Options for Removing Water in Oil (1) - PowerPoint PPT Presentation

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Options for Removing Water in Oil (1)

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Water co-exists in oil in essentially the same way it co-exists in the atmosphere. It starts off in the dissolved phase - dispersed molecule-by-molecule throughout the oil. – PowerPoint PPT presentation

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Title: Options for Removing Water in Oil (1)


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Options for Removing Water in Oil
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  • Water, water, everywhere . . . Water is ever
    present in the environment. Unless you live in an
    arid region, it is a fundamental fact of life.

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  • Water co-exists in oil in essentially the same
    way it co-exists in the atmosphere. It starts off
    in the dissolved phase - dispersed
    molecule-by-molecule throughout the oil. Just
    like water present in the air, it cannot be seen
    in oil, which may appear clear and bright.

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  • However, once the saturation point is exceeded,
    water is typically present in the emulsified
    phase creating a milkiness or fog in the oil,
    just like moist air on a cool day. When
    sufficient water exists, or when the oil has
    adequate demulsibility, free water will collect.

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  • Because water is typically heavier than oil, it
    settles below the oil, at the bottom of sumps and
    reservoirs.

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  • The point at which an oil contains the maximum
    amount of dissolved water is termed the
    saturation point. The saturation point is
    dependent on the oils temperature, age and
    additive composition.

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  • The higher the temperature, the higher the
    saturation point and hence more water held in
    solution, in the dissolved phase.

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  • This is the same as being able to dissolve more
    sugar in hot water, than in cold water.
    Similarly, the older the oil, the higher the
    level of water that can be dissolved.

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  • This is due to polar by-products of oxidation in
    the oil, which act as hooks holding on to the
    water molecules and keeping them in solution.

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  • Likewise, highly additized oils, like crankcase
    oils, have a higher saturation point than lightly
    additized oils like turbine oils, because the
    additives - many of which are polar - also hold
    the water in solution.

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