Amides

1
Amides
2
Amides

• O
• R-C
• NH2
• Alkanoamide

3
Common Amides
4
Formamide

• O
• H-C
• NH2
• Methanoamide

5
Acetamide

• O
• CH3-C
• NH2
• Ethanoamide

6
Amides

• O
• CH3-CH2-C
• NH2
• Propanoamide

7
Amides

• O
• -C
• NH2
• Benzoamide

8
N-methylbenzoamide

• O
• -C
• NH
• CH3

9
Making Amides
10
Add Acids Amines

• O
• R-C-OH NH3
• O
• R-C-O- NH4

11
Dehydration Syn

• O
• R-C-O- NH4
• O
• R-C-NH2 H2O

Heat
12
Add Acids Amines

• O
• R-C-OH NH3
• O
• R-C-NH2 H2O

13
Dehydrating Agents

• H2SO4
• P2O5

14
Acetic acid Met amine

• O
• H3C-C-OH CH3NH2

15
N-methylacetamide

• O CH3
• H3C-C-NH H2O

16
Predict Products

• Dehydration synthesis of benzoic acid
  cyclopropylamine

17
Drill

• Draw the organic reactant then, draw name the
  organic product of the dehydration synthesis of
  propanoic acid ammonia.

18
Esters Amines

• O
• R1-C-O-R2
• NH3

19
Amides Alcohols

• O
• R1-C-NH2
• R2-OH

20
Methyl benzoate A

• O
• -C-O-CH3
• NH3

21
Benzoamide MeOH

• O
• -C-NH2
• HO-CH3

22
Anhydrides Amines

• O O
• R1-C-O-C-R2
• NH3

23
Amides Acids

• O
• R1-C-NH2
• O
• R2-C-OH

24
Polyamides
25
AA HDA

• O O
• n HO-C-(CH2)4-C-OH
• n H2N-(CH2)6-NH2

-water
26
Nylon 66

• O O
• -(-C-(CH2)4-C
• NH
• -(HN-(CH2)6

n
27
6-aminohexanoic acid

• O
• x HO-C-(CH2)5-NH2

-water
28
Nylon 6

• O
• x -(-(CH2)5-C-NH-)-

29
COOH COOH
H2N H2N
30
CO H2O C O
HN HN
31
Nitriles
32
Making Nitriles

• O
• R-C-NH2

Heat Dehydration
Dehydrate amides
33
Nitrile Water

• R-C-N H2O

34
CommonNitriles

• R-CN

35
Acetonitrile

• CH3-CN

36
Hydrogen Cyanide

• H-CN

37
Benzonitrile

• -CN

38
Draw name 10 Isomers ofC4H7NO2
39
Draw Isomers ofC4H6O2