Title: Mineral%20resources
1Mineral resources
- Minerals or rocks mined from the earth and used
in the products we use daily. - Coal, oil, and natural gas are also mined, but
these energy resources will be considered
separately.
2The use of minerals and rocks in products
- Sometimes actual minerals and rocks are used in
products or to make things. The rock granite is
mined to make countertops, and the mineral halite
is mined, crushed, and sold as table salt. - Other times, minerals and brines are processed to
extract one specific element, and these
individual elements are often called mineral
commodities. For example, the commodity aluminum
is extracted from the rock bauxite, which
contains aluminum-bearing minerals like gibbsite.
- The process of extracting the desired mineral or
element from an ore is called beneficiation.
3Minerals
- solid
- inorganic (or identical to an inorganic mineral)
- natural (or made in a way that mimics nature)
- chemically homogeneous (that is, the mineral
contains the same chemicals throughout) - crystalline (the atoms in a mineral are arranged
in an orderly and repeating pattern)
4Examples of minerals
Mineral Quartz Hematite Diamond Halite
Chemical formula SiO2 Fe2O3 C NaCl
Elements in these minerals Si silicon, O oxygen (two oxygen atoms for every one silicon atom) Fe iron, O oxygen (two iron atoms for every three oxygen atoms) C carbon Na sodium, Cl chlorine
Crystal structures
5NOT minerals
The "minerals" in these vitamins and minerals
are not real minerals. These are elements that
may have been extracted from minerals.
6Common elements and common minerals
- Minerals are comprised of elements.
- Eight elements make up the majority of Earth's
crust and mantle
Whats within the crust (by mass)
Elements in the crust Mass
Oxygen (o) 46.6
Silicon (Si) 27.72
Aluminum (Al) 8.13
Iron (Fe) 5.00
Calcium (Ca) 3.63
Sodium (Na) 2.83
Potassium (K) 2.59
Magnesium (Mg) 2.09
Common metals (Al,Fe,Ca, Na, K, Mg)
All others
Oxygen
Silicon
7Common elements and common minerals
- These elements can combine in a variety of ways
to make different minerals. - Most minerals contain silicon and oxygen (plus
other elements). These minerals are called
silicate minerals.
Crystal structure of almandine garnet (Fe3 Al2
Si3 O12 ) containing iron and aluminum in
addition to silicon and oxygen.
8Common elements and common minerals
- Why do we care about this?
- Sustainability The eight elements just listed
are the most plentiful. Other elements are more
rare we find them less frequently and have a
lower overall supply of them. - Ease of use Silicate minerals tend to be
refractory they have high melting points and low
solubilities, so they hold onto the elements
within them. - Although the majority of Earths elements are
found in silicate minerals, they are usually
found in higher quantities in nonsilicate
minerals, commonly oxide or sulfide minerals. It
is more efficient to mine elements when they are
found in higher concentrations.
9If we want the element in the mineral (and not
the mineral itself), then we seek nonsilicate
minerals that contain the element, because it is
easier (fewer resources are needed) to extract
those elements from the mineral. For example,
although the silicate mineral fayalite (Fe2SiO4)
contains iron (Fe), it is easier and more
efficient to extract iron from hematite (Fe2O3),
which is a nonsilicate mineral.
Fayalite. Not an economic source for iron,
though it contains iron.
Hematite. Iron is commonly extracted from this
mineral.
10Mineral properties
- A mineral's chemical and crystalline nature gives
it properties that make it useful. - These properties also must be considered when
determining how best to mine, process, and
dispose of the mineral and mine waste.
11Mineral properties Chemistry
- The elements within minerals give them distinct
and useful properties.
- For example
- Sulfur allows gunpowder to ignite at a lower
temperature and provides fuel for the fire.
Sulfur can be found as a mineral (native sulfur,
S)
Sulfur can also exist as an element within other
minerals like pyrite (FeS).
12Mineral properties Chemistry
Aluminum alloys were extensively used for
constructing Apollo 16 whose Command and Service
Module (CSM) "Casper" is shown here
- For example
- Aluminum metal is very lightweight but strong.
Aluminum does not form a mineral on its own, but
is beneficiated from the minerals gibbsite and
bohemite.
13Mineral properties Hardness
- A mineral's hardness is determined by
- The crystalline nature of that mineral,
- The type and strength of bonds that hold the
atoms together, and, - The nature of the repeating pattern
Both graphite and diamond are made up of the same
element, carbon (C). However, diamond is much
harder than graphite.
Crystal structure for graphite
Crystal structure for diamond
14Mineral properties Hardness
- For example
- Very hard minerals (like diamond, corundum, and
garnet) are useful as abrasives. Saw blades
impregnated with diamonds can cut rock, and
sandpaper is often made with garnet sand.
Almandine garnet crystals. Hardness of almandine
garnet is 78 On the Mohs scale of hardness
Talc (hardness 1 on the Mohs scale of
hardness) is used in baby powder because it is a
very soft mineral.
