Videos
- Click a hyperlink to choose a video.
- Atomic Structure
- Energy Levels and Ionic Bonding
- Covalent Bonding
- Enzymatic Reactions
145Video 1
Video 1
Atomic Structure
- Click the image to play the video segment.
146Video 2
Video 2
Energy Levels and Ionic Bonding
Click the image to play the video segment.
147Video 3
Video 3
Covalent Bonding
Click the image to play the video segment.
148Video 4
Video 4
Enzymatic Reactions
Click the image to play the video segment.
149Internet
Go Online
- Career links on forensic scientists
- Interactive test
- Articles on organic chemistry
- For links on properties of water, go to
www.SciLinks.org and enter the Web Code as
follows cbn-1022. - For links on enzymes, go to www.SciLinks.org and
enter the Web Code as follows cbn-1024.
150Section 1 Answers
Interest Grabber Answers
- 1. Give an example of solid matter.
- Sample answers books, desks, chairs
- 2. Give an example of liquid matter.
- Sample answers water, milk
- 3. Give an example of gaseous matter.
- Sample answers air, helium in a balloon
- 4. Is all matter visible?
- No
- 5. Does all matter take up space?
- Yes
151Section 2 Answers
Interest Grabber Answers
- 1. Working with a partner, make a list of ten
things that have water in them. - Possible answers bodies of water, rain and
snow, soft drinks and other beverages, juicy
foods such as fruits, and so on. - 2. Exchange your list for the list of another
pair of students. Did your lists contain some of
the same things? Did anything on the other list
surprise you? - Students answers will likely be similar, but
not exactly alike. - 3. Did either list contain any living things?
- Students lists may include plants, animals, or
other living things.
152Section 3 Answers
Interest Grabber Answers
- 1. On a sheet of paper, make a list of at least
ten things that contain carbon. - Students will likely know that charcoal and coal
contain carbon. They may also list carbohydrates
(starches and sugars), oil, gasoline, wood, or
carbon dioxide. - 2. Working with a partner, review your list. If
you think some things on your list contain only
carbon, write only carbon next to them. - Students will say that charcoal and coal contain
only carbon. While these materials do contain
small amounts of other elements, such as sulfur,
they are composed mostly of carbon. - 3. If you know other elements that are in any
items on your list, write those elements next to
them. - Students may know that many carbon compounds
also contain oxygen and/or hydrogen.
153Section 4 Answers
Interest Grabber Answers
1. What are the reactants when wood
burns? Reactants are oxygen and cellulose. 2.
What are the products when wood burns? Products
are carbon dioxide and water. 3. What kinds of
energy are given off when wood burns? Light and
heat are given off. Some students may also
mention sound (the crackling of a fire). 4. Wood
doesnt burn all by itself. What must you do to
start a fire? What does this mean in terms of
energy? To start a fire, you must light it with
a match and kindling. You are giving the wood
some energy in the form of heat. 5. Once the fire
gets started, it keeps burning. Why dont you
need to keep restarting the fire? Once the fire
gets going, it gives off enough heat to start
more of the wood burning.
154End of Custom Shows
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