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Review

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Title: PowerPoint Author: xfjin Last modified by: Administrator Created Date: 9/3/2002 6:49:44 AM Document presentation format: – PowerPoint PPT presentation

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Title: Review


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  1. Review
  2. Applications

2006-12-6
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  • Heat is energy that is transferred from one body
    to another because of a difference in temperature.

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  • dUdQdW

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  • Molar Specific Heats
  • QnCv?T (Cvmcv/n)
  • QnCp?T (Cpmcp/n)

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for the same ?T Qv?U (dUdQ-PdV)
Qp?UP?V Qp-QvP?V nCp?T-nCv?TP(nR ?T/P)
Cp-CvR
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  • an ideal monatomic gas
  • Qv?U
  • Because U3nRT/2
  • Thus ?U3nR?T/2nCv?T
  • Or Cv3R/2

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Adiabatic expansion dUdQ-PdV-PdV (since
dQ0) on the other hand dUnCv?T so nCv?T
PdV0 From PVnRT, we have PdVVdPnRdT and
nCv(PdVVdP)/nR PdV0 or (CvR)PdVCvVdP0
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Since CpCvR So CpPdVCvVdP0 Or
(Cp/Cv)PdVVdP0 Define ? Cp/Cv dP/P
?dV/V0 lnP ?lnVC Therefore PV?C
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