19661971 ' , '

1
??????8-909-966-78-85

• ????? ???????? ???????????, ?.?.?.
• ?????? ?????????????????? ??????
• ??????? 20 ??????? 1949 ???? ? ??????
• 1966-1971 ??????????????? ???????? ????? ?
  ????? ?? ?. ??????????, ?. ????
• ?????? ???????????? ??????????? 1978, ????,
  ???? ?? ?? ???
• ?????? ?????????? ??????????? 1992, ????, ????
  ?? ?? ??? (???????? ??????????? ??? ???,
  ??????)
• ???????? ????????????
• 1971 1997 ?????? ? ?? ?? ???, ?.?.?., ?.?.?,
  ???. ??????????? ??????? ????? ?????????????
  ?????????????,
• 1998 2006 ?????? ? ??????????? ????????????
  ??. ???-???????, ???????????? ?? ?????
  ????????????? ??????? ? ????????.
• ??? ???????????? ?.?.?. ?. ???????????? ????????
  ??? ????????? ???? (?????????? ?.?. ? ???????
  ?.?.).
• ? ?????? 2007 ???? ??????? ??????? ?????????
  ????????? ???????????????? ??????? (????) ??.
  ?.?.???????? ???, ????? 24 (?????????? ????????
  ????????? ?.?.)

2
-2-

• ??????? ????????????
• ????????????? ?????????????? ?????????????,
  ????????????? ????????? ?????????????? ?
  ???????????, ?????????????? ?????????, ?????
  ?????????? ????????
• ????????????? ????? ??. ?????? ??????? ?? ??????
  ? ?????? ? 2004-2006 ?????.
• ???????? ???????????
• Patent USA 4198586, priority 28.12.78, Patent
  France 244019, Inventive Bulletin 47, 1980.
• Patent Russia (SU) 551856, 789470, 944269,
  957540, 1273353 (Divinyl-making) 782286, 944270,
  1058249, 1483869 (Isoprene-making) 1234397,
  Inventions Bulletin 20, 1986 (Styrene-making).
• Patent Russia (SU) 1734272, priority 1987,
  registr.15.0192 (Catalyst for synchronous
  preparation of aniline adiponitrile).
• Patents Abstracts
• Manufacture of butadiene. Patent Russia (SU)
  1273353
• Aliev V. S., Rizaev R. G., Gadzhi-Kasumov V. S.,
  Talyshinskii R. M.
• (Mamedaliev Yu. G., Institute of Petrochemical
  Processes, USSR). USSR (1986) CODEN URXXAF SU
  1273353 A1 19861130 Patent written in Russian.
  Application SU 85-3867901 19850124. CAN
  106177931 AN 1987177931 CAPLUS
• Abstract
• Butadiene (I) is manufd. by oxidative
  dehydrogenation of butane-butylene fractions in
  an adiabatic reactor at an elevated temp. in the
  presence of steam and a catalyst contg. Ni, V,
  and Sb oxides on an ? -Al2O3 support. The yield
  of I and dehydrogenation selectivity are
  increased by using a catalyst using 0.1-0.3 wt.
  MgO and 0.3-0.5 wt. ZnO, in add. to NiO 9-11,
  V2O5 2.5-4, Sb2O3 5-9, and ?-Al2O3 up to 100 wt.
  , and conducting the oxidative dehydrogenation
  at 570-590.

