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Low-temperature Catalytic Depolymerization

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Title: Low-temperature Catalytic Depolymerization


1
Low-temperature Catalytic Depolymerization
  • Power and diesel fuel generation from Waste
    Plastics, Tyres and Waste Oils

2
Topics
  • Company Profile
  • Depolymerization Technology
  • Depolymerization Advantages
  • Applications for Utilization of Synthetic Oil
  • Depolymerization Unit
  • Utilization of Synthetic Polyfuel Oil

3
Company Profile
Complete Waste Processing with environmentally
friendly technologies
Waste sorting
Municipal waste
Depolimerization
Gasification
Waste heat utilization and electricity prod.
GTE International Holding Company deals with
green energy plants, waste treatment-, municipal
waste management projects and the supply of the
necessary technology and equipment. Our company
executes the local and international
consultations, sales and supplies through our
sales partner.
4
  • Main activities of GTE International Holding
    Company
  • Supply of environmentally friendly technologies
  • Project management and implementation on which
    the plant has to be built. Examination of the
    context and analysis.
  • Pre-feasibility study this study assesses
    whether the project is actually feasible,
    considering the potential obstacles and the
    technical and economic opportunities.
  • Detailed feasibility study this definitive
    document indicates whether the project can really
    be realized, considering all the conditions and
    assessing the sustainability of the system and
    technology.
  • Plant design precise definition of all the plant
    components of the relevant technology. This
    includes mechanical-, electric-, and functional
    drawings, plans and flow charts are drawn up for
    the construction, installation and commissioning
    of the plant.

5
  • Main activities of GTE International Holding
    Company
  • Authorization and permits obtaining of the
    authorization for the installation of the plant
    built in compliance with the relevant legal
    requirements from the competent local
    authorities.
  • Project financing the availability of the
    financial resources needed for the realization of
    a project is the crucial factor in the decision
    making. We are able to support our clients in
    this stage by introducing potential financing
    sources.
  • Supply of technology the machinery will be
    delivered on time with the contracted deadlines.
  • Installation, commissioning, acceptance and
    maintenance

6
Depolymerization Technology
Waste plastics and tires are long-chain polymers,
containing more than 50,000 carbon atoms,
directly linked by the cross-link or branched
chains. Depolymerization decomposes the
long-chain to shorter chains.
Depolymerization is the process of the molecular
decomposition, larger molecules are cracking to
smaller molecules.
7
Depolymerization Technology
  • The result is the generation of
  • Poly-fuel - green synthetic (fuel) oil
  • Poly-carbon - soot (carbon black)
  • Poly-gas - synthetic gas
  • Environmentally friendly, dealing with the
    comprehensive issue of waste disposal
  • Energetically independent, using the input
    material for its own operation, while at the
    same time it is possible to generate electric
    power and heat (CHP) and comprehensively -
    ecologically and energetically utilize waste
    polymers

8
Depolymerization Unit
The thermal decomposition means chemical
breakdown of polymer chains at oxygen-poor or
oxygen-free environment in a properly designed
reactor. In this way, the energy content of
plastic waste is recovered better efficiency.
Also a big advantage is that the resulting
liquid, gas and solid products can utilize as
primarily energy source and secondly the chemical
industry can use as secondary raw materials.
9
Depolymerization Unit
  • Technology Benefits
  • Lower reaction temperature, ranging from the
    minimum of 275 C up to 445 C at maximum
    (depending on the type of the input material)
  • Synthetic oil recovery ratio higher by 10
    compared to other technologies
  • Process with zero emissions no damage to
    environment
  • Shorter reaction time and larger power savings
  • Optimum conversion of polymer waste to
    hydrocarbon fluid with negligible trace of wax
  • The most modern cleaning systems ensuring that
    the content of sulphur in the synthetic oil to be
    lower than 75 ppm
  • Patented highly effective catalyst with very
    low impacts for production process
  • Continuous production process with lower demand
    for labour and operators and more

