Fourier transform (see Cowley Sect. 2.2) - PowerPoint PPT Presentation

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Fourier transform (see Cowley Sect. 2.2)

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Title: PowerPoint Presentation Author: Earle Ryba Last modified by: Earle Ryba Created Date: 1/10/2005 1:27:36 PM Document presentation format: On-screen Show – PowerPoint PPT presentation

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Title: Fourier transform (see Cowley Sect. 2.2)


1
Fourier transform (see Cowley Sect. 2.2)
2
Fourier transform (see Cowley Sect. 2.2)
3
Fourier transform (see Cowley Sect. 2.2)
4
Fourier transform (see Cowley Sect. 2.2)
5
Fourier transform
6
Fourier transform
7
Fourier transform
8
Fourier transform
9
Scattering of x-rays by single electron (Thomson)
(see Cowley sect. 4.1)
10
Scattering of x-rays by single electron (Thomson)
(see Cowley sect. 4.1)
11
Scattering of x-rays by single electron (Thomson)
12
Scattering of x-rays by single electron (Thomson)
13
Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
14
Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
Can define an atomic scattering factor
15
Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
Can define an atomic scattering factor
For spherical atoms
16
Scattering of x-rays by single atom
Need to find ?(r) . A QM problem But soln for
f(?) looks like this (in electron scattering
units)
17
Dispersion - anomalous scattering
Have assumed radiation frequency gtgt
resonant frequency of electrons in atom
frequently not true
18
Dispersion - anomalous scattering
Have assumed radiation frequency gtgt
resonant frequency of electrons in atom
frequently not true Need to correct
scattering factors f fo f' i f"
19
Dispersion - anomalous scattering
Need to correct scattering factors f fo f'
i f"
5
f"
???K
1
2
f'
20
Atom assemblies
(see Cowley sect. 5.1)

21
Atom assemblies
(see Cowley sect. 5.1)

For this electron density, there is a Fourier
transform
F(u) is a fcn in reciprocal space
22
Atom assemblies
(see Cowley sect. 5.1)

23
Atom assemblies

24
Atom assemblies
For single slit, width a g(x) 1

If scatterer is a box a, b, c
25
Atom assemblies
For single slit, width a g(x) 1

If scatterer is a box a, b, c
For periodic array of zero-wiidth slits
26
Atom assemblies

This requires ua h, an integer. Then
Finally
27
Atom assemblies

This requires ua h, an integer. Then
Finally
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