3
-3-

• Styrene. Patent Russia (SU) 1234397
• Aliev V. S., Talyshinskii R. M. (Mamedaliev Yu.
  G. Institute of Petrochemical Processes, USSR).
  USSR (1986) CODEN URXXAF SU 1234397 A1 19860530
  Patent written in Russian. Application SU
  82-3504104 19820927. CAN 105134495 AN
  1986534495 CAPLUS
• Abstract
• Styrene is prep. by oxidative dehydrogenation of
  PhEt at 500-620 in steam over catalyst contg.
  4-5
• VOx, 9-11 NiOx, and 11-13 SbOx on g-Al2O3.
• Decationizing mordenite with ammonium chloride
  solution. Patent Russia (SU) 1669861,
• registr.1991
• Khudiev, A. T. Adigezalova, N. I. Abdullaeva,
  L. E. Nasirova, F. M. Talyshinskii, R. M.
  Rizaev, R. G. (Institute of Inorganic and
  Physical Chemistry, Academy of Sciences,
  Azerbaidzhan S.S.R., USSR). USSR (1991) CODEN
  URXXAF SU 1669861 A1 19910815 Patent written in
  Russian. Application SU 89-4740857 19890808.
  CAN 11729865 AN 1992429865 CAPLUS
• Abstract
• To decrease the toxicity of the wastewater from
  the title process by decreasing the consumption
  of NH4Cl, a 0.05-0.10 sol. is used which is
  electroactivated to pH 1.9-2.5 at an NH4-Na
  ratio of (1-3) 1.
• Catalyst for oxidation of carbon monoxide. .
  Patent Russia (SU) 1685509
• Ali-Zade F. M., Mardanova N. M., Sorgin P. M.,
  Talyshinskii R. M., Medzhidov A. A., Rizaev R. G.
  (Institute of Inorganic and Physical Chemistry,
  Academy of Sciences, Azerbaidzhan S.S.R., USSR).
  USSR (1991) CODEN URXXAF SU 1685509 A1 19911023
  Patent written in Russian. Application SU
  89-4745366 19890808. CAN 116200249 AN
  1992200249 CAPLUS
• Abstract
• Activity of the catalyst is improved when Sb
  oxide is used at 1.0-2.0 in ads. to Cu oxide
  2.0-2.5, Co oxide 1.0-2.0, Cr oxide 3.0-5.0, Mn
  oxide 2.5-4.0 wt. and balance g-Al2O3.
• Talyshinsky R. M. others. Patent Russia (SU)
  645353, 910183, 789471, 1330797, 1513672,
• 1685509, 1734272 (subsidiary patents, 1976-1992).
• 1,3-butadiene. Pilaeva L. P., Seifullaeva Z. M.,
  Aliev V. S., Rizaev R. G., Gadzhi-Kasumov V. S.,

4
-4-

• Ter-Sarkisov B. G., Talyshinskii, R. M.
• (Mamedaliev, Yu. G., Institute of Petrochemical
  Processes, USSR). Fr. Demande (1980), 28 pp.
  CODEN FRXXBL FR 2444019 19800711 Patent written
  in French. Application FR 78-35423 19781215. CAN
  9448602 AN 198148602 CAPLUS
• Abstract
• Butadiene (I) 106-99-0 is prepd. by
  dehydrogenation at 550-650 of butane
  106-97-8, optionally contg. Butene
  25167-67-3, in the presence of O, inert
  diluents, and catalysts contg. oxides of Sb 5-20,
  V 2-10, Ni 4-20, Th 0.1-1, and Ti 0.1-1. Thus,
  passing a mixture of 8515 butane-butene 1, O
  1.4, and steam 40 parts over a catalyst contg.
  oxides of Sb 15, V 7.0, Ni 4.0, Th 0.5, and Ti
  0.1 on Al2O3 at 600-20 gives a 28.4 conversion
  with selectivity for I 50 and productivity 14.2
  L I/L catalyst-h.
• Butadiene (divinyl).
• Aliev V. S., Gadzhi-Kasumov V. S., Pilaeva, L.
  P., Rizaev R. G., Seifullaeva Z. M., Talyshinsky
  R. M., Ter-Sarkisov B. G. (USSR). U.S. (1980), 6
  pp. CODEN USXXAM US 4198536 19800415 Patent
  written in English. Application US 78-973756
  19781228. CAN 9348265 AN 1980448265 CAPLUS
• Abstract
• Butadiene 106-99-0 is prepd. by dehydrogenation
  of butane 106-97-8 or its mixed with butenes
  at 550-650 in the presence of O, an inert
  diligent, and a catalyst comprising Sb oxide
  5.0-20.0, V oxide 2.0-10.0, Ni oxide 4.0-20.0, Th
  oxide 0.1-1.0, Ti oxide 0.1-1.0 wt., and the
  balance carrier, preferably Al2O3. Thus, a
  mixture of hydrocarbon feed (8515
  butane-butenes), O, and steam in molar ratio
  11.440 was passed at space velocity of the
  hydrocarbon feed of 100 h-1 through a reactor
  with a stationary bed of catalyst in 3 sections
  at 600, 620, and 615. The catalyst comprised Sb
  oxide 15.0, V oxide 7.0, Ni oxide 4.0, Th oxide
  0.5, and Ti oxide 0.1 wt. supported on Al2O3.
  The butane conversion was 28.4, the selectivity
  for butadiene was 60, and the butadiene yield
  was 14.2 L/L catalyst per h.
• Regeneration of a catalyst for oxidative
  dehydrogenation of n-butane to butadiene. Patent
  Russia
• (SU) 910183
• Seifullaeva Zh. M., Gadzhi-Kasumov, V. S.
  Rizaev, R. G. Talyshinskii, R. M. Guseinova E.
  M. (Mamedaliev Yu. G. Institute of Petrochemical
  Processes, USSR). USSR (1982) CODEN URXXAF SU
  910183 A1 19820307 Patent written in Russian.
  Application SU 79-2756675 19790320. CAN
  9729226 AN 1982429226 CAPLUS
• Abstract
• The catalyst contg. Treating with a chem. reagent
  followed by drying and calcining regenerates Mo,
  Bi, V, and Sb oxides supported on Al2O3. The
  regeneration is accelerated and simplified by
  using a chem. reagent consisting of 5-6 aq. Ni
  nitrate at 1.26-1.30 L/kg catalyst with calcining
  at 550-600 for 2-2.5 h.

