Title: Fourier transform (see Cowley Sect. 2.2)
1Fourier transform (see Cowley Sect. 2.2)
2Fourier transform (see Cowley Sect. 2.2)
3Fourier transform (see Cowley Sect. 2.2)
4Fourier transform (see Cowley Sect. 2.2)
5Fourier transform
6Fourier transform
7Fourier transform
8Fourier transform
9Scattering of x-rays by single electron (Thomson)
(see Cowley sect. 4.1)
10Scattering of x-rays by single electron (Thomson)
(see Cowley sect. 4.1)
11Scattering of x-rays by single electron (Thomson)
12Scattering of x-rays by single electron (Thomson)
13Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
14Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
Can define an atomic scattering factor
15Scattering of x-rays by single atom
For n electrons in an atom, time-averaged
electron density is
Can define an atomic scattering factor
For spherical atoms
16Scattering of x-rays by single atom
Need to find ?(r) . A QM problem But soln for
f(?) looks like this (in electron scattering
units)
17Dispersion - anomalous scattering
Have assumed radiation frequency gtgt
resonant frequency of electrons in atom
frequently not true
18Dispersion - anomalous scattering
Have assumed radiation frequency gtgt
resonant frequency of electrons in atom
frequently not true Need to correct
scattering factors f fo f' i f"
19Dispersion - anomalous scattering
Need to correct scattering factors f fo f'
i f"
5
f"
???K
1
2
f'
20Atom assemblies
(see Cowley sect. 5.1)
21Atom assemblies
(see Cowley sect. 5.1)
For this electron density, there is a Fourier
transform
F(u) is a fcn in reciprocal space
22Atom assemblies
(see Cowley sect. 5.1)
23Atom assemblies
24Atom assemblies
For single slit, width a g(x) 1
If scatterer is a box a, b, c
25Atom assemblies
For single slit, width a g(x) 1
If scatterer is a box a, b, c
For periodic array of zero-wiidth slits
26Atom assemblies
This requires ua h, an integer. Then
Finally
27Atom assemblies
This requires ua h, an integer. Then
Finally