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More polarization transfer DEPT

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Transfer) is another sequence that takes advantage of the ... Using pulegone as an example (real data...) For f = p / 2 (90), we edit the CH carbons ... – PowerPoint PPT presentation

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Title: More polarization transfer DEPT


1
  • More polarization transfer - DEPT
  • DEPT (Distortionles Enhancement by Polarization
  • Transfer) is another sequence that takes
    advantage of the
  • surplus 1H population to see 13C signals.
    Furthermore, it can
  • edit the signals in order to obtain response
    from CH, CH2,
  • and CH3 according to the settings of the
    sequence

90x
180x
13C
90x
180x
fy
tD
tD
1H
tD
1H
2
  • DEPT results for different f values
  • Using pulegone as an example (real data)
  • For f p / 2 (90), we edit the CH carbons

3
  • DEPT (continued)
  • If we plot the responses for different carbons
    versus the tip
  • angle f of the 1H pulse, we get

p/2
3p/2
p/4
CH
CH2
CH3
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