Title: Ions in Aqueous Solution
1Ions in Aqueous Solution
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Pb(NO3)2(s)
Pb(NO3)2(aq)
H2O(l)
Pb2(aq) 2 NO31(aq)
add water
in solution
dissociation
NaI(s)
H2O(l)
NaI(aq)
Na1(aq) I1(aq)
Mix them and get Balance to get overall ionic
equation Cancel spectator ions to get net ionic
equation
2Ions in Aqueous Solution
Solubility Chart
Pb(NO3)2(s)
Pb(NO3)2(aq)
H2O(l)
Pb2(aq) 2 NO31(aq)
add water
dissociation
NaI(s) NaI(aq)
H2O(l)
Na1(aq) I1(aq)
Mix them and get Balance to get overall ionic
equation Cancel spectator ions to get net
ionic equation
3Solubility Chart
Mix them and get
solid
in solution
Balance to get overall ionic equation
Cancel spectator ions to get net ionic equation
4Solubility Chart
Mix together Zn(NO3)2(aq) and Ba(OH)2(aq)
Mix them and get
Ba(OH)2(aq)
Zn(NO3)2(aq)
Zn2(aq) 2 NO31(aq)
Ba2(aq) 2 OH1(aq)
Balance to get overall ionic equation
Cancel spectator ions to get net ionic equation
5- Pre-lab
- 1. What ions are present in the following
solutions? - NaCl(aq) ? ____________________ AgNO3(aq)
? ____________________ - When these solutions are mixed together, a
precipitate is seen. What are the new
combinations of ions that could have formed the
precipitate? - ____________________ and ____________________
- Using the solubility table, which new combination
will form a precipitate? - ____________________ ?
- Which new combination will remain in solution?
- ____________________
- 5. Write the overall reaction equation for this
reaction. Be sure to indicate the correct phase
(reaction condition) for each reactant and each
product.
Na1(aq)
Cl1-(aq)
Ag1(aq)
NO31-(aq)
Na1(aq)
Cl1-(aq)
Ag1(aq)
NO31-(aq)
Cl1-(aq)
Ag1(aq)
AgCl(s)
Na1(aq)
NO31-(aq)
Na1(aq)
Cl1-(aq)
Ag1(aq)
NO31-(aq)
Na1(aq)
NO31-(aq)
AgCl(s)
Cl1-(aq)
Ag1(aq)
AgCl(s)
When the cations switch places they end with a
hydroxide (no new combination is formed)
6Reactions Between Ions in Aqueous Solutions
Key
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spectator ions
2. Co2(aq) 2 NO31-(aq) 2 K1(aq)
2 OH1-(aq) Co(OH)2(s) 2 K1(aq)
2 NO31-(aq)
7Reactions Between Ions in Aqueous Solutions
Key
15. Cu2(aq) 2 NO31-(aq) 2 K1(aq)
2 OH1-(aq) Cu(OH)2(s) 2 K1(aq)
2 NO31-(aq)
Cu2(aq) 2 OH1-(aq) Cu(OH)2(s)
16. Cu2(aq) 2 NO31-(aq) 2 Na1(aq)
2 OH1-(aq) Cu(OH)2(s) 2
Na1(aq) 2 NO31-(aq)
Cu2(aq) 2 OH1-(aq) Cu(OH)2(s)
20. Fe3(aq) 3 Cl1-(aq) 3 K1(aq)
3 OH1-(aq) Fe(OH)3(s) 3 K1(aq)
3 Cl1-(aq)
Fe3(aq) 3 OH1-(aq) Fe(OH)3(s)
21. Fe3(aq) 3 Cl1-(aq) 3 Na1(aq)
3 OH1-(aq) Fe(OH)3(s) 3 Na1(aq)
3 Cl1-(aq)
Fe3(aq) 3 OH1-(aq) Fe(OH)3(s)
24. Co2(aq) 2 Cl1-(aq) 2 K1(aq)
2 OH1-(aq) Co(OH)2(s) 2 K1(aq)
2 Cl1-(aq)
Co2(aq) 2 OH1-(aq) Co(OH)2(s)
25. Co2(aq) 2 Cl1-(aq) 2 Na1(aq)
2 OH1-(aq) Co(OH)2(s) 2 Na1(aq)
2 Cl1-(aq)
Co2(aq) 2 OH1-(aq) Co(OH)2(s)
8TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER
aluminum ss s n s n i s s i s d
ammonium s s s s s s s s s s s
barium s s i s i s s s i i d
calcium s s i s s ss s s i ss d
copper (II) s s i s i i n s i s i
iron (II) s s i s n i s s i s i
iron (III) s s n s i i n s i ss d
lead s ss i ss i i ss s i i i
magnesium s s i s s i s s i s d
mercury (I) ss i i i ss n i s i ss i
mercury (II) s ss i s ss i i s i d i
potassium s s s s s s s s s s s
silver ss i i i ss n i s i ss i
sodium s s s s s s s s s s s
zinc s s i s s i s s i s i
chromate
hydroxide
bromide
carbonate
chloride
nitrate
phosphate
sulfate
sulfide
acetate
iodide
Legend
SOLID SOLID AQUEOUS
i insoluble ss slightly soluble s
soluble d decomposes n not isolated
9TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER
aluminum s aq n s n s aq aq s aq d
ammonium aq aq aq aq aq aq aq aq aq aq aq
barium aq aq s aq s aq aq aq s s d
calcium aq aq s aq aq ss aq aq s s d
copper (II) aq aq s aq s s n aq s aq s
iron (II) aq aq s aq n s s aq s aq s
iron (III) aq aq n aq s s n aq s s d
lead aq s s ss s s s aq s s s
magnesium aq aq s aq aq s aq aq s aq d
mercury (I) s s s s s n s aq s s si
mercury (II) aq s s aq s s s aq s d si
potassium aq aq aq aq aq aq aq aq aq aq aq
silver s s s s s n s s s s s
sodium aq aq aq aq aq aq aq aq aq aq aq
zinc aq aq s aq aq s aq aq s aq s
chromate
hydroxide
bromide
carbonate
chloride
nitrate
phosphate
sulfate
sulfide
acetate
iodide
Legend
s solid aq aqueous d decomposes n not
isolated
10TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER TABLE OF SOLUBILITIES IN WATER
aluminum s aq n s n s aq aq s aq d
ammonium aq aq aq aq aq aq aq aq aq aq aq
barium aq aq s aq s aq aq aq s s d
calcium aq aq s aq aq ss aq aq s s d
copper (II) aq aq s aq s s n aq s aq s
iron (II) aq aq s aq n s s aq s aq s
iron (III) aq aq n aq s s n aq s s d
lead aq s s ss s s s aq s s s
magnesium aq aq s aq aq s aq aq s aq d
mercury (I) s s s s s n s aq s s si
mercury (II) aq s s aq s s s aq s d si
potassium aq aq aq aq aq aq aq aq aq aq aq
silver s s s s s n s s s s s
sodium aq aq aq aq aq aq aq aq aq aq aq
zinc aq aq s aq aq s aq aq s aq s
chromate
hydroxide
bromide
carbonate
chloride
nitrate
phosphate
sulfate
sulfide
acetate
iodide
Legend
s solid aq aqueous d decomposes n not
isolated