Title: CHEMISTRY
1CHEMISTRY
- Chemistry is a huge topic. You will be asked to
do lots of worksheets, problem solving. You will
take quizzes and tests. You will be asked to
memorize important material, There will be video
presentations and MAYBE a trip to the chem labif
it can be arranged. - Chemistry is the study of the composition of the
universe. - It studies what the world is made of!
- Chemistry began not so much as a science as it
was a pseudoscience. - A pseudoscience is a false science.
- If we argue that true science requires a search
for the truth via the use of the scientific
method, the quantification of knowledge that it
is published and available to all then a
pseudoscience does NOT do those things and thus
is a FALSE (pseudo) science. - False studies like UFO claims, phrenology and
astrology are examples of pseudosciences. They do
not follow the scientific method, their work
cannot be isolated to one variable, it cannot be
duplicated, it is not scrutinized by members of
the international scientific community, etc. etc. - There are rules and scientists must play by the
rulesso must studies that claim to be sciences.
2Alchemy
- It turns out that a core true science like
chemistry started out really as a pseudoscience
called alchemy. - Alchemy is all about the search for two things
- 1. The elixir of life
- 2. The process that would turn anything into
gold. - It was all very secret, coded, symbolic. This is
truly the antithesis of a true science. - Those of you into Harry Potter and the LORD OF
THE RINGS, into wizards and spells and the like
are all drawn from the stereotypes of ALCHEMISTS.
Wizards who knew magic were alchemists who knew
something of chemistry but werent willing to
share the know-how with anyone else. - They never found the elixir of life.
- They never could spin straw into gold as
Rumplestiltskin tried to do.
3The journey from alchemy to chemistry
- Along the way as wizards and magicians and the
like tried to find the elixir of life and a way
to turn anything else into gold, they learned a
lot of other things, they invented a lot of
equipment and they began to find the real world
as interesting a search as the search for the
elusive. - We still use a lot of the glassware they
invented, we still use a lot of the processes
they pioneered. - Alchemists became chemists when they began to
write things down in the vernacular, when they
studied the world around them and when they began
to publish their results so their peers could
scrutinize and duplicate.
4Soin chemistry
- The study of chemistry begins with the base of
operations, the bible for all chemiststhe
Periodic Table of Elements. - Without exaggeration I can say that on a single
piece of paper there is a list of EVERYTHING IN
THE UNIVERSE. THERE IS NOTHING ELSE. - Notice various Periodic Tables. What differences
among them do you notice? - They are merely cosmetic, merely a function of
the date of publication. - I will offer 50 EC points if you can name one
thing that is NOT on an updated periodic table.
5Editing a periodic table for use in this class
- Miss Malley will give you a copy of a Periodic
Table that we will use in this classroom. - We will mark the stepline.
- We will distinguish between columns and rows.
- We will number the rows from 1-7 and explain
their significance. - We will number the columns from 1A-8A and explain
their significance.
6Dmitri Mendeleev
- The Father of the Periodic Table was the
Russian Dmitri Mendeleev. - Among others, he tried to organize stuff.
- Mankind has always liked to organize in order to
control, to understand. So, look around this
room. Look at all the different things. How would
you begin to classify, organize, inventory
everything in this room. What plan would you use?
How would you visually design the inventory so
that you could easily find some item, any item?
That was the challenge of chemists. They studied
things all thingshow would one BEGIN to
organize EVERYTHING?
7Atomists
- Eventually it came to be that scientists agreed
that everything was made of atoms. - Whats an atom?
- Well, a few thousand years ago men speculated
about the smallest particle that made up all
things. A Greek by the name of DEMOCRITUS was
among them. What he speculated was that if you
took a chunk of something, anything, and you cut
it in half and in half and in half and in half
etc. eventually you would come to the smallest
particle that could not be cut, the tiny
fundamental marble-like particle he called
atomos. - Atomos is Greek for indivisible, not
divisible.(not invisibleinDIVISible.)
8Atoms
- If everything is made of atoms then what makes
gold different from oxygen and zinc different
from lead. Were there different ATOMOS? - By the 20th C we realized the atom was NOT
indivisible. The atom itself had parts - Every atom was made up of smaller particles,
protons, neutrons, electrons. - We thought they were indivisiblecould not be
cutthen we found quarks. Quarks are even smaller
particles that make up P.N.e. - So, what is the smallest, indivisible particle??
