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Literature Review

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EEL. KASSERIS EMMANUEL. The Author. Joseph J. Romm ... EEL. KASSERIS EMMANUEL. Analytical Presentation- Chapter 4 'Natural Gas Steam Reforming. ... – PowerPoint PPT presentation

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Title: Literature Review


1
Literature Review
  • The Hype about Hydrogen

2
Overview
  • The Hype about Hydrogen-Fact and Fiction in the
    Race to Save the Climate publ. 2004
  • Main Themes
  • Hydrogen isnt the quick technological fix it is
    cracked up to be. The hurdles are significant.
  • Hydrogen for transportation is unlikely to have
    an impact before 2040.
  • The climate cant wait that long.
  • We should adopt already commercially available
    energy-efficient and renewable technologies now.
  • Neither gov. policy, nor business investment
    should be based on the belief that FCVs will
    have medium term commercial success.

3
The Author
  • Joseph J. Romm
  • Involved with Hydrogen and FCV RD at the DOE
    during the Clinton Administration.
  • Currently executive director of the Center for
    Energy and Climate Solutions
  • Author of 2 books

4
Analytical Presentation-Chapter 1
  • Why Hydrogen? Why Now?
  • In the last ten years hydrogen RD has taken huge
    proportions (DOE funding from 1-2106 to
    1.2109 /year)
  • Reasons
  • Advances in PEM F/Cs-Reductions in cost.
  • Growing energy security risks.
  • Environmental risks.
  • Advances in H2 production Technology from
    renewables.

5
Analytical Presentation-Chapter 2
  • Fuel Cell Basics
  • Presentation of different F/C types advantages
    and disadvantages
  • Promise vs Performance Caution!
  • People tend to be overoptimistic in the RD phase
  • UTC in the mid 90s promised 40 efficiency for
    the PC25,sold it for 3000/kW and projected
    1500/kW by 2000.
  • By 2003 measured efficiency was 35 and the cost
    was 4500/kW.
  • DOE FC cost goals unrealistic.

6
Analytical Presentation-Chapter 3
  • The path to Fuel Cell Commercialization
  • The problem Who will buy F/Cs before their cost
    comes down dramatically?
  • How will the reduction in cost be achieved
    without mass sales? (mass production RD cash
    inflow)
  • The problem especially acute in the USA-cheap gas
    and electricity.

7
Analytical Presentation-Chapter 3
  • The High-Reliability Distributed Generation
    Market (e.g. banks)
  • This market is much smaller and growing much more
    slowly than has been widely touted
  • A significant number of companies that need
    premium power, have a system that works well for
    them.
  • New technology needs time to establish itself.

8
Analytical Presentation-Chapter 3
  • The Residential Market(0.75kW)
  • PEM unsuitable (Reformers, ?el, cost)
  • SOFCs have unacceptably long start-ups (hours)
  • The Cool Power Market (ultra clean energy for
    PR).
  • CHPgthigh temperature F/Csgt continuous
    operation only.
  • Few companies with such applications are willing
    to pay the extra cost.

9
Analytical Presentation-Chapter 3
  • The enormous On-Site Generation Market.(sub MW)
  • A mid-term prospect (as soon as F/C costs are
    down to 800-1300/kW)
  • DoE studies have shown that the potential market
    is enormous
  • Still, penetration will be difficult because
  • The competition is tough (very mature
    technologies )
  • Competition from a lower utilities bill
  • Procrastination
  • Regulatory barriers

10
Analytical Presentation-Chapter 3-4
  • Hydrogen Production
  • Although stationary FCs might have potential for
    the mid-term, to tackle oil demand and CO2
    emissions one needs to replace gas in
    transportation.
  • Need for H2 production for car PEMs

11
Analytical Presentation-Chapter 4
  • Natural Gas Steam Reforming.
  • 4-5/kgr H2 equivalent to 1 gallon of gas.
  • Low to no GHG-benefits
  • Very expensive infrastructure
  • Effect on NG prices?
  • Much cheaper at large centralized facilities than
    at the filling station but then it has to be
    transported.

12
Analytical Presentation-Chapter 4
  • Electrolysis.
  • 7-9/kgr H2 at centralized facilities , 12/kgr
    H2 at the filling station but no transportation
    required.
  • No GHG benefits until the grid is to a large
    extent CO2 free (decades).

13
Analytical Presentation-Chapter 4
  • Coal.
  • Most abundant Fossil Fuel (more than 300 years)
  • Gasificationcombined cycleH2electricity.(Though
    still transportation required)
  • The key term here is sequestration-Still in the
    early RD stage with many doubts that it is
    feasible.