5
-5-

• Neftekhimiya, 1992, 32(4), 339-347.
• Journal written in Russian.
• Effect of the macroscopic distribution of
  components in nickel-vanadium-antimony/g-alumina
  catalyst granules on activity in the oxidative
  dehydrogenation of n-butane.
• Talyshinskii R. M., Shkarin A. V., Gol'denberg G.
  I., Seifullaeva Zh. M.,
• Panteleeva Yu. A., Guseinova E. M., Rizaev R. G.
• Neftekhimiya, 1992, 32(2), 113-124.
• Journal written in Russian.
• Role of oxide catalyst basicity in selective
  oxidation.
• Mamedov, E. A. Vislovskii, V. P. Talyshinskii,
  R. M. Rizayev, R. G.
• Stud. Surf. Sci. Catal, 1992, 72 (New Dev. Sel.
  Oxid. Heterog. Catal.), 379-386.
• Journal written in English.
• Gibbs rule and multiroute heterogeneous catalytic
  reactions.
• Talyshinsky R. M.
• Dokl. Akad. Nauk Az. SSR, 1989, 45(6), 30-33
• Journal written in Russian.
• Kinetic analysis of the effect of support
  activation for nickel-vanadium-antimony oxide
  catalyst in the single-stage oxidative
  dehydrogenation of n-butane to divinyl.
• Panteleeva Yu. A., Musaev A. M., Talyshinskii R.
  M., Seifullaeva Zh. M., Rizaev R. G.
• Kinet. Katal., 1991, 32(3), 642-646.
• Journal written in English.