- Havent found it yet.
9And what IS the difference between gold and
oxygen??
- On the P.T. there are 2 numbers that identify
every element. The smaller of the 2 numbers is
called the ATOMIC NUMBER. This number identifies
the element. This number is the number of protons
in the element. - So Li has..
- Gold has
- Oxygen has.
- Sodium has..
- The difference between Lithium and Gold is the
number of protons in each atom of the element.
10What about the bigger number?
- The larger of the 2 numbers is called the ATOMIC
MASS NUMBER in most books, but in some texts it
may be called the ATOMIC WEIGHT. - The larger number is the TOTAL number of Protons
and NEUTRONS. - Neutrons and protons are jammed together in an
area called the nucleus. - Neutrons have NO electric charge. Protons have a
POSITIVE electric charge. - All protons have the same positive charge so they
do NOT want to stay close togetherlike charges
repelthey would fly apart if they could BUT - Like cowboys herding cattle, neutrons keep the
protons in the nucleus. So there is this dynamic
tension in every atom. Electrons spinning,
protons and electrons pulling on one another
while the protons in the nucleus are repelling
one another.
11And where are the electrons?
- We said there were 3 common particles that make
up every atom, Protons, Neutrons and electrons. - Electrons are very tiny.
- They orbit the nucleus of every atom.
- Protons and Neutrons are in the nucleus, in the
CENTER, electrons spin in orbits around the
center nucleus. - The number of electrons is the same as the number
of protons in every atom. - The NUMBER OF PROTONS equals the NUMBER OF
ELECTRONS.
12Electron orbits
- Electrons spin around the nucleus not unlike
planets around the sun. Electrons travel at
different distances from the nucleus just like
some planets are closer or farther from the sun. - There are rules for placing electrons in orbit
around the nucleus. - 1. Only 2 electrons can fit in the first energy
level, the first orbit. - 2. UP to 8 electrons can fit in the second energy
level. - 3. Up to 8 electrons is stable for electrons in
the third energy level. - 4. But keep in mind that the number of electrons
you must distribute is equal to the number of
protons that identify the element.
13Atomic models
- We cant see an atom, not even today with all of
our equipment. The best we can get is just a
blur. So over the years scientists have developed
models which try to give us a picture of what an
atom looks like. - How do we know if they are good models?
- Accurate?
- The models are good if we can make predictions
based on the model and real matter behaves just
the way we predict they will behave according to
our model. - Over the years there have been many models.
- We could start with Democritus who said the
atomos was the indivisible particle.
14Daltons model
- John Dalton was a teacher.
- Over time he studied the behavior of matter and
suggested his verbal model of the atom. - Dalton also thought the atom was
atomosindivisiblea hard marble - BUT
- He went on to suggest several new ideas
- 1. Atoms of the same element are all alike.
- 2.Atoms of different elements are different.
- 3. Atoms of different elements can join together
in small whole number ratios to form compounds.
15Thomsons model
- JJ Thomsons model of the atom included the newly
discovered particle called the electron. - The electron was discovered in the cathode ray
tube near the turn of the century. Its discovery
proved the atom was NOT indivisible but had
parts. There were SUBATOMIC particles. - Thomson reasoned also that since most matter was
neutral, if this negatively charged particle
existed then a positively charged particle must
also exist to make matter neutral. - He envisioned the atom to be like chocolate chip
cookie dough. The dough was the positive part of
the atom and the chocolate chips were the
electrons.
16Dr. Rutherford said
- Rutherfords model of the atom came about as a
result of an elegant experiment in 1911 called
the gold foil experiment. - He had engineers pound a bit of gold until it was
VERY thin. He fired POSITIVELY charged particles
into this gold foil. - 99.999 of those particles went through the
foil unhampered. Straight through. - Once in awhile a particle would come bouncing
straight back at him. - Once in awhile a particle would be deflected
off at some angle. - What the world realized was that the atom was
made of a charged, very dense, very SMALL
nucleusa center. The electrons must be outside
that nucleus somehow. And in between the nucleus
and the negative electrons there was NOTHING!!! - It was Rutherfords gold foil experiment that
began to suggest that the world was really an
illusion, that the world was mostly made of EMPTY
SPACE. - Everything is made of atoms and the atom is
99.999 empty space thus everything is
mostly.. - His experiment also proved that most of the mass
was in the nucleus. Electrons contributed
insignificant mass to the atom.
