(PCT,PCN)???

1
????????????? (PCT,PCN)???
????????????????? ?? ? (???????? ???????
???????????)
2
?????????PCB?????????????????????????(PCT)???????
????(PCN)?????????????????????????????????????????
???????GC/MS?????????????
3
????PCT????
HVAS,?1000m3 PUF,GFF
????
PUF??????? GFF???? over16hrs
????????
????
????????????
?????
??????????
HRGC/HRMS??
4
????
????
5
???????
M1CT
D2CT
6
1????2???????????????????????????????????????????
??????????????????????????????????????????????????
?????????????????????????????
7
????PCN????
????
?1L
?????????????
?/???
???????
????
??????????
HRGC/HRMS??
8
????PCN????
????
?????10g
?????????????
????????
???? over16hrs
????
?????????????(GPC)
??????
???
??????????
HRGC/HRMS??
9
????
????
10
???????
T4CN
11
????????????????????????????????????????????????
??????????????????? ???????????????????????????
??GPC???????????? 1???????????????2-Chloronaphth
alene-d7??????????????????????????????????????????
??????????????
12
PCN???????
?????????
?????????
?????????
13
????PCN????
????
?10L
?????????????
ADVANTEC GC-50 EmporeTM Disk C18 FF
????
?????
????100mL30?2?
????????????
?????
??????????
HRGC/HRMS??
14
??????????
T4CN
???10L
T4CN
???1L
15
???????
16
????
12C
12C
HCB
HCB
13C
13C
HCB
HCB
ß-HCB
a-HCB
12C
ß-HCB
12C
?-HCB
?-HCB
a-HCB
?-HCB
ß-HCB
ß-HCB
13C
?-HCB
a-HCB
a-HCB
13C
17
??????
????????????????????????????????????????????????
?????????? ????????????????????????1???????????
????????????????????????????
18
????PCN????
????
?10g(????)
?????????????
?? ?????? ?? ASE
????????????
?????
?????????????(GPC)
??????
???
????????????
?????
??????????
HRGC/HRMS??
19
????
20
??????
????????????????????????????????
??????????ASE???????????????????????
1??????????????????????
21
????PCN????
????
??????
?10g??
?????????????
??????(ASE)
n-???? 2?
????????????
?????
?????????????(GPC)
????????????
?????
??????????
HRGC/HRMS??
22
????
23
??????
???ASE??????????????????????????????????????????
????????????????????
24
?????
PCT ????????????? PCN 1???????????? ?????????
??? ????????