This interaction looks electrstatic not chemical - PowerPoint PPT Presentation

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This interaction looks electrstatic not chemical

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What is wrong with this wavefunction? No delocalization!!! Note: Fermi says overall wavefunction must be antisymmetric /wrt exchange of electrons. ... – PowerPoint PPT presentation

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Title: This interaction looks electrstatic not chemical


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This interaction looks electrstatic not
chemical This trial wavefunction does NOT
describe (even qualitatively) the behavior of H2
What is wrong with this wavefunction? No
delocalization!!!
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Note Fermi says overall wavefunction must be
antisymmetric /wrt exchange of electrons. But,
this is just the spatial part of the
wavefunction The spin part of the wavefunction
can be symmetric (triple) or antisymmetic
(singlet), too.
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Fin
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