17Niels Bohr
- In 1913 Niels Bohr (Danish) suggested another
model. This is the one most useful to us. - In the Bohr atom, the nucleus contains protons
and neutrons. - The electrons orbit the nucleus in orbits at
different distances like planets orbiting the
sunthey dont all orbit in the same path but are
spread out some closer to the sun, some farther. - Electrons are like that.
- It turns out that because matter is neutral, the
number of positive charges (P) must be equal to
the number of negative charges (e-). - Over the years we have realized that 2 e- can
spin in the closest orbitcalled an energy level. - Up to 8e- can orbit in the second energy level.
- Up to 8 e- can orbit in the third energy level
and we wont go much beyond that as we sketch
atoms. - One more point, the farther out the electron is
from the nucleus, the more energy it has. The
closer it is to the nucleus, the less energy the
electron has.
18Sketching atoms
- We will use the BOHR atom as our model.
- Niels Bohr developed this particular model.
- Miss Malley will now turn off the system and we
will learn how to sketch atoms from 1 - 20.
19Properties
- Go to the bulletin board and get the picture.
Ill give you 10 EC points for the correct one. - Butthat would be kind of difficult because???
- YOU NEED TO NARROW DOWN THE CHOICES
- YOU NEED MUCH MORE INFORMATIONYOU NEED
PROPERTIES - PROPERTIES ARE WORDS THAT IDENTIFY, DESCRIBE, AND
DISTINGUISH.
20Properties identify, describe, select
- Words that describe and identify and select
particular objects from among others are called
properties. - They include physical properties
- Color, odor, luster, state, density, texture,
- Conductivity, malleable, ductile, magnetic.
- And there is ONE chemical property
- The number of electrons in the OEL determines how
the atom will behave when forming
compoundschemical reactivity.
21Properties include
- Solids , liquids, gases have identifying
properties. - Solids have a definite shape and volume.
- Liquids have a definite volume but take the
shapes of their container. - Gases spread out to occupy the entire space
available so gases have neither a definite shape
nor volume.
22Things can change
- It turns out there are two ways that matter can
be changed. There are physical changes. There are
chemical changes. - Physical changes are any changes you might make
in an object that do NOT change the identity of
the object. So you must ask yourself after the
change is made Did I end up with the same
substance I started with? If the answer is YES
then that describes a physical change. - If you end up with an entirely different
substance that has different physical and
chemical properties than the substanve you
started with then that describes a CHEMICAL
change.
23Physical changes
- You tear a piece of paper. After you do that you
still have a paper. You have not altered the
identity of the substance. - If you cut, saw, shred, tear,etc then those are
physical changes because when you are done you
still have the original substance. - After you melt butter, you started with butter,
you end up with butter. So freezing, boiling
melting are all physical changes. - A change in density is a physical change.
24Chemical changes
- In all chemical changes you will end up with
something VERY different from what you started
with. - Take some hydrogen, odorless, colorless EXPLOSIVE
gas and add it to some oxygen, odorless,
colorless gas that supports combustion (burning).
After you do that you end up with a clear liquid
you use to put out fires called water. Water is
VERY different from EITHER hydrogen or oxygen. - Other things that produce very different products
include baking, cooking, exploding, burning,
tarnishing, rusting, corroding,all chemical
reactionsthe forming of compounds, the
destruction of compounds, the rearrangements of
compounds, the production of light,
25Now, back to the P.T.
- The stepline divides the P.T. into..and.
- Elements that sit ON the stepline are called
- The column number tells us..
- The row number tells us..
- The atomic number tells us..
- The atomic mass number tells us.
- The man who designed the first modern periodic
table was - The difference between gold and oxygen is.
- The difference between an atom of sodium and an
atom of lithium is.. - The smallest part of an element is.
- The word atom comes from.
- The atom is made ofcommon particles
- Consider the differences between metals and
nonmetals. Characteristics include?
M
26Properties of M and NM
- A metal is generally
- Solid at room temperature
- Solid with a luster
- Malleable
- Ductile
- Silvery in color
- On the left side of the stepline on the P.T.
