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Our purpose of well studies

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... Langmuir Adsorption Isotherm If C/C* vs. C is a straight line: C/C* = 1/( 1 2) + C/ 2 C = equilibrium concentration of the ion in contact with the soil ... – PowerPoint PPT presentation

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Title: Our purpose of well studies


1
Our purpose of well studies
  • Compute the decline in the water level, or
    drawdown, around a pumping well whose hydraulic
    properties are known.
  • Determine the hydraulic properties of an aquifer
    by performing an aquifer test in which a well is
    pumped at a constant rate and either the
    stabilized drawdown or the change in drawdown
    over time is measured.

2
Drawdown
  • T Q/ 4?(h0-h)G(u)
  • G(u)
  • W(u) - completely confined.
  • W(u,r/B) leaky, confined, no storage.
  • H(u,?) leaky, confined, with
    storage.
  • W(uA,uB,?) - unconfined.

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Aquifer test
  • Steady-state conditions.
  • Cone of depression stabilizes.
  • Nonequilibrium flow conditions.
  • Cone of depression changes.
  • Needs a pumping well and at least one
    observational well.

5
Aquifer tests
  • T Q/ 4?(h0-h)G(u)
  • G(u)
  • W(u) - completely confined.
  • W(u,r/B) leaky, confined, no storage.
  • H(u,?) leaky, confined, with
    storage.
  • W(uA,uB,?) - unconfined.

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9
Slug test
  • Overdamped
  • water level recovers to the initial static
    level in a smooth manner that is approximately
    exponential.
  • Underdamped
  • water level oscillates about the static water
    level with the magnitude of oscillation
    decreasing with time until the oscillations cease.

10
Cooper-Bredehoeft-Papadopulos Method (confined
aquifer)
  • H/H0 F(?,?)
  • H head at time t.
  • H0 head at time t 0.
  • ? T t/rc2
  • ? rs2S/rc2

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Underdamped Response Slug Test
  • Van der Kamp Method confined aquifer and well
    fully penetrating.
  • H(t) H0 e-?t cos ?t
  • H(t) - hydraulic head (L) at time t (T)
  • H0 - the instantaneous change in head (L)
  • ? - damping constant (T-1)
  • ? - an angular frequency (T-1)

13
? 2?/(t2-t1)
  • lnH(t1)/H(t2)/ (t2 t1)

14
Underdamped Response Slug Test (cont.)
  • T c a ln T
  • c -a ln0.79 rs2S(g/L)1/2
  • a rc2(g/L)1/2 / (8d)
  • d ?/(g/L)1/2
  • L g / (?2 ?2)

15
Confined
x -y/tan(2?Kbiy/Q)
Q - pumping rate
K - conductivity
b initial thickness
i initial h gradient
x0 -Q/tan(2?Kbi)
ymax ? Q/(2Kbi)
16
Capture Zone Analysis (unconfined aquifer)
  • x -y / tan?Kh12-h22)y/QL
  • x0 -QL/?K(h12-h22)
  • ymax ? QL/K (h12-h22)

17
Static fresh and slat water
Ghyben-Herzberg principle
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Total Dissolved Solids (TDS)
  • Total dissolved solids (TDS) is the total amount
    of solids, in milligrams per liter, that remain
    when a water sample is evaporated to dryness.

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Solid Constituents
  • Major constituents Calcium, magnesium, sodium,
    and potassium (cations) Chloride, sulfate,
    carbonate, and bicarbonate (anions).
  • Minor constituents iron, manganese, fluoride,
    nitrate, strontium, and Boron.
  • Trace elements arsenic, lead, cadmium, and
    Chromium.

22
Dissolved Gases
  • Oxygen.
  • Carbon dioxide.
  • Nitrogen.
  • Hydrogen sulfide
  • Methane.

23
Mass transport of solutes
  • Diffusion both ionic and molecular species
    dissolved in water move from area of higher
    concentration (chemical activity) to areas of
    lower concentration.
  • Advection moving water carries it dissolved
    solutes.

24
Diffusion Ficks laws
  • Ficks first law
  • F -D dC/dx
  • F mass flux of solute per unit area per
    unit time.
  • D diffusion coefficient (area/time)
  • C solute concentration (mass/volume)
  • dC/dx concentration gradient
    (mass/volume/distance).
  • D ranges from 1 x 10-9 to 2 x 10-9 m2/s, for the
    major cations and anions.

