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Chain Reaction Mechanisms

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... molecular species (not necessarily a reactant in the overall reaction) reacts to ... A reactive intermediate attacks a reactant in the overall reaction to generate ... – PowerPoint PPT presentation

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Title: Chain Reaction Mechanisms


1
Chain Reaction Mechanisms
  • A chemical pathway characterized by the
    following distinctive steps
  • a) Initiatiation
  • b) Propagation
  • c) Inhibition
  • d) Termination

2
Chain Reaction Mechanisms - contd.
  • Initiation A step in which a stable molecular
    species (not necessarily a reactant in the
    overall reaction) reacts to generate one or more
    reactive intermediates
  • Propagation A reactive intermediate attacks a
    reactant in the overall reaction to generate a
    new reactive intermediate
  • Inhibition A reactive intermediate attacks a
    product in the overall reaction to generate a new
    reactive intermediate
  • Termination Reactive intermediates combine with
    one another to form a stable molecular species

3
Example of a Chain Reaction Mechanism
4
Example of a Chain Reaction Mechanism - contd.
5
Example of a Chain Reaction Mechanism - contd.
6
Example of a Chain Reaction Mechanism - contd.
7
Example of a Chain Reaction Mechanism - contd.
8
Example of a Chain Reaction Mechanism - contd.
9
Example of a Chain Reaction Mechanism - contd.
10
Example of a Chain Reaction Mechanism - contd.
11
Example of a Chain Reaction Mechanism - contd.
12
A Chain Reaction - Problem 1
13
A Chain Reaction - Problem 2
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