- Have fewer electrons in the outer energy level of
the atom. - Likely to give away electrons as compounds are
formed - SOME METALS ARE MAGNETIC
- Nonmetals are none of those things.
27More, More of the P.T.
- Col. IA, Group I are called the ALKALI metals.
They all have only 1 e- in their OEL and thus are
looking to get rid of it! They happily form
compounds with any element in Col . VIIA Metals
form a 1 ion while the Col. VII halogens form
a -1 ion. - Col.I Col. VII produce SALTS.
- Every element in Col IA is soft, silvery, low
density, melt at low temps and highly REACTIVE
28And Col IIA
- These are called the ALKALINE EARTH METALS
- They all have 2 e- in their OEL so that they try
to get rid of 2 OEL e-. Thus they are very
reactive, eager to form compouhnds, but not
kquite as eager as those in Col IA since these
elements are closer to achieving 8 e- in the
OEL. - Col. IIA metals will form compounds very easily
with those elements in Col VIA.
29Transition elements/metals
- Groups 3-12 is that big middle group of metals.
- These do not follows the rules quite as nicely as
the Col. A elements. - These metals are mostly shiny, have high melting
points, are good conductors of heat and
electricity. They make ionic compounds with
nonmetals. - These metals are often found in ores dug out of
the ground.
30RARE EARTH ELEMENTS
- These are metals that were pulled out of the main
P.T. and put at the bottom in two row. This was
done both because the elements are rareyou
probably wont run into any of these in your
lifeANDbecause it made the table able to fit on
a single piece of paper. - The two rows were called the Lanthanide and
Actinide series. - Generally Lanthanides are from 51-71 though this
may vary slightly on PT - Generally the Actinides are 90-103.
- Keep in mind that the last naturally found
element is 92 Uranium beyond that the elements
are man made by bombarding large nuclei with one
more Protonrecall that it is the number of
protons that identify the element.
31Col IIIA
- This is claled the Boron Group only because Boron
is the first element in the col. On some PT it is
col 13. - Boron is a metalloid. It is brittle,black.
- Every element below Boron is a metal though, just
to the left of the stepline. - The most common metal that comes from the earth
is Aluminum in this group.
32Col. IVA
- Called the Carbon group. Carbon is clearly a NM
But Si is a metalloid, it sits ON the stepline. - Silicon compounds make up 60 of the Earths
crust. - Tin and lead are both metals.
33Col. VA
- Called the Nitrogen group.
- Nonmetal, N is a diatomic element that is 80 of
our air..it also fills the tires of airplanes. It
does not combine easily with other elements.
Nitrogen is part of our bodies in proteins. - Other elements include P, a NM
- Arsenic is a poison.
- Sb, Bi, are both metals.
34Col. VIA
- The oxygen group is very important to usto
breathe. It only make sup 20 of the air but
essential. Most oxygen is combined with Silicon
in rocks.
35Col. VIIA
- Halogens.
- Col. 7A elements are salt formers. They love to
make salts with metals in 1A. - These are all very reactive nonmetals. Fluorine
is the MOST reactive of all the nonmetals.
36Col. VIIIA
- The Noble gases are all in col 8A.
- Group 18
- These gases are used in signs.
- These gases have 8 e- in the OEL and thus are
stable and thus make NO compounds with other
elements.
37Hydrogen
- Notice that Hydrogen is set off by itself. It is
often set above Col 1A. - H is a NONMETAL
- It is a diatomic gas nonmetal
- BUT
- We put it in Colo. IA usually because it has 1 e-
in its OELits ONLY ELand thus behaves a little
like the elements in Col IA. - It loses its 1 e- a lot!
- Hydrogen is the most abundant element in the
UNIVERSE.
38ISOTOPES
- It turns out that
- Atoms of the same element have the same number
of protons in the nucleus. - Recall that the number of protons identifies the
element. - Element number 3 is .because..
- BUT.
- It also turns out that
- Although every atom of a particular element has
the same number of protons, atoms of the same
element can have different numbers of neutrons. - For example although every atom of oxygen
has.protons, one atom of oxygen might have 7
neutrons, another atom of oxygen might have 8
neutrons, another atom might have 6 neutrons. So
there are 3 isotopes of oxygen in this example3
isotopes, 3 versions of oxygen as it were.. - Carbon has .protons and.electrons. BUT some C
atoms have 6 neutrons but other C atoms have 8
neutrons. So we would say that carbon has two
isotopes2 versions of carbon. - You couldnt tell the difference among isotopes.