6
-6-

• Effect of the nature of mineralizer modifying a
  support on distribution, dispersity, and activity
  of a catalyst for oxidative dehydrogenation.
• Talyshinskii R. M., Guseinova M. K., Mardanova N.
  M., Medzhidov A. A.
• Kinet. Katal., (1987), 28(4), 933-937.
• Journal written in English.
• Mathematical modeling of the synthesis of
  o-cresol by alkylation of phenol by methanol in a
  fluidized catalyst bed.
• Akhundov, A. A. Agaev, A. A. Indyukov, N. M.
  Agaev, F. M. Talyshinskii, R. M. Babaev, R. K.
  Khim. Prom-st. (Moscow), (1987), (5), 271-272.
• Journal written in Russian.
• Catalytic effects of modification of
  nickel-vanadium composition carrier by
  electroactivated water.
• Rizaev R. G., Talyshinskii R. M., Seifullaeva Zh.
  M., Panteleeva Yu. A. Gasanov Ch. A., Suleimanov
  A. S., Novruzova S. Kh.
• Dokl. Akad. Nauk Az. SSR, 1986, 42(7), 40-44.
• Journal written in Russian.
• Mathematical modeling of the catalytic alkylation
  of phenol by methanol.
• Akhundov A. A., Agaev, A. A., Talyshinskii, R.
  M., Indyukov N. M., Aliev F. V.
• Azerb. Khim. Zh., 1985, (5), 39-342.
• Journal written in Russian.
• Methodological aspects of stoichiometric analysis
  of complex heterogeneously catalyzed reactions.
• Talyshinskii, R. M., Rizaev R. G., Gadzhi-Kasumov
  V. S., Seifullaeva Zh. M.
• Azerb. Khim. Zh., 1985, (3), 3-7.
• Journal written in Russian.

7
-7-

• Journal written in Russian.
• Inversion of the total routes basis for complex
  chemical reactions.
• Talyshinskii, R. M. Gadzhi-Kasumov, V. S.
  Rizaev, R. G. Akhundov, A. A.
• Guseinova, E. M.
• Dokl. Akad. Nauk Az. SSR, 1984, 40(10), 59-61.
• Journal written in Russian.
• Optimization of an adiabatic sectional reactor
  for oxidative dehydrogenation of
  isopentane-isoamylene mixtures.
• Aliev V. S., Akhundov A. A., Rizaev R. G.,
  Gadzhi-Kasumov V. S., Talyshinskii, R. M.,
  Bashirov N. A.
• Dokl. Akad. Nauk Az. SSR, 1984, 40(7), 61-64.
• Journal written in Russian.
• Kinetic analysis of a overall stoichiometric
  equation of catalytic single-stage oxidative
  dehydrogenation of n-butane to butadiene.
• Rizaev R. G., Gadzhi-Kasumov V. S., Talyshinskii
  R. M., Azizov A. G.
• Dokl. Akad. Nauk Az. SSR, 1984, 40(8), 58-61.
• Journal written in Russian.
• Mathematical model of one-step oxidative
  dehydrogenation of isopentane to isoprene.
• Aliev V. S., Akhundov A. A., Talyshinskii R. M.,
  Gadzhi-Kazumov V. S., Rizaev R. G., Bashirov N.
  A.
• Azerb. Khim. Zh., 1983, (4), 3-7.
• Journal written in Russian.
• Some features of the mechanism and selectivity of
  the single-stage dehydrogenation of n-butane to
  1,3-butadiene.

8
-8-

• R. G.
• Azerb. Khim. Zh., 1982, (5), 3-7.
• Journal written in Russian.
• Participation in Conferences
• 1. Mechanism of the single-stage oxidative
  dehydrogenation of butane to divinyl over oxide
  catalysts.
• Aliev V. S., Gadzhi-Kasumov V. S., Rizaev R. G.,
  Talyshinskii R. M., Seifullaeva Zh. M., Rodin, N.
  P.
• Proc. IV Intern. Congress Geterog. Katal., 1979,
  4th, Pt. 2 185-190.
• Journal written in Russian.
• 2. Mechanism of the single-stage oxidative
  dehydrogenation of paraffin hydrocarbons to
  dienes.
• Gadzhi-Kasumov V. S., Seifullaeva Zh. M.,
  Talyshinskii R. M., Rizaev R. G.
• Mekhanizm Katalit. Reaktsii. Materialy 3 Vses.
  Konf. Novosibirsk (1982), (Ch 1), 62-65. From
  Ref. Zh., Khim. 1982, 21B1288. Journal written
  in Russian. CAN 9852946 AN 198352946 CAPLUS
• 3. About mechanism of one-step
  oxidehydrogenation reactions of n-butane into
  divinyl over oxide catalysts.
• Talyshinsky R. M., Aliev V. S., Gadzhi-Kasumov V.
  S., Rizaev R. G.
• IV Intern. Congress on Heterogeneous Catalysis,
  Varna, 1979, p.185
• 4. Kinetic model of the single-stage oxidative
  dehydrogenation of n-butane to 1,3-butadiene.
• Aliev V. S., Gadzhi-Kasumov V. S., Rizaev R. G.,
  Talyshinskii R. M.
• USSR. Materialy 3-i Vses. Konf. po Kinet.
  Geterogen. Katalitich. Reaktsii, 1980, Kalinin,
  1980, (1), 9-16. From Ref. Zh., Khim. 1982,
  Abstr. No. 3B1809. Journal written in Russian.
  CAN 96181655 AN 1982181655 CAPLUS
• Kinetic model of one-step oxidehydrogenation of
  n-butane to divinyl over modified Catalyst
  L-8N-2.
• Talyshinsky R. M., Gadzhi-Kasumov V. S.

