Title: ?????????(ATRP)
1?????????(ATRP)
- Atom Transfer Radical Polymerization
??? ??
2?ATRP????
1995 ??????????????????(Carnegie2Mellon)
???????????????????????(A tom Transfer Radical
Polymerization , ??ATRP) , ????????????????,
?????????????????????????????????????????
3??????12??????????, ????????(bpy) ?????????,
?130???????(St) ????????3h ????95????????????????
???????????, ???????????????????????????,
?????????
??RX ?????? BPY ?2 , 2 '2 ????? CuX ?????
4?ATRP?????
Mn?n????????? M ??? R-X????(?????)Mn t
??????????? Mn 1t ??????????? R-M