25
Diffusion Ficks laws (cont.)
  • Ficks second law
  • ?C/?t D ?2C/?x2
  • D diffusion coefficient (area/time)
  • C solute concentration (mass/volume)
  • t time

26
Effective diffusion coefficient
  • D wD.
  • D effective diffusion coefficient.
  • w empirical coefficient.

27
Advection
  • Advecting contaminants travel at the same rate as
    the average linear velocity of ground water
  • vx -(K/ne) dh/dl
  • vx average linear velocity
  • K hydraulic conductivity
  • ne effective porosity
  • dh/dl hydraulic gradient

28
Mechanical Dispersion
  • Dispersion is a process that a contaminated fluid
    dilutes as it mixs with noncontaminated water
    when passing through a porous medium.

29
Mechanical Dispersion
  • Longitudinal dispersion the mixing occurs along
    the pathway of fluid flow

30
Mechanical Dispersion
  • Longitudinal dispersion if the mixing occurs
    along the pathway of fluid flow
  • - it moves faster through the center of the
    pore
  • - some of the fluid will travel in longer
    pathways
  • - fluid travels faster through larger pore.
  • Transverse or lateral dispersion if the mixing
    occurs normal to the pathway of fluid flow.
  • - flow paths can split and branch out to the
    side.

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Mechanical Dispersion
  • Mechanical dispersion aLvx
  • aL dynamic dispersivity
  • vx average linear velocity

33
Hydrodynamic Dispersion
  • Hydrodynamic dispersion
  • DL D aLvx
  • DL longitudinal coefficient of hydrodynamic
    dispersion
  • D effective molecular diffusion
    coefficient
  • aL dynamic dispersivity
  • vx average linear ground-water velocity

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Advection-dispersion Equation
  • DL?2C/?x2 vx?C/?x ?C/?t
  • DL?2C/?x2 dispersion (diffusion
    dispersivity).
  • vx?C/?x Advection

36
Solute Transport by Advection-Dispersion
  • C C0/2erfc(L-vxt)/2(DLt)1/2
    exp(vxL/DL)erfc(L-vxt)/2(DLt)1/2
  • C solute concentration (M/L3, mg/L)
  • C0 initial concentration (M/L3, mg/L)
  • L flow path length (L ft/m)
  • vx average ground velocity (L/T)
  • t time since release of the solute (T)
  • DL longitudinal dispersion coefficient
    (L2/T)

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Apparent longitudinal dynamic dispersivity
  • aL 0.83(log L)2.414
  • aL apparent longitudinal dynamic dispersivity
    (L ft/m)
  • L length of the flow path (L ft or m).

41
Ground water flow
Continuous source
42
Ground water flow
Continuous source
43
Retardation
  • Adsorption is a process for a negative (positive)
    charge to adsorbing a charged cation (ion).

44
Retardation adsorption isotherm
  • A graphic plot of C as a function of C
  • C mass of solute adsorbed per bulk unit dry
    mass of soil
  • C equilibrium solute concentration

45
Retardation - Freundlich equation
  • log C j log C log Kf or C KfCj
  • C mass of solute adsorbed per bulk unit dry
    mass of soil
  • C equilibrium solute concentration
  • Kf, j coefficients
  • If C vs C is a straight line Kd dC/dC
    (distribution coefficient)

46
C mass adsorbed per unit weight of soil
C equilibrium concentration of solute remaining
in solution
Adsorption isotherm
47
Langmuir Adsorption Isotherm
  • If C/C vs. C is a straight line
  • C/C 1/(?1?2) C/?2
  • C equilibrium concentration of the ion in
    contact with the soil (mg/L)
  • C amount of the ion adsorbed perl unit weight
    of soil (mg/g)
  • ?1 an adsorption constant related to the
    binding energy
  • ?2 an adsorption maximum for the soil.

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Retardation Factor
  • Retardation factor 1 (?b/?)(Kd)
  • ?b dry bulk mass density of the soil (M/L3
    gm/cm3)
  • ? volumetric moisture content of the soil
    (dimensionless).
  • Kd distribution coefficient for solute with
    the soil (L3/M mL/g)

50
Solute Movement with Retardation
  • vc vx/1 (?b/?)(Kd)
  • vc velocity of the solute front. In
    one-dimensional column the solute concentration
    is one-half of the original value (L/T ft/day or
    m/day).
  • vx average linear velocity (L/T ft/day or
    m/day).

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55
Mass transport of solutes
  • Diffusion both ionic and molecular species
    dissolved in water move from area of higher
    concentration (chemical activity) to areas of
    lower concentration.
  • Advection moving water carries it dissolved
    solutes.

56
Retardation Factor
  • Retardation factor 1 (?b/?)(Kd)
  • ?b dry bulk mass density of the soil (M/L3
    gm/cm3)
  • ? volumetric moisture content of the soil
    (dimensionless).
  • Kd distribution coefficient for solute with
    the soil (L3/M mL/g)
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