Title: Home%20Work%208%20(Electrode)
1Home Work 8 (Electrode)
2Ranking of Proj.
- 2007102856 ???
- 2005200439 ???
- 2007102854 ???
- 2004200459 ???
- 2004200456 ???
3About Electrode
???? - ?? ????? ?? - NaCl ??? ??
Anode
Cathod
4About Electrode
- ?? ???
- - ??
- ??? ??? to
- ??? ?? ? - to
- ?????
- ??? ??? to
- ??? ?? ? - to
i
?? ??? ?? ?? ??? ??
Anode
Cathod
5Charge double layer
?? - ??? ?????
Halfcell potential(contact potential)
Ehd
Ehd
? ??? Charge double layer(????)??. Ehd?
Halfcell potential ??. Charge double layer?
????? ??? ???? ??? electrod circuit?? ?? ??? ???
??.
Charge double layer
????
6Charge double layer
Cd
Rs
Ehc
Rd
Ehc? ?? ? ??? Cd? ? ??
Polarizable electrode Pt, Ag, Au, Cu ?
Cd
Rs
Ehc
Capacitive
Motion artifact? ??.
7Charge double layer
Ehc? ?? ? ??? ??? Cd? ?? ??
Nonpolarizable electrode Ag AgCl ??
Calomel ??
Resistive
Motion artifact? ??.
(??? ?? ???? ??? ??? ?? ??.) (?? ??? AgCl ??? ?
???? ?? ??.)
8Charge double layer
1mV- 0mV-
501mV- 500mV-
ECG electrode circuit
DC Level ? ?? ??? Overloading? ??? ? ??. ??? HPF?
????.
9Half cell potential
Half cell potential? ? ???? ??? ??? ? ??.
??? ???? ?? Charge double layer? ??? ??? ? ??. ?
??? Half cell potential? ???? ??? ? ??. ???
electrod AgCl? little half cell potential ? ???
?? ??? electrod AgCl ? ???? ??.
10Ag-AgCl electrode
t
I
Ag
Ag
Ag
Anode
AgCl Coating
Cathod
KCl solution
??
AgCl ?? ??? I , t ? ??
11Real circuit of electrode
Sponge with NaCl
12Real circuit of electrode
13Real circuit of electrode
C
Multimeter
R
Z
Z R jX
14Real circuit of electrode
????? ?? ( )
Impedance Analyzer
Impedance Spectrum
R
0.707R
Frequancy Sweeping
15Real circuit of electrode
??
??
Resistance Reactance
Impedance
16Real circuit of electrode
17Real circuit of electrode
Cd
Cd
Rs
Rs
Rd
Rd
Rd Rs
Rs
18Real circuit of electrode
?? ???? ??? ??
Cd
Ps
Rd
??? Cd? open ?? ??? Rd Ps ? ??.
?? ????? Rs? AC? ?? Cd? short ??? ? ??? Rs? ??.
19Real circuit of electrode
Nonpolarizable electrode ? ??
Ag AgCl
Rd Rs
AgCl ?? ????
???? ?? ????? ??? ???. Resistance Electrode
20Real circuit of electrode
Polarizable electrode ? ?? (Pt ??)
Pt
21Real circuit of electrode
??? ?? ?? ?? ? ???? ??? ?? ???? ?? ???
????. ??? ?? ?? ?? ? ???? ??? ?? ???? ??
?? ??? ???. ??? ?? ?? ?? ? ???? ??? ??
???? ?? ?? ??? ???, ??? ?? ?? ?? ?
?? ????? ?? ? ?? ????. ?, ???? ???? ?? ??
???? ?? ???? ?? ?? ??? ??? ?? ????? ? ? ??. ??
??? ??? ?? ??? ?????, ???? ??? ? ????? ??? ???
??? ???? ?????? ??? ???? ???? ????. ??? ?? ???
??? ????? ??? ? ?? ???.