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Chapter 33: Radioactivity

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Title: Chapter 33: Radioactivity


1
  • Chapter 33 Radioactivity
  • Atomic Structure pg. 637-8 fig. 33.5 33.7 33.8
  • The atomic nucleus composed of _____________ and
    __________
  • Protons (__ charge) neutrons (___ charge).
  • Nucleons (p and nos) nearly _______ times more
    massive than electrons.
  • In a neutrally charged atom there is an
    __________ number of protons and electrons (the
    magnitude of the charge of electrons and protons
    is the same but opposite in __________).
  • Positively charged protons hold negatively
    charged electrons in their ___________.
  • When an atom gains or loses electrons it becomes
    an ________ (if more p than e- it is a
  • ___ charged cation, if more e- than p than a
    ___ charged anion).
  • Chemical properties of an element determined by
    the numbers of __________.
  • (_________number-identifies the element).
  • Numbers of nos has no effect on the electron
    orbits (wont effect the chemistry of the
    element).
  • no act as a ___________ to hold the nucleus
    together (adds to the nuclear _________
    force/force holding nuclear particles together)
    to overcome repulsive forces of ps for each
    other.
  • The greater the number of ps in a nucleus, the
    greater the number of nos required to hold the
    nucleus together (for light elements there can be
    nearly _________ numbers of nos and ps / very
    heavy elements there are many _________ nos than
    ps).
  • Unpaired no decays into a p and an e- (an e- is
    a ____ particle).
  • For a nuclear reaction, mass of products is
    ______ than mass of reactants. Mass converted
    to energy (E mc2).
  • All elements above the atomic of _____ are
    radioactive (too many nos required to hold the
    nucleus together, unpaired nos decay).

neutrons protons
no
2000
equal
sign
orbits
ion

-
protons
atomic
strong
cement
equal
more
ß
less
83
2
  • 3 distinct modes of decay pg. 635-6 fig. 33.3
    33.4
  • Alpha ( a ) decay-a ________ nucleus (42 He2).
  • Beta ( ß ) decay- an ______________ (0-1e) .
  • Gamma ( ? ) highest _________ (shortest ?) EM
    radiation.
  • Alpha least penetrating Gamma most penetrating.
  • Radioactive Isotopes pg. 638
  • Elemental isotopes have _________ numbers of
    ps but different numbers of _________
  • (isotopes of same element have different mass
    numbers).
  • Symbols of elements are written as follows mass
    atomic Element for example 146C
  • Atomic mass a _____________ average of all the
    isotopes of an element
  • Isotopes will vary in their degree of
    __________________.
  • Half-Life pg. 641-2 fig. 33.9
  • Radioactive elements decay at different
    _________.
  • Half-life ________ required for ½ of a substance
    to decay.
  • Example If you have 40 g of sample and the
    half-life is 2 years, how much of the 40 g will
    remain after 2 years? ____ g after 6 years?
    ____ g
  • Transmutation of Elements pg. 645-6 fig. 33.4
  • Transmutation New nucleus formed from a
    nuclear change.
  • Transmutations represented by chemical equations
    (the sum of the mass and atomic s of reactants
    is _________ to products)

helium
electron
energy
equal
neutrons
weighted
radioactivity
rates
time
20
5
equal
3
  • Nucleus composed of p and no
  • Nucleon (p or n0 nearly 2000 times more massive
    than e-)
  • Atomic number ( of p) identifies an element
  • p and e- have the same magnitude of charge
    (opposite sign)
  • When elements lose e-s they become cations (gain
    anions)
  • Neutron plays no role in the chemistry of
    elements
  • but acts as a cement to hold nucleus
    together
  • The force holding nuclear particles (p and no)
    together is the nuclear strong force (only acts
    over extremely short distances)
  • For light elements there are nearly s of no
    and p
  • The more protons in a nucleus, the larger the
    neutron to proton ratio required to hold nucleus
    together
  • no not paired with p will decay into a p and an
    e-
  • (this will decrease the no to p ratio)
  • For nuclear reactions mass ?
    energy
  • (Emc2)

4
  • All elements above atomic of 83 or more are
  • 3 modes of decay
  • Alpha Decay(a - a Helium nucleus 42He, least
    penetrating)
  • Beta Decay (ß - an electron o-1e)
  • Gamma Decay (? - short ? EM radiation, most
    penetration)

5
  • Radioactive Isotopes- same of p different of
    no
  • (some more than others)
  • Half-Life a way to measure rate of radioactive
    decay
  • (time required for half of a sample to decay)
  • Transmutation-A nucleus changing into another
    nucleus
  • 23892U ? 23490Th 42He 23490Th ? 23491Pa 0-1e
  • (the sum of the mass and atomic are conserved
    on each side of the yields arrow)

6
  • Artificial Transmutation pg.647-648
  • In 1919, Ernest Rutherford bombarded nitrogen
    nuclei with ________ particles from a piece of
    radioactive ore and found traces of oxygen and
    hydrogen were produced.
  • 147N 42He ? 178O 11H
  • After Rutherfords work, many bombarded elements
    with radioactive particles (later with high speed
    particles in atom-smashing particle
    _______________________).
  • Elements beyond _____ of periodic table formed
    by transmutation.
  • Carbon Dating pg. 651-652 fig. 33.18
  • The earths atmosphere continually bombarded with
    _________ rays (mainly high energy protons).
    Result of bombardments is the transmutation of
    many atoms. Atmospheric protons capture stray
    electrons to become _______________ in the upper
    atmosphere. Neutrons have _____ charge (can
    travel long distances with no interactions with
    other matter).
  • The neutrons can __________ with nitrogen
    molecules in lower atmosphere to convert 14N to
    14C
  • (14C is a radioactive nuclide). 147N 10n ?
    146C 11H
  • Most carbon on earth is 12C a small percentage is
    14C (contained atmospheric CO2).
  • Plants take in CO2, living things eat plants, so
    all living things contain some 14C.
  • Carbon-14 (a ____ emitter) decays into nitrogen.
    146C ? 147N 0-1e
  • When a living thing dies, it stops taking in 14C
    (which will decay at a known rate called _______
    life).
  • If analyzed later, the amount of 14C in dead
    material carbon-14 will ___________.
  • Compare amount of 14C in a current piece of
    material to the old material of the same size.
    The ratio can be used to ________ the material
    (used to date trees, wooden artifacts, skeletons
    etc).
  • Assumptions are made which can yield large
    sources of error.
  • Atmosphere remains ____________ in its
    production of 14C (not true due to the changing
    magnetic field of the earth and changing cosmic
    activity of the earth or no microorganisms on the
    materials to add to or take away from the amount
    of 14C).

alpha
accelerators
92
cosmic
no
neutrons
collide
ß
half
decrease
date
constant
7
  • Radioactive Tracers pg.649 fig. 33.15
  • Radioactive __________ (radioactive isotopes)
    incorporated into compounds can give location of
    the compound over time.
  • Once in an organism or material, a detector
    (Geiger counter, scintillation counter, or other
    radioactive probe) can determine the amount of
    that isotope present in different locations.
  • Tracers used to study metabolic pathways, blood
    circulation or the amount of a certain fertilizer
    taken up by a plant.
  • Automobile engineers test wear (using different
    kind of motor oils) of pistons (make piston wall
    _______________ ). When piston wall wears away
    the radiotracer is gone (gives off no radiation
    from that point on).
  • Tracers used to determine location of pipe
    _____________.
  • Effects of Radiation on Humans Read pg. 653-655

tracers
radioactive
leaks
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