1. Metalation of p-Excessive Heteroaromatics

1
1. Metalation of p-Excessive Heteroaromatics
2
Thermodynamic Acidities of p - Excessive
Heteroaromatics
3
Kinetic Acidities of p - Excessive
Heteroaromatics.
4
Synthetic Use of Metalated non-DMG Furans
and Thiophenes. Conversions into other
Heterocycles
5
Synthetic Use of Metalated non-DMG Furans
and Thiophenes. Oxidative Pathways
6
Metalated Furans. Additions on Glycosyl Nitrones
7
Use of Metalated non-DMG Thiophenes. Historical
Industrial Practice
8
Directed ortho Metalation (DoM) Reactivity of
Furans and Thiophenes
9
DoM Chemistry of Furans and Thiophenes.
Carbon-Based DMGs. DMG 2-oxazolino
10
DoM Chemistry of Furans. DMG CON-R. Application
11
DoM Reactivity of Furans and Thiophenes.
Dianion Equivalents with Carbon-based DMGs
12
DoM Reactivity of Furans and Thiophenes. DMG
CO2-
13
DoM Chemistry of Furans. DMG CH2O-
14
DoM Chemistry of Furans and Thiophenes.
Heteroatom - Based DMGs, DMG SO2R
15
DoM Reactivity of N-DMG Pyrroles
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DoM Reactivity of N-DMG Pyrroles
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DoM Reactivity of Indoles. N - DMGs
18
DoM Reactivity of Indoles. N-DMG CO2t-Bu.
Indirect C-7 Substitution
19
DoM Reactivity of Indoles. Non-N DMG Indoles.
DMG CONR2
20
DoM Reactivity of Indoles. Non-N DMG Indoles.
DMG CH2NR2
21
DoM Reactivity of Non-N DMG Indoles. DMG
OCONEt2. Benzenoid Ring Functionalization
22
DoM Reactivity of p-Excessive Heteroaromatics.
Pyrrazoles. N DMGs
23
DoM Reactivity of Pyrrazoles. Non-N DMGs. DMG
SO2N-R
24
DoM Reactivity of Pyrrazoles. Total Synthesis
Application
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Metalation Reactivity of Imidazoles
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DoM Reactivity of Imidazoles. DMG N-SO2NR2.
Silicon Protection
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DoM Reactivity of Imidazoles in Context of
Nucleosides
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DoM Reactivity of Oxazoles
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Metalation Reactivity of Thiazoles
30
Metalation and DoM Reactivity of Methyl
Substituted Oxazoles and Thiazoles
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DoM Reactivity of Aminoisoxazoles
32
DoM Reactivity of 1-Substituted 1,2,4-Triazoles