Chapter 3 Stoichiometry: Calculations with Chemical Formulas and Equations

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Chapter 3 Stoichiometry: Calculations with Chemical Formulas and Equations

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0.5 mol of carbon is combusted with 1.0 mol of oxygen gas. ... g of carbon are combusted with. 32.0 g of ... 3.0 moles Mg are combusted with 2.0 moles O2. ... –

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Title: Chapter 3 Stoichiometry: Calculations with Chemical Formulas and Equations


1
Chapter 3Stoichiometry Calculations with
Chemical Formulasand Equations
2
The following equation is unbalanced CS2 O2
CO2 SO2 What is the correct
balanced equation?
3
Correct Answer
  • CS2 2 O2 CO2 2 SO2
  • 2 CS2 12 O2 2 CO2 4 SO2
  • CS2 3 O2 CO2 2 SO2
  • CS2 6 O2 CO2 2 SO2

This is the only case where the number of each
type of atom is the same on both the reactant and
product sides of the equation.
4
Which of the following is the correct, balanced
chemical equation for the combustion of ethanol
(C2H5OH)?
  • C2H5OH O2 CO2 H2O
  • C2H5OH 3 O2 2 CO2 3 H2O
  • C2H5OH 6 O2 4 CO2 6 H2O
  • 2 C2H5OH 7 O2 4 CO2 6 H2O

O
O
5
Correct Answer
  • C2H5OH O2 CO2 H2O
  • C2H5OH 3 O2 2 CO2 3 H2O
  • C2H5OH 6 O2 4 CO2 6 H2O
  • 2 C2H5OH 7 O2 4 CO2 6 H2O

O
O
O
6
If the empirical formula of a compound is C2H2N
but the molecular weight is 160 g/mol, what is
the molecular formula?
  • C2H2N
  • C4H4N2
  • C6H8N3
  • C8H8N4
  • None of the above choices is correct.

7
Correct Answer
  • C2H2N
  • C4H4N2
  • C6H8N3
  • C8H8N4
  • None of the above choices is correct.

FW C2H2N (24 2 14) g/mol 40 g/mol MW/FW
160/40 4 Thus, molecular formula is 4?
empirical formula 4(C2H2N) C8H8N4
8
How many fluorine atoms are present in 2.0 moles
of AlF3?
  • 3.0 ? 1023
  • 6.0 ? 1023
  • 1.2 ? 1024
  • 3.6 ? 1024
  • None of the above answers is correct.

9
Correct Answer
  • 3.0 ? 1023
  • 6.0 ? 1023
  • 1.2 ? 1024
  • 3.6 ? 1024
  • None of the above answers is correct.

(2.0 moles AlF3)(6.0 ? 1023 molecules AlF3/mole
AlF3) (3 atoms F/1 molecule AlF3) 3.6 ? 1024
10
Which of the following samples has the largest
number of atoms?
  • 28 g Si
  • 28 g CO
  • 28 g N2
  • 15 g C2H4
  • All of the above have equal numbers of atoms.

11
Correct Answer
  • 28 g Si
  • 28 g CO
  • 28 g N2
  • 15 g C2H4
  • All of the above have equal numbers of atoms.

28 g Si has 1 mole of atoms, whereas 28 g of CO
and N2 have 2 moles of atoms, even though they
also have only 1 mole substance. However, there
are 6 atoms for every 1 mole of C2H4, so in this
case there are slightly more than 3 moles worth
of atoms.
12
The molecular mass for the compound, XClO3, is
122.5 amu. The atomic mass of X is equal to ____
amu, which is the element ____.
  • 1.0 H
  • 6.9 Li
  • 23.0 Na
  • 39.1 K
  • 85.5 Rb

13
Correct Answer
  • 1.0 H
  • 6.9 Li
  • 23.0 Na
  • 39.1 K
  • 85.5 Rb

MW 122.5 amu AW X AW Cl 3(AW O) 122.5 amu
? AW Cl ? 3 (AW O) AW X 122.5 amu ? (35.45 amu)
? 3 (16.0 amu) AW X 122.5 ? 35.45 amu ? 48.0
amu AW X AW X 39.1 amu
14
When the chemical equation, C4H10(g) O2(g)
H2O(g) CO2(g), is balanced, the
stoichiometric coefficients are, respectively
  • 1, 4, 5, 4
  • 2, 13, 10, 8
  • 2, 9, 8, 10
  • 2, 7, 4, 5

15
Correct Answer
  • 1, 4, 5, 4
  • 2, 13, 10, 8
  • 2, 9, 8, 10
  • 2, 7, 4, 5

16
The combustion of methane (CH4) is shown below
CH4(g) 2 O2(g) 2 H2O(l) CO2(g)
How many grams of water are produced in the
combustion of 1.0 moles of methane?
  • 16 g
  • 32 g
  • 36 g
  • 48 g

17
Correct Answer
  • 16 g
  • 32 g
  • 36 g
  • 48 g

(1.0 mole CH4)(2 moles H2O/1 mole CH4)
(18 g H2O/1 mole H2O) 36 g
18
0.5 mol of carbon is combusted with 1.0 mol of
oxygen gas. Which of the following statements is
correct?
  • There is a molar excess of carbon, not all carbon
    is consumed.
  • There is a molar excess of oxygen, not all oxygen
    is consumed.
  • There are stoichiometrically equivalent amounts
    of carbon and oxygen gas.