15Mineral properties Color
- Some minerals have distinct, and vibrant, colors.
This makes them incredibly useful as pigments in
paints, cosmetics, colored plastic, etc.
The rust red color of hematite (left) and rust
yellow color of limonite ( a variety of goethite,
right) have long been used as a pigment.
Malachites green color has made it useful in
paints
16Mineral properties Color
For example The native people in Himba Village,
Namibia, powder iron oxide minerals (like
hematite and goethite) to color their skin and
hair.
17Mineral properties Specific gravity
- Specific gravity is a relative density,
determined both by a mineral's chemistry
(minerals containing heavier elements will have
higher specific gravities) and how closely
together the atoms are packed.
Galena (PbS) contains the heavy element lead,
giving it a high specific gravity
18Mineral properties Behavior of light in the
crystal
- The crystalline structure determines if and how
light passes through a mineral. For example,
light reflects inside of diamond, which gives
diamond ring an exquisite sparkle. - Other minerals (like rutile) are quite opaque,
which makes titanium oxide (the chemical name of
rutile) an important additive in things that need
to be opaque, like paint. - Some minerals are also useful in blocking other
wavelengths of light barite and lead (from the
mineral galena) block X-rays, for example.
The crystalline structure of calcite (Iceland
spar variety) can split light rays passing
through it, making the horizontal lines seen
through the calcite crystal appear to double up
in this photo. Iceland Spar crystals were once
used in polarizing microscopes and telescopes
because of this property.
19Mineral properties Luster
- Luster describes how light interacts with the
surface of a mineral. - For example, the mineral hematite can have both
metallic or nonmetallic luster hematite with
metallic luster (photo on left) is used to make
jewelry.
20Mineral properties Crystal shape and cleavage
- These are determined by the nature of the
crystalline structure. The sheet-like cleavage of
muscovite allows it to be broken into tiny pieces
of glitter.
Muscovites cleavage causes it to break into
sheets.
21Mineral properties Solubility
- Different minerals dissolve differently depending
on their crystalline structure (the type of
bonds) and chemistry. When a mineral dissolves,
it breaks into the ions that it contains. - Some dissolve quickly in water (or acidic or
alkali solutions), whereas others are very
stable.
For example, people eat tablets made of calcite
that calcite dissolves in the stomach,
neutralizing some of the acid and reducing
heartburn
TUMS tablet dissolving in acidic water releasing
bubbles of carbon dioxide.
22Mineral properties Solubility
- For some applications, an insoluble mineral is
preferred. For example, the Eads Bridge that
crosses the Mississippi River is faced with rock
made of insoluble minerals below the water line,
whereas more decorative limestone (made of the
more soluble mineral calcite) faces the support
above the water line. - If a mineral is being mined from the element it
contains, then it will be easier to extract that
element from a soluble mineral.
23Mineral properties Magnetism
- The chemistry of certain minerals allows them to
store an applied magnetic field. For example,
magnetic minerals in a hard drive can be
programmed to store information.
A bar magnet hanging from a sample of magnetite.
Magnetite is an iron oxide (Fe3O4), and is
naturally magnetic.
24Mineral properties Electrical conductivity
- Electrical conductivity is mainly determined by
the presence of metallic bonds. Metals have these
bonds, which is why metals are favored for wires.
Coppers electrical conductivity and resistance
to corrosion make it ideal for electric wiring.
Copper can be found as a pure metal (native
copper, Cu)
Copper is often beneficiated from minerals like
chalcopyrite (CuFeS2).
25Mineral properties Electrical conductivity
- Minerals that have low electric conductivity will
be used for insulators, which block and/or
confine the electric current.
Clay minerals such as kaolinite show very low
electrical and thermal conductivity.
Ceramic insulators made from clay minerals are
used for supporting electric power lines
26Mineral properties Thermal conductivity
- Minerals can also be used to conduct or confine
heat. Thermal conductivity is determined by both
a minerals chemistry and crystalline structure
Ceramic kitchen utensils made from clay minerals
are used to confine the temperature of food and
beverages
Clay minerals such as kaolinite show very low
electrical and thermal conductivity.
27Mineral properties Melting point
- Different minerals melt at different
temperatures. Minerals with high melting points
are used for high-temperature applications.
For example, the mineral graphite is used for
lining furnaces and as crucibles for melting
metals
28Mineral properties Response to stress
Different minerals/rocks behave differently under
stress. For example, while many minerals will
shatter if hit with a hammer, gold is malleable.
This allowed early people to easily shape it into
ornaments.
- Piezoelectricity is another property related to
stress. An electric current is generated in
piezoelectric minerals when a stress is applied. - For example, a hammer hits a piezoelectric
crystal, and this will generate a spark to ignite
a cigarette lighter. The piezoelectricity of
quartz allows it to be used to tell time (in
quartz crystal watches), and piezoelectricity is
also useful in transformers and motors.