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Functionalized Diaziridines as Potential Electrophilic Aziridinating Agents

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... Aziridinating Agents. Katherine L. Hervert, Department of Chemistry, Ohio Wesleyan University. The facile alkene oxidation to an epoxide is an excellent ... – PowerPoint PPT presentation

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Title: Functionalized Diaziridines as Potential Electrophilic Aziridinating Agents


1
Functionalized Diaziridines as Potential
Electrophilic Aziridinating Agents
Katherine L. Hervert, Department of Chemistry,
Ohio Wesleyan University
  • The facile alkene oxidation to an epoxide is an
    excellent example of an extremely useful
    transformation that produces an intermediate that
    possesses unlimited synthetic utility.
  • By modeling the dioxirane epoxidation reaction,
    we propose a simple, electrophilic aziridination
    methodology utilizing the diaziridine in lieu of
    the dioxirane.

The reaction of trans-stillbene with
electrophilic diaziridine 1 was investigated
using several Cu(I) catalysts and salen
complexes. IIt was found that the aziridine 3
was not yet formed under the examined reaction
conditions.
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