They chemically behave identically.
39So what
- So what is the periodic table?
- What is an element?
- An element is a collection of atoms that all look
alikeall have the same number of protons. - An element is the fundamental building block of
everything else. - ALL things are either elements or compounds.
40And a compound is.
- A compound is a collection of 2 or more elements
that have joined together to make something BRAND
NEW. - EVERYTHING then is either an element, on the
periodic table or it is a collection of elements. - Gold is an element. Water is a compound. Whats
the difference?
41Elemental symbols and chemical formulas
- On the P.T. every element has a symbol of 1 or 2
letters. Sometimes the symbol makes sense.O is
oxygen. But Na is sodium because the symbol Na is
from the Latin word Natrium. - N is nitrogen but Hg is from the Latin
Hydrargyrum which is Latin for Mercury. - It is wise to learn the symbols of the most
common elements since it will save you time in
the long run. - Compounds can also be written with shorthand
symbols. NaCl is sodium chloride. H2O is water. - We will talk much more about compounds as we move
on.
42Why do elements form compounds at all?
- It turns out that compounds form at all because
Nature Seeks Stability. - So what does nature think is stable?
- Nature plays by something called the octet rule.
That means that an atom is considered chemically
stable if it faces the world with 8 e- in its
outermost energy level. - Atoms want 8 e- in their outer energy level.
- They will do whatever it takes to get a full
outer energy level to face the world. - It turns out that atoms can gain or lose
electrons in order to face the world with a full
OEL. - Miss Malley will spend a good deal of time
lecturing further on the how and why of compounds.
43Three types of compounds.
- An atom will do whatever it must in order to get
a full outer energy level facing the world. - Metals in Col. I, II, III have 1,2,3 e- in the
OEL so it is easier for the atom to LOSE 1 or 2
or 3 e- than it is for them to pick up 7e-, 6e-
or 5e-. - Nonmetals have 5,6,7 or 8 e- in their energy
levels for Col. V, VI, VII, VIII. It is easier
for those elements to pick up 3 or 2 or just 1 e-
than to try and give away 5 or 6 or 7 e-. So NM
want to GAIN e-. - Col IV elements have no advantage in either
gaining or losing e- so we will discuss their
UNIQUE situation later. - Col. VIII elements already HAVE 8e- in their OEL
so they need nothing! Therefore they do NOT make
compounds. - Compounds are made because atoms seek stability,
they seek a full OEL facing the world. - Col. VIII A elements already have 8, they are
stable, they are full, they do NOT form
compoundsthats why some books call them the
INERT gases. Col 8A elements are all gases and
the word INERT describes and object that does
NOTHING! - If someone says you are inertthat is not a
compliment. - Some books call Col. 8A elements the NOBLE gases.
Nobility means royaltyand the royals do not
associate with the masses.do not mingle with
others.so they do not form compounds.
44IONIC compounds
- Atoms gain stability by joining with other
elements, other atoms so they have a full OEL. - Atoms will gain or lose the number of electrons
that will give them the full OEL. - So when a metal atom seeks to lose some e-, a
nonmetal that wants to pick up that number of e-
will join with it to produce a COMPOUND - This is an IONIC compound. An ionic compound is a
METALNONMETAL.
45Covalent Compounds
- Covalents compounds are sometimes called
MOLECULAR compoundsthey mean the same thing. - A covalent compound is made up of 2 NONMETALS.
When a Nonmetal and a Nonmetal join one is not
strong enough to pull off e- from another NM. And
NM dont really want to give away any e-. So what
happens when a NM and a NM join is the e- are
shared between them so that each of the atoms has
influence over 8e-. - This produces a compound called a covalent
compound.
46What follows this will be the naming of
compounds, the definition of ions, polyatomic
ions and the PAI compounds, the binary and
ternary rules, writing formulas and predicting
compound formation.
47Whats an ION
- Atoms will gain or lose electrons in order to
achieve a full OEL facing the world. - The definition of an atom includes the notion
that the number of Protons the number of
electrons in every atom. - BUT
- When at atom wither gains or loses electrons then
the number of Protons NO LONGER equals the number
of electrons. - And THAT is an ion. An ion is an atom thqt has
lost or gained electrons. An ion has an electric
charge. It either has more electrons that protons
so it has a NEGATIVE chare OR it has fewer
electrons that protons so that it now has a
POSITIVE electric charge. - Atoms are NEUTRAL.