9
-9-

• Kinetic behaviors mechanism of
  oxidehydrogenation reactions of C4, C5 paraffins
  over composite oxide catalysts.
• Gadzhi-Kasumov V. S., Talyshinsky R. M.,
• XII Mendeleev Congress on overall applied
  Chemistry. Abstracts Lecture report, ? 3, - M.,
  Nauka.,1981, p.80-81
• 8. About single oxidative dehydrogenation
  reactions mechanism of paraffine carbohydrons to
  diens.
• Gadgi-Kasumov V. S., Talyshinsky R. M.
• Mater. III All Union Conf. Mechanism of
  catalytic reactions, v. 1, Novosibirsk, 1982, p.
  62-65.
• 9. Regeneration of the discharged Catalysts for
  oxidative dehydrogenation of hydrocarbons.
• Gadzhi-Kasumov V. S., Talyshinsky R. M., Rizaev
  R. G.
• I All Union meeting on the problems of catalytic
  deactivation. Deactivation of heterogeneous
  Catalysts by component reactions medium. Ufa,
  1985, p. 101-103
• 10 Modeling of multiroute reaction over fluid
  catalysts layer.
• Akhundov, A. A., Gadzhi-Kasumov V. S.,
  Talyshinsky R. M., Rizaev R. G.
• The 9 All Union. Conf. Khimreactor-9, vol.1.,
  Grodno,1986,p. 126-131
• 11. Control of concentration profiles of the
  supporting oxide catalyst components.
• Talyshinsky R. M., Rizaev R. G., Gadzhi-Kasumov
  V. S.
• III Czechs. Conf. on preparation
  characteristics of the heterogeneous Catalysts.
  Czechoslovakia, Bechin, 1988, p.132-133
• 12. Modification of multicomponent catalysts by
  electrolytic treatment of a support.
• Gadzhi-Kasumov V. S., Talyshinsky R. M., Rizaev
  R. G.
• Proceedings. Institute of Inorganic and Physical
  Chemistry. Azerbaijan Republic Academy of
  Sciences, Baku. Comp.Chemical processes and
  inorganic materials, ELM, 1991, p.16-22
• 13. Kinetic behaviors of Ammoxidation reaction
  of cyclohexanone.

