Dendron rodcoil : functional triblock selfassembler

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Dendron rodcoil functional triblock
self-assembler
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Analogous DRC molecules
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SAXS of DRC analogues
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Analogous DRC molecules (dendrons generation
series)
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Analogous DRC compounds (coil series)
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Rod-dendron model compounds
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Crystal structure of dendron
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Hydrogen bonded stacks of dendron dimers
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(No Transcript)
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Unit cell of the crystal
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Crystal structure of rod-dendron compound
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Supramolecular ribbon formed by DRC molecules
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TEM image of twisted ribbons formed in ethyl
methacrylate
100 nm
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Tapping mode AFM image of helical ribbons
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Mineralization of gels with cadmium sulfide
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TEM image of CdS structures formed in DRC gels
Angew. Chem., Int. Ed. 2002, 41, 1705
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Minerilization of nanoribbons suspension in EMA
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Controlling the thickness of CdS nanohelices
diameter 12 nm pitch 40 nm
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Proposed templating mechanism
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Proposed route to double helices
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Two-sided mineralization