10
Benefits of Depolymerization Process
  • Low-temperature catalytic depolymerization of
    plastics, oils and tires offers the following
    benefits
  • generates quality fuel with near-zero emissions
  • facilitates to solve the issue of the soil
    pollution with plastic, oils and tires
  • recovers energy from the waste
  • helps to recycle the carbon with its subsequent
    utilization.
  • The waste breaks down to utilizable end products
    synthetic oil, gas and soot

11
Depolymerization input-output ratios
  • Conversion of waste plastic and tyres to
    synthetic oil, soot and synthetic gas
  • The unit converts polymers to precious fuels.
  • Technology yield, input, output ratios

12
Types and Labels Waste Plastics
13
Depolymerization of Plastics, Tyres and Waste
Oils
  • Input material suitable for Depolymerization
  • Waste plastics
  • Mixed plastics (HDPE, LDPE, PE, PP, nylon,
    teflon,
  • PS, ABS, FRP, etc.)
  • Layered plastic
  • Waste tyres
  • Rubber
  • Plastic and rubber parts of
  • transport vehicles
  • Waste engine oils, industrial oils

14
Polyfuel Synthetic Oil Typical Industrial
Applications for the Use of Pyro-fuel as Fuel
  • Produced oil has the same specifications as light
    diesel oil (LDO)
  • LDO boilers (industrial boilers, central heating
    plants)
  • CHP - Diesel aggregates (cogeneration units for
    producing electricity heat)
  • Vapour, hot water and hot air generators
  • Burners with a heat bed
  • Electric power generator (mixing with 50
    diesel)
  • Diesel pumps (mixing with 50 of diesel)

15
Basic Functions of the UnitUnit Operating
Condition
  • Temperature in the reactor ranging from the
    minimum of 275C to 445C at maximum
  • Depolymerization of plastics/tyres/oils in an
    oxygen starved atmosphere
  • Permanent inlet and outlet of input and output
    products
  • Cleaning of synthetic oil, hydrocarbon gases and
    fuels as a prevention of soiling

16
The Unit consists of
  • Input material preparation unit
  • Grinding machine for tyres/plastic
  • Feeding transporters
  • Bucket conveyor of material to receiver
  • Dosing system of fuel and catalyst
  • Depolymerization reactors
  • System for heating the reactors by gas
  • Airing systems, solid residue removal
  • Cleaning and condensing system
  • Condensers, tanks
  • Dry scrubber gas cleaning system
  • Fuel tanks for synthetic oil storage
  • Gas containers for synthetic gas
  • System of filtration and wax removal
  • Cooling tower, vacuum pump, etc.
  • Control panel and safety system
  • Remote monitoring

17
Synthetic Oil Usage
  • Main usage and types
  • Electric power and heat generation
    (cogeneration), industrial processes, heating,
    vapour production
  • Refining production of diesel, petrol and
    marine diesel
  • Usage as chemical raw material

18
Synthetic Oil Usage
  • Electric Power Generation
  • Combusting synthetic oil in cogeneration units
    CHP
  • Conversion to electric energy with high
    efficiency of approx. 38 41,5 ,
  • heat efficiency 45 - 49, Green Machine ORC
    modules for the utilization of heat
  • Performance rage from 80 kW to 3 000 kW.
  • Cogeneration unit suppliers Dresser-Rand,
    Caterpillar, Cummins, Perkins, Volvo

19
Synthetic Oil Usage
  • Industrial Processes
  • Thermo-oil boilers
  • Central heating,
  • Hot water production, vapour generation

20
Synthetic Oil Usage
  • Refining in Refineries
  • Production diesel, gasoline and fuel oil
    sale and distribution

21
Thank you for your attention Contact GTE-Inte
rnational Holding Company.Hungary -
EuropeCellular phone 36 30 620 1369 Email
szp_at_gte-international.comwww.gte-international.co
m
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