19
Correct Answer
  • There is a molar excess of carbon, not all carbon
    is consumed.
  • There is a molar excess of oxygen, not all oxygen
    is consumed.
  • There are stoichiometrically equivalent amounts
    of carbon and oxygen gas.

C and O2 react in a 11 stoichiometric ratio,
therefore there must be excess O2 because there
was a larger initial number of moles of it.
20
0.5 mol of carbon is combusted with 1.0 mol g of
oxygen gas. How many moles of carbon dioxide are
produced?
  • 1.5 mol
  • 1.0 mol
  • 0.5 mol
  • 2.0 mol

21
Correct Answer
  • 1.5 mol
  • 1.0 mol
  • 0.5 mol
  • 2.0 mol

C and O2 react in a 11 stoichiometric ratio,
therefore C must be the limiting reagent and O2
must be the excess reagent. Initially, (0.5
moles C)(1 mole CO2/1 mole C) 0.5 mole CO2
22
24.0 g of carbon are combusted with 32.0 g of
oxygen gas. How many grams of carbon dioxide are
produced?
  • 56.0 g
  • 88.0 g
  • 28.0 g
  • 44.0 g

23
Correct Answer
  • 56.0 g
  • 88.0 g
  • 28.0 g
  • 44.0 g

C and O2 react in a 11 stoichiometric ratio.
Initially, (24.0 g C) ? (1 mole C/12.0 g C) ? (1
mole CO2/1 mole C) 2.0 mole CO2 (32.0 g O2) ?
(1 mole O2/32.0 g O2) ? (1 mole CO2/1 mole O2)
1.0 mole CO2 Thus, O2 is limiting, and 1.0 mole
of CO2 is 44.0 g.
24
3.0 moles Mg are combusted with 2.0 moles O2.
What is the limiting reagent and how many moles
of the excess reagent remain?
  • Magnesium, 0.5 mole
  • Magnesium, 1.0 mole
  • Oxygen gas, 0.5 mole
  • Oxygen gas, 1.0 mole

25
Correct Answer
  • Magnesium, 0.5 mole
  • Magnesium, 1.0 mole
  • Oxygen gas, 0.5 mole
  • Oxygen gas, 1.0 mole

Mg and O2 react in a 21 stoichiometric ratio.
Initially, (3 mole Mg)(2 mole MgO/2 mole Mg)
3.0 mole MgO (2 mole O2)(2 mole MgO/1 mole O2)
4 mole MgO Thus, Mg is limiting, and 3 mol Mg
will consume 1.5 mol of O2, leaving 0.5 mole of
O2.
26
How many oxygen atoms are presentin MgSO4 7
H2O?
  • 4 oxygen atoms
  • 5 oxygen atoms
  • 7 oxygen atoms
  • 11 oxygen atoms
  • 18 oxygen atoms

27
How many oxygen atoms are presentin MgSO4 7
H2O?
  • 4 oxygen atoms
  • 5 oxygen atoms
  • 7 oxygen atoms
  • 11 oxygen atoms
  • 18 oxygen atoms

28
How many sulfur atoms are presentin 1.0 mole of
Al2(SO4)3?
  • 1 sulfur atom
  • 3 sulfur atoms
  • 4 sulfur atoms
  • 6.0 x 1023 sulfur atoms
  • 1.8 x 1024 sulfur atoms

29
How many sulfur atoms are presentin 1.0 mole of
Al2(SO4)3?
  • 1 sulfur atom
  • 3 sulfur atoms
  • 4 sulfur atoms
  • 6.0 x 1023 sulfur atoms
  • 1.8 x 1024 sulfur atoms

30
If you have equal masses of the following metals,
which will have the most number of atoms?
  • Lithium
  • Sodium
  • Potassium
  • Rubidium
  • Calcium

31
If you have equal masses of the following metals,
which will have the most number of atoms?
  • Lithium
  • Sodium
  • Potassium
  • Rubidium
  • Calcium

32
How many moles of oxygen gas are requiredto
react completely with 1.0 mole NO?
  • 0.5 mol O2
  • 1.0 mol O2
  • 1.5 mol O2
  • 2.0 mol O2
  • 2.5 mol O2

33
How many moles of oxygen gas are requiredto
react completely with 1.0 mole NO?
  • 0.5 mol O2
  • 1.0 mol O2
  • 1.5 mol O2
  • 2.0 mol O2
  • 2.5 mol O2

34
If 10.0 moles of NO are reacted with 6.0 moles
O2, how many moles NO2 are produced?
  • 2.0 mol NO2
  • 6.0 mol NO2
  • 10.0 mol NO2
  • 16.0 mol NO2
  • 32.0 mol NO2

35
If 10.0 moles of NO are reacted with 6.0 moles
O2, how many moles NO2 are produced?
  • 2.0 mol NO2
  • 6.0 mol NO2
  • 10.0 mol NO2
  • 16.0 mol NO2
  • 32.0 mol NO2

36
If 10.0 moles of NO are reacted with 6.0 moles
O2, how many moles of the excess reagent remain?
  • 1.0 mol O2
  • 5.0 mol O2
  • 4.0 mol NO
  • 8.0 mol NO
  • None of the above

37
If 10.0 moles of NO are reacted with 6.0 moles
O2, how many moles of the excess reagent remain?
  • 1.0 mol O2
  • 5.0 mol O2
  • 4.0 mol NO
  • 8.0 mol NO
  • None of the above
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