14
Analytical Presentation-Chapter 4
  • Biomass.
  • With sequestration-CO2 reducer.
  • Gasification or Pyrolysis
  • 5-6.3/kg H2
  • What fraction of land would be needed?
    Politically feasible?
  • Transportation
  • Is H2 the best use for biomass ? Biofuels?

15
Analytical Presentation-Chapter 4
  • Nuclear.
  • Thermochemical Water-Splitting.
  • Safety?
  • Waste?
  • Transportation
  • Cost

16
Analytical Presentation-Chapter 5
  • Key Elements of a Hydrogen-Based Transportation
    System
  • Bernard Bulkin, BP If H2 is going to make it in
    the mass market, it has to be available in 30-50
    o the retail network,the day the 1st mass
    produced FCV hits the showrooms
  • 50.000-90.000 new stations-0.51012
    infrastructure costs

17
Analytical Presentation-Chapter 5
  • On-board H2 storage
  • LH2
  • good grav. and vol. density
  • 40 energy lossesgtmore GHG than gas.
  • CH2
  • Bad grav. vol. density
  • Hydrides
  • Good vol. density/Terrible grav.
  • Suboptimal H2 release.

18
Analytical Presentation-Chapter 5
  • H2 transportation
  • TrucksLH2least expensive but 50 losses
  • PipelinesCH2Extremely expensive (unless very
    high flow rate)
  • Trailerscanisters of CH2Practical but expensive
    and energy intensive . A 40t truck carries 400kg
    of H2.For distancesgt300miles 40 losses.
  • H2 Safety issues

19
Analytical Presentation-Chapter 5
  • Key Elements of a Hydrogen-Based Transportation
    System
  • Production Site
  • On board (cancelled by the DOE)
  • Centralized Leads to transportation problems.
  • At the fuel station Leads to high cost, losses
    and safety issues

20
Analytical Presentation-Chapter 6
  • Barriers
  • Honda At least 10 years before FCV cost down to
    100.000
  • DOE Future FCV at least 40-60 more expensive
    than ICE
  • Fuel Cost at least 2xgas cost
  • Infrastructure issues

21
Analytical Presentation-Chapter 6
  • Possible Solutions
  • H2 ICEs
  • DO NOT solve the chicken and egg problem
  • Less WTW, possibly more GHG, higher LCA costs
    than gas ICE
  • Fleets
  • Cost Range are more important
  • AFV fleets failure in the 90s
  • Mobile Utilities
  • Where is the fuel going to come from?
  • Lifetime, Cost and regulatory issues

22
Analytical Presentation-Chapter 7
  • Global Warming and Scenarios for a Hydrogen
    Transition
  • Evidence on the magnitude of global warming
    correlation to CO2 emissions.
  • Time and money is limited
  • The most easy/efficient way to reduce CO2 is
    needed.

23
Analytical Presentation-Chapter 8
  • Coping with the Global Warming Century
  • Which technology achieves the highest CO2
    reduction/ spent?
  • The competition is getting tougher (clean ICEs,
    RES, energy saving technologies)
  • In the mid-term H2 from NG-Gas. Hybrids have less
    CO2 emissions
  • NG and RES used to make H2 for FCVs would
    achieve higher CO2 reduction at lower costs if
    used to displace coal plants

24
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25
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26
Analytical Presentation-Chapter 8
  • Coping with the Global Warming Century
  • The authors scenario for this century
  • In the beginning,more hybrids,NG and RES
  • Possibly sequestration and biofuels afterwards.
  • In the end, we will be forced to switch to
    renewable H2 because of severe climate change.
  • One way or another we wont avoid serious climate
    change effects.

27
Analytical Presentation-Chapter 10
  • Conclusion-Choosing our Future
  • What we should do
  • Long term, conservative perspective on H2.
  • Increase RD into clean energy Technologies.
  • Start reducing emissions using low cost
    strategies
  • Begin a national effort to use CHP
  • Launch a national effort to use Electricity and
    gas more efficiently
  • Phase in CO2 related standards for cars
  • Prepare the public for the tough choices ahead

28
Commentary
  • Generally well-stated and supported case.
  • Not completely impartial.
  • at times he leaves important information out.
    (e.g. power comparison in the tank instead of on
    the road)
  • Exaggerations
  • A quote is not always proof-2 graphs in the whole
    book.
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