10
-10-

• 15. Optimization of combined reactor system for
  hydrocarbon catalytic oxidehydrogenation.
• Talyshinsky R. M., Rizaev R. G., Akhundov, A. A.,
  Gadzhi-Kasumov V. S.
• XII International Conf. Khimreactor-12,
  Yaroslavl, 1994
• 16. Reactor for steam-phase Ammoxidation of
  cyclohexanone to adiponitrile.
• Talyshinsky R. M., Rizaev R. G., Akhundov, A. A.,
  Gasanov E. Sh.
• XII International Conf. Khimreactor-12,
  Yaroslavl, 1994
• 17. Influence of active components applying
  method on catalytic activity of carbon monoxide
  oxidation catalyst.
• Mardanova N. M., Talyshinsky R. M.
• II International Conf. of the Petrochemistry,
  Baku, 1996, p.186
• 18. Ammoxidation of Cyclohexane to adiponitrile
  over vanadium-containing oxide catalysts.
• Talyshinsky R. M., Rizaev R. G., Akhundov, A. A.,
  Gasanov E. Sh.
• Selective oxidations in petrochemistry, (Conf.
  DGMK Petrochem. Div., Goslar, Germany, 1992.
• 19. Activation of support in preparation of
  nickel-vanadium-antimony catalyst.
• Talyshinsky R. M., Rizaev R. G.
• III Russian. Conf. Yaroslavl, 1996. Preparation
  and Technology of Catalysts scientific
  Foundation. - CD-II, p.95
• 20. The influence of component application
  technique on the catalytic activity of carbon
  monoxide oxidation.
• Mardanova N. M., Talyshinsky R. M., Rizaev R. G
• II Int. Petrochemical Conference dedicated to the
  memory of the Academician Yu. G. Mamedaliev.
  Baku, June 18-21, 1996, p186
• 21. Three stages in the development of
  heterogeneous catalyst preparation technology for
  hydrocarbon oxidative transformation.

11
-11-

• Talyshinsky R M., Mardanova N. M, Litvishkov Yu.
  N., Muradova P. A., Godjaeva N. S., Processes of
  Petrochemistry and Oil Refining, 1 (12) 2003 p.
  74-87
• 24. Oxidative conversion of isobutane to
  isobutene over V-Sb-Ni oxide catalysts
• Vislovskiy V. P., Shamilov N. T. ,Sardarly A. M.
  ,Talyshinskii R. M., Bychkov V. Yu., Ruiz P.,
  Cortés Corberán V., Schay Z. and Koppany Zs.
  Applied Catalysis A General v 250 (1) 2003, p
  143-150
• 25. ?.?. ???????????, ?.?. ?????, ?.?. ????????.
  ?????????? ? ?????????? ?????????????????
  ???????????? ????????????? ?? ???????? ????????.
  ????? ? ?????????? ?????? ? ?????, 1, 2005, 40-43
• 26. ?.?. ???????????, ?.?. ?????, ?.?. ????????,
  ?.?. ????????. ???????????? ??????? ????????????
  ????????????? ??? ?????????? ????????????. ?????
  ? ?????????? ?????? ? ?????, 1, 2006, 35-37.
• .? ??.
• ??????????? ? ??????? ????????????
  ?????????????????
• 1. ??????????????? ??????????????? ?????????? ?
  ?????????????? ????????????????????? ????
• ??? ???????? ?????????? ?????? ? ????????????????
  ???????? ????????????? ??????, ?????????? ?
  ??????????? ??????? ???? ???????.
  ???????????????? ????????????? ????? ??????????
  ???????????? ????????? ?????????????? ??
  ???????????
• Patent Russia (SU) 1669861, registr.1991
• 2. ????? ???? - ????????? ???????, ???
  ???????????? ??????????? ????????????? ??????
  ????????? ?????
• Kinet. Catal. (Transl. of Kinet. Katal.), 1996,
  37(1), 90-97.
• 3. ?????? ??????? - ????????? ???????????,
  ?????????? ?? ?????-????? ???????? ??? ?????????
  ?????????????? ?????????????? ?-??????,
  ?????????? ? ??????????? ? ???????????????
  ???????? ?????????????? ??????? (?? ????
  ??????????).
• ???????? ?????? ??????????????? ??????????????
  ??????? ? ?????????? ??????????
• ?????????? ? ??????? ?????? ?????? ??????????
  ???????????? ? ?????? (?? ?????? ????????????
  ?????????????????? ????????? ???????????? ?????
  ????????????? ????????).

12
-12-

• ???????????????? ????????
• ????????????????? ???????, ???????
  ??????????????? ???????, ???????? ? ???????,
  ?????????? ???????????? ?????????????,
  ????????????????? ????????? ??????????????
  ???????????, ?????????? ???????.
• ???????? ?????????????? ????????
• ??? ???? ?????????????, ?????????????????,
  ???????????? ????????????? ??????????????
  ?????????, ??????????????????? ??????,
  ??????????? ???????????.
• ????? ???????, ????????, ??????????, ?????.