48Binary ionic compound
- A binary ionic compound
- This is a compound made of 2 elementsbinarytwo.
- Ionic means this is a metal attached to a
nonmental. - Compound is two or more elements making something
very new and different so that atoms will become
more stable. - The metal wants to give away electronas and the
nonmetal gains those electrons. - In writing ionic compound formulas OXIDATION
NUMBERS must equal zero.THIS WILL REQUIRE A LOT
OF PRACTICE - Oxidation numbers tell us how the atom will
behave when forming compoundsit tells us how
many electrons it wants to gain or lose. - Name the metal, name the root of the nonmetal and
end the compound in IDE - Sodium chloridesodium is metal and chlor is root
of NM and we end the binary name in IDEsodium
chloride. - Calcium chloride.
- Magnesium oxide
49Binary Molecular compounds
- Nonmetal attached to another nonmetal is a BMC.
This is where Nonmetals SHARE OEL e-. In ionic
compounds one atom loses electrons and the NM
gains electrons. BUT in BMC no aytom gains or
loses electrons. The two nonmentals simply SHARE
electrons so that eacha tom has influence over
enough electrons to make them more stable. - We name the first nonmetal, name the root of the
second nonmetal and end the name in IDE. ALL
binary compounds end in IDE.
50MIXTURES
- There are elements which are pure substances,
fundamental, basic, and made of all the same kind
of atom. Hydrogen, oxygen , sodium , chlorine - There are compounds which are pure substances
made of 2 or more types of atoms joining together
to make something new in order to achieve a full
OEL facing the world. Water , salt - Mixtures on the other hand are NOT pure
substances. Mixtures do not require a recipe. A
mixture is just a collection of stuff thrown
together with no particular quantities required.
No electrons are involved. All parts of a mixture
keep their own identities. Nothing new is made.
Salt water. Tossed salads stew vegetable soup
51Homogeneous vs Heterogeneous
- Substances, elements, compounds, mixtures can be
described as either homogeneous or heterogeneous. - Homogeneous describes any substance that has the
same composition throughoutno matter where you
take the sample it will be the same as every
other sample. So elements are homogeneous. All
atoms of an element are the same. Water is a
compound. Compounds are homogeneousevery
spoonful of water is the same no matter where the
sample is from. All NaCl molecules are the same. - Mixtures might also be homogeneous. Cream mixed
into coffee produces an evenly mixed mixture. No
matter where the sample is taken in that ocoffee
cup the sample with be the same. Salt water is
homogeneous, the salt is evenly distributed
throughout the water. .All solutions are
homogeneous mixtures. Solutions involve a SOLUTE
mixed into a SOLVENT. The solvent DISSOLVES the
solute until it is evenly mixed. The word
DISSOLVE means to break into tiny pieces..
Breaking is a physical changeso a solution is
just a mixturea physical event.Not a chemical
reaction - So all elements, all compounds and SOME mixtures
can be described as homogeneous - Heterogeneous describes only mixtures. It
describes mixtures that are NOT evenly mixed so
that every spoonful is different. This would be
a tossed salad, vegetable soup, chocolate chip
cookies., stew. Each sample would be different.
52ALLOYS
- An alloy is a solution, a mixturea very specific
mixture of metals melted together. - We will make a list from the chemistry texts but
alloys include steel, pewter, solder, brass, 24
karat gold - But it is just a mixture. Not a compound. No
recipe is requiredjust a homogeneous solution
53CHEMICAL REACTIONS
- 1. Chemical reactions produce chemical changes.
- Chemical reactions can be written in shorthand
using an equation form. - We begin with REACTANTS and we end up with
PRODUCTS. - Products are VERY different from the reactants we
started with. - BUT everything must be accounted for. All the
elements on the left must equal the elements on
the right. - Evidence that a chemical reaction has taken place
include forming a precipitate, color change,
formation of a gas, change in temperature. - If heat, light or energy is given off then we
call that an EXOTHERMIC REACTION. Things get hot. - If heat is absorbed into the chemical reaction
then we call that an ENDOTHERMIC REACTION.
Things get Colder.
54Keep in Mind
- In chemical reactions, the energy is not in the
atoms themselves but it is in the BONDS that are
formed or broken. As when you digest food. It
isnt the Atom itself you are really interested
in, it is the energy stored in the atomic bonds
that hold different atoms together. When bonds
are formed, broken or rearranged it is the energy
required to do that that is stored in or released
from that action. And THAT is what we are after.
55Reactants yield Products
- In chemical equations reactants must equal
products. Energy is always involved. - All chemical equations must be balancedthe law
of conservation of mass and energy is the rule.
You cannot end up with more or less than what you
started with and you cannot end up with different
elements than what you started with. - We balance chemical equations by using
COEFFICIENTS. Coefficients are whole numbers we
can place in front of compounds or fee standing
elements. They cannot separate a compound, they
must be IN FRONT OF wither the element or the
compound. - We learned that when writing a proper chemical
formula, subscripts were essential to the recipe.
The recipe for water or sugar or carbon monoxide
or sulfur dioxide is ALWAYS the same. The
subscripts are there to tell us how many of each
atom we need to make a molecule of a compound.
SUBSCRIPTS do not change. The recipe for water is
ALWAYS the same. - SO
- When you go to balance chemical equations you may
NEVER NEVER EVER NEVER change a subscript in
order to balance a chemical equation.
56We will now practice balancing a LOT of chemical
reaction.
- It is like solving a puzzle.
- Some of you will do well, others of you will
struggle. - There are no hard and fast rules except
ONEwhatever is on the left of the equation must
equal whatever is on the right. - So when you ask Miss Malley, is this right? I
will answer count!!! Just count!!! - Lets try some.
57There are 5 common types of Chemical reactions.
- 1. Synthesis reaction.
- From simple to complex.
- AB AB Two simple reactants, substances, join
together to seek stability at the OEL e-. The
product is a more complex compound. - 2. Analytical reaction. When your English teacher
asks you to analyze a poem, what do you do? Dont
you take it apart and look at it line by line,
word by wordsee what its made of? So Analysis
is to take apart, look at what is is made of. - So in chemistry we start with a complex compound
and tear it apart, down to its simpler building
blocks. - AB AB
58Single replacement reactions
- 3. The third type of chemical reaction is just
thisa single replacement reaction. - A BC AC B
- Bill and Cynthia go to the dance. Antonio goes to
the dance aloneuh oh, - Poor Bill has been replaced by AntonioAntonio is
taking Cynthia home. - One element replaces another element in a
compound. - We start out with a compound and a free standing
element. We end up with a different compound and
a different free standing element. - AB C CB A
59Double replacement reaction
- 4. Double replacement reactions look the most
complicated. - Reactants are two compounds, products are two
different compounds. - Two couples go to a dance and everyone changes
partners. - AB CD AD CB
60Combustion reaction
- 5. The 5th chemical reaction is combustion which
means burning. - It is EASY to spot because the products are
always the same. - We start with some Hydrocarbon compound we add
oxygen and the products are always carbon dioxide
and water! - Miss Malley will now give you a lot of examples
for you to identify.
61A few more terms to know
- In chemical reactions there is always some energy
echange involved, absorbed or given off. - There is something called activation energy. That
is the energy needed to start a chemical
reaction, give the reactants a nudge to get them
started. - A push on the sled. A push to start a skateboard.
A match to light a fire. - A CATALYST is a substance often used in chemical
reactions. A catalyst is a substance that speeds
up a chemical reaction but does not get involved
directly. Your friend fixes you up with someone
but your friend does not go the date! Your
friend brings two people together and then steps
back. So thats what a catalyst does in a
chemical reaction. Speeds up the reaction but in
the end is not PART of the reactants. - Enzymes are excellent examples of catalysts. In
the human body thats the job of an enzyme to
speed up reactions, let them take place at a
relatively low temperature98.6F is not a very
high temperaturewe cook roasts at 350F. Body
temperature cannot be too high since
proteinslike your brainstarts to unravel at
higher temps. So catalysts are REALLY essential
in surviving.
62A huge topic!!
- There is lots of work to be done. Worksheets,
videos, projects, quizzes, tests all ongoing and
upcoming. - You